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Surveying organic matter, thermal maturity level, and paleo-environmental conditions by considering biomarker and stable carbon isotopic analysis
Meysam Hemmati, Yaser Ahmadi, Behzad Vaferi, Ali Hosin Alibak, David A. Wood
 doi: 10.1007/s12583-024-1984-x
[Abstract](69) [PDF 1351KB](39)
Abstract:
Biomarker and stable carbon isotope analyses are presented for the Garau formation of the Cretaceous age, an important source rock in western Iran, to reveal its potential as an oil-prone source rock. The C28/C29sterane ratio value range (0.72 to 0.83) of bitumen samples from the formation suggests that they were likely formed during phytoplankton blooms. Sterane, hopane, and isoprenoid/n-alkane ratios indicate that the formation's organic matter predominantly consists of algae, and bacteria, accompanied by some reworked material derived from higher plants. Due to the predominance of anoxic conditions and the actions of sulfate-reducing bacteria, the bitumen present is enriched with sulfur compounds. The percentages of saturates, aromatics, and nitrogen-sulfur-oxygen (NSO) fractions in the bitumen samples classify them as naphthenic oils. Isotope analysis reveals that biodegradation and water-washing have reduced the concentrations of some volatile saturates and low molecular weight aromatics in the bitumen samples. These actions have resulted in distinctive δ13C values for the formation's kerogen and bitumen fractions. The formation's organic matter has been subjected to high-temperature thermal regimes and has entered the oil-generation window at the sampled localities, with vitrinite reflectance (%RC) varying between 0.7 % and 0.75 %.
A potentially new early Ediacaran glaciation
Zhongwu Lan, Magdalena H. Huyskens, Rong Ren, Qing-Zhu Yin
 doi: 10.1007/s12583-024-1979-7
[Abstract](74) [PDF 1423KB](20)
Abstract:

Multiple episodes of Neoproterozoic glaciation, namely the Beiyixi, Altungol, Tereeken and Hankalchough glaciations, are recorded in the Kuruktag area of northeastern Tarim Craton, NW China. The Tereeken glaciation was previously correlated with the global Marinoan glaciation based on sedimentary and chemostratigraphic features recorded in the cap dolostone immediately overlying the glaciogenic diamictite, as well as less precise radiometric age constraints. In this study, we obtained chemical-abrasion isotope dilution isotope ratio mass spectrometry (CA-ID-IRMS) U-Pb age of 624.03 ± 0.1 Ma from zircons extracted from a tuff lava interbeded within the diamictite of the Tereeken Formation, which suggests an early Ediacaran age for the Tereeken glaciation. Such newly discovered early Ediacaran glaciation in the Tarim region could have induced the negative δ13Ccarb excursions between 625-605 Ma by providing oxygen and other oxidants to invoke remineralization of a deep ocean dissolved organic carbon (DOC) reservoir.

Detrital zircon U-Pb age analysis of Late Pliocene deposits from the lower Yangtze River, South China: Implications for sedimentary provenance and evolution of the Yangtze River
Xu Lin, Chang’an Li, Jing Liu-Zeng, Jovliet Marc, Haijin Liu, Lingling Li, Chengwei Hu, Xiaokang Chen, Jixin Chen
 doi: 10.1007/s12583-023-1961-9
[Abstract](220) [PDF 5297KB](61)
Abstract:
The Yangtze River, with a length of approximately 6,300 km, holds the distinction of being the largest river in East Asia that empties into the Pacific Ocean. Its formation is intricately linked to regional tectonic activity and climate fluctuations. However, the exact timeline for the formation of the Yangtze River remains elusive. This study investigates the provenance of the late Cenozoic strata in the Wangjiang Basin, situated in the lower Yangtze River, through the application of detrital zircon U-Pb dating. A total of seven sand samples were analyzed, leading to the identification of new U-Pb detrital zircon ages (n = 577). Our study reveals that the sand materials found in the Pliocene gravel beds of the Anqing Formation originate predominantly from the Yangtze River. The findings of our study, along with the provenance tracing of boreholes in the Yangtze River Basin and the shelf sea in East China, provide compelling evidence for the continuous presence of the Yangtze River throughout the Pliocene period. The development of the Yangtze River during the Pliocene is intricately connected to both the tectonic adjustments occurring at the southeastern margin of the Tibetan Plateau and the intensification of the Asian Monsoon.
Application of Synthetic Iron Oxyhydroxide with Influencing Factors for Removal of As(V) and As(III) from Groundwater
Shakeel Ahmed Talpur, Muhammad Yousuf Jat Baloch, Chunli Su, Javed Iqbal, Aziz Ahmed, Hafeez Ahmed Talpur
 doi: 10.1007/s12583-023-1862-y
[Abstract](494) [PDF 1684KB](25)
Abstract:
Synthesized iron oxyhydroxide was applied for the adsorptive removal of As(V) and As(III) from the aquas media. Additionally, this investigation highlighted the synergistic effect of calcium carbonate in conjunction with iron oxyhydroxide, resulting in enhanced removal efficiency. The experiment was conducted under various conditions: concentration, dosage, pH, agitation, and temperature. Material characterizations such as Brunauer Emmett Teller, X-ray Diffraction, Scanning Electron Microscopy, and Fourier Transform Infrared Spectroscopy were implied to understand adsorption mechanisms. The Langmuir model revealed optimal concentrations for As(V) = 500 μg/L at pH-5 and As(III) = 200 μg/L at pH-7, resulting in 95% and 93% adsorption efficiencies, respectively. Maximum adsorption capacities "qm" were found to be 1266.943 μg/g for As(V) and 1080.241 μg/g for As(III). Freundlich model demonstrated favorable adsorption by indicating "n>1" such as As(V) = 2.542 and As(III) = 2.707; similarly, the speciation factor “RL<1” for both species as As(V) = 0.1 and As(III) = 0.5, respectively. The kinetic study presented a pseudo-second-order model as best fitted, indicating throughout chemisorption processes for removing As(V) and As(III). Furthermore, incorporating calcium carbonate presented a significant leap in the removal efficiency, indicating As(V) from 95% to 98% and As(III) from 93% to 96%, respectively. Our findings offer profound motivation for developing effective and sustainable solutions to tackle arsenic contamination, underscoring the exceptional promise of iron oxyhydroxide in conjunction with calcium carbonate to achieve maximum removal efficiency.
Multi-scale structural geological model and quantification of stability evaluation for a high-steep fractured rock slope
Jia Wang, Wen Zhang, Donghui Chen, Han Yin, Junqi Chen
 doi: 10.1007/s12583-023-1953-9
[Abstract](72) [PDF 20246KB](37)
Abstract:
This study aims to evaluate the stability of a high-steep fractured rock slope on the right bank of Dongcuo River, Southeast Tibetan Plateau by establishing a multi-scale structural geological model. Multi-scale discontinuity information was first identified via the unmanned aerial vehicle photogrammetry. The multi-scale structural geological model for the cross section of the slope was established by multi-scale discontinuity processing. In particular, large-scale discontinuities were directly embedded into the model, medium-scale discontinuities were realized via discrete fracture network simulation technology, and small-scale discontinuities were implicitly considered in the equivalent rock parameter calculation. A staged scheme for searching the shortest paths of the multi-scale structural geological model via Dijkstra's algorithm was established. The searched shortest path with the largest discontinuity persistence passes the most fractures and processes the lowest shear strength, which can represent the critical slip surface (CSS). Three potential CSSs were selected for the quantification of the factor of safety (FOS) using the transfer coefficient method. Modified Jennings' criteria were proposed to estimate the equivalent shear strength of the CSS composed by rock bridges and discontinuities. Finally, FOS is calculated as 3.81, implying that the studied rock slope remains stable
First record of Middle Eocene elephant ancestors' footprints in the Gonjo Basin, East Tibet Plateau
TAHIR Asma, Huazhou Yao, KHAN Junaid, Yangui Li, He Zhao, Yue Yu
 doi: 10.1007/s12583-023-1946-6
[Abstract](63) [PDF 2407KB](23)
Abstract:
It is the first time that the fossil footprints of a group of middle Eocene elephant ancestors have been discovered in the Gonjo Basin, east Tibet Plateau. The Gonjo Formation is attributed to the middle Eocene epoch (U-Pb age = 44.7 ± 1.2 Ma) and consists mainly of purplish-red, medium- to coarse-grained sandstones, siltstones interbedded with mudstones, and conglomerates with sedimentary structures like ripple marks, rip-up clasts, and trough-cross bedding, suggesting fluvial-lacustrine systems. The group of fossil footprints has a characteristic oval-concave shape, and the toe impressions are absent. Some fossil footprints are overstepped with a pockmarked texture resembling Proboscipeda enigmatica. More than 165 fossil footprints of the group are relatively well-preserved with different diameters, which is evidence of highly social behavior and trackmakers of different ages, including calves, juveniles, adolescents, and adults. The size frequency of the fossil footprints enabled us to deduce the body mass, shoulder height, and hip-height distribution of the trackmakers that crossed the east Tibet Plateau 44.7 million years ago. The trackmakers comprised an estimated average hip-height of 111.8 cm, an average shoulder height of 172.8 cm for males/155.9 cm for females, and an average body mass of approximately 1218.1 kg for males/907.8 kg for females. The abundance of fossil footprints reveals that in the middle Eocene epoch, the environment was extraordinarily conducive for the elephant ancestors to live in the East Tibet region.
Investigation of oil content in lacustrine shale-oil systems: Insights from two different pyrolysis
YUPING WU, Chinglin Liu, Fujie Jiang, Tao Hu, Chenxi Zhang, Jiahao Lv, Renda Huang, Meiling Hu, Guanyun Wu, Rizwan Sarwar Awan
 doi: 10.1007/s12583-023-1814-6
[Abstract](916) [PDF 1935KB](67)
Abstract:
This research has investigated the oil content of lacustrine shale-oil systems from the Junggar Basin. Twenty-eight samples are used for different pyrolysis experiments to study the characteristics of shale oil occurrence and the difference between various evaluation methods. Additionally, the factors affecting the physical states of shale oil are discussed. Compared with the standard Rock-Eval, the two-step pyrolysis and multi-step pyrolysis can eliminate the influence of the carryover effect. Therefore, these two types of pyrolysis are used to obtain the total, free, and adsorbed oil yield of the shale. The results demonstrate that the total oil yield acquired by multi-step pyrolysis is quite similar to that obtained by two-step pyrolysis. Both of them can prevent the retained oil yield from being underestimated by more than 50%. However, the free oil yield obtained by multi-step pyrolysis is significantly higher than that obtained by two-step pyrolysis. The multi-step pyrolysis can easily exaggerate the real free oil yield in resource evaluation. Therefore, this article suggests using the two-step pyrolysis to evaluate the characteristics of petroleum in shales. Furthermore, the amount of hydrocarbons within shales is related to organic matter properties. The higher the organic matter richness, the higher the total/adsorbed oil yield within the shale before reaching the adsorption saturation. The better the kerogen type, the higher the amount of liquid hydrocarbons within shales. As the thermal evolution of shales increases, the free oil proportion and the mobility of petroleum increase. This study compared different pyrolysis methods, which provided new insight for obtaining the oil content of shales, a key parameter of shale oil resource evaluation.
Application of unmanned aerial vehicle remote sensing on dangerous rock mass identification and deformation analysis: case study of a high-steep slope in an open pit mine
Wenjie Du, Qian Sheng, Xiaodong Fu, Jian Chen, Jingyu Kang, Xin Pang, Daochun Wan, Wei Yuan
 doi: 10.1007/s12583-023-1813-7
[Abstract](392) [PDF 4237KB](112)
Abstract:
Source identification and deformation analysis of disaster bodies are the main contents of high-steep slope risk assessment, the establishment of high-precision model and the quantification of the fine geometric features of the slope are the prerequisites for the above work. In this study, based on the UAV remote sensing technology in acquiring refined model and quantitative parameters, a semi-automatic dangerous rock identification method based on multi-source data is proposed; In terms of the periodicity UAV-based deformation monitoring, the monitoring accuracy is defined according to the relative accuracy of multi-temporal point cloud. Taking a high-steep slope as research object, the UAV equipped with special sensors was used to obtain multi-source and multi-temporal data, including high-precision DOM and multi-temporal 3D point clouds. The geometric features of the outcrop were extracted and superimposed with DOM images to carry out semi-automatic identification of dangerous rock mass, realizes the closed-loop of identification and accuracy verification; changing detection of multi-temporal 3D point clouds was conducted to capture deformation of slope with centimeter accuracy. The results show that the multi-source data-based semi-automatic dangerous rock identification method can complement each other to improve the efficiency and accuracy of identification, and the UAV-based multi-temporal monitoring can reveal the near real-time deformation state of slopes.
Organic matter occurrence and its effects on pore structure and methane adsorption capacity capacity: A case study of the Niutitang black shale in Guizhou, China
Peng Xia, Fang Hao, Jinqiang Tian, Yong Fu, Chuan Guo, Zhen Yang, Yuliang Mou, Ke Wang
 doi: 10.1007/s12583-022-1688-z
[Abstract](1219) [PDF 5313KB](95)
Abstract:
The black shale samples from the Niutitang Formation in the Yangtze Block were sequentially treated using organic solvent extraction and wet chemical oxidation. The organic matter (OM) in the shales includes physically mobile OM (PmOM), chemically mobile OM (CmOM), and stable OM (StOM). The CmOM has the strongest CH4 adsorption capacity because it has the largest volume of micropores and mesopores. In contrast, the PmOM has a very negative effect on the CH4 adsorption because it is poreless. The XD shale is a siliceous shale, in which the quartz particles wrap partly OM, preventing extraction and oxidation. The SL shale is an argillaceous shale, in which most of the OM is combined with clay minerals to form organo-clay composites. In both the SL and XD shales, the OM that is extractable via organic solvents is distributed among the mineral particles and is interconnected. The conceptual model of marine black shale in different environments needs to be perfected in the future because quantitative and qualitative methods should be combined to clarify the relationship between the known OM types (e.g., pyrobitumen, solid bitumen, and solid kerogen) and the OM types identified in this study.
Multivariate statistical analysis of dominating groundwater mineralization and hydrochemical evolution in Gao, northern Mali
TRAORE ADIARATOU, Xumei Mao, Alhousseyni Traore, YAHAYA YAKUBU, Aboubacar Sidibe
 doi: 10.1007/s12583-022-1689-y
[Abstract](224) [PDF 1783KB](38)
Abstract:
Population growth and expanding urbanization have caused persistent shortages and contamination of groundwater resources in Mali, Africa. The increase in groundwater salinity makes it more difficult for residents to obtain drinking water, it is necessary to clarify the causes and control factors of groundwater mineralization in Gao region, northern Mali. Based on the analysis of the hydrochemical composition of groundwater in 24 boreholes, Piper and Schöeller diagrams, principal component analysis (PCA) and hierarchical cluster analysis (HCA) are used to carry out multivariate statistical analysis on the main ions. The results show that the groundwater samples are weakly alkaline, with pH values ranging from 5.83 to 8.40, and the average values of boreholes are 7.50, respectively. The average electrical conductivity (EC) value is 354.4 (µS/cm), and the extreme value is between 124.0 and 1247 (µS/cm). Water is usually mineralized and presents nine types of water phase. The three principal components explain 84.42% of the total variance for 13 parameters. The factor F1 (58.85%), the factor F2 (16.88%) and the factor F3 (8.69%) present for the majority of the total data set. In addition, multivariate statistical analysis confirmed the genetic relationship among aquifers and identified three main clusters. Clustering related to groundwater mineralization (F1), clustering related to oxide reduction and iron enrichment (F2), and clustering of groundwater pollution caused by nitrate and magnesium (F3). We found that agriculture, weathering activities and dissolution of geological materials promote the mineralization of groundwater. Groundwater quality in the Gao region is becoming less and less potable because of increasing salinity.
Spatial and temporal evolution of lithospheric mantle beneath the eastern North China Craton: Constraints from mineral chemistry of peridotite xenoliths from the Miocene Qingyuan basalts and a regional synthesis
Jian-Fang Guo, Qiang Ma, Jianping Zheng, Yuping Su
 doi: 10.1007/s12583-022-1691-4
[Abstract](179) [PDF 5165KB](58)
Abstract:
Mineralogical data are presented for the peridotite xenoliths from Miocene (~19Ma) Qingyuan basalts in the eastern North China Craton (NCC), with the aim of constraining on property of the sub-continental lithospheric mantle (SCLM) beneath the northern Tan-Lu Fault zone (TLFZ) during the Cenozoic. The Qingyuan peridotites are dominated by spinel lherzolites with moderate-Mg# olivines (89.4 to 91.2), suggesting that the regional SCLM is mainly transitional and fertile. Light rare earth element (LREE)-depleted, slightly depleted and enriched clinopyroxenes (Cpx) are identified in different peridotites. Chemical compositions of the LREE-enriched Cpx and the presence of phlogopite suggest that the Qingyuan SCLM has experienced silicate-related metasomatism. The synthesis of available mineral chemical data of the mantle xenoliths across the NCC confirms the SCLM beneath the NCC is highly heterogeneous in time and space. The Mesozoic-Cenozoic SCLM beneath the TLFZ and neighboring regions are more fertile and thinner than that beneath the region away from the fault zone. The fertile and refractory peridotite xenoliths experienced varying degrees of silicate and carbonatite metasomatism, respectively. The spatial-temporal lithospheric mantle heterogeneity in composition, age and thickness suggest that the trans-lithosphere fault zone played an important role in heterogeneous replacement of refractory cratonic lithospheric mantle.
Limitation of the Application of Heat Tracer in Investigating Groundwater and River Interactions under Dynamic Flow Conditions
Mengyan Ge, Rui Ma, Ziyong Sun
 doi: 10.1007/s12583-022-1683-4
[Abstract](149) [PDF 3970KB](25)
Abstract:
The groundwater (GW) in the floodplain riparian area frequently interacts intensely with surface water (SW). Heat as a tracer is one of the hot research fields in investigating GW-SW interactions, and analytical approaches have been proposed for the calculation of exchange flow velocity. However, few studies have considered the effects of very dynamic flow conditions and monitoring instrumentation on the calculation with field measured data. Herein, taking the middle reaches of the Heihe River as the study area, different types of monitoring wells were constructed under the riverbed and near the river, and multiple methods (Darcy’s law, heat tracing, and isotopic mixing methods) were employed to trace the exchanges between the river and groundwater. The results indicate that different methods demonstrate diverse information with obvious unevenly distributed flux along the vertical direction. And the combination of multiple methods has an important role in studying the interaction between GW and SW. Fully screened wells produce intraborehole flow and disturb the heat transport, which is relevant to flow velocity, and further affects the temperature distribution, impacting the temperature-based flow velocity calculation. Dynamic flow conditions aggravate riverbed sediment disturbances, e.g., scour and deposition, and additionally affect the interaction and monitoring data.
Geochemical Modeling of Fluid–Rock Interactions in Shallow buried Carbonate Reservoirs based on the Water Bath Instrument
Jiayi Ma, Anjiang Shen, Shuyun Xie, Min She, Huayun Tang, Emmanuel M. CARRANZA, Tianfu Zhang
 doi: 10.1007/s12583-022-1690-5
[Abstract](165) [PDF 2439KB](25)
Abstract:
Fluid–rock interaction plays a critical function in physical and chemical processes associated with the formation and evolution of oil and gas reservoir space. In the diagenetic stage of shallow burial, the dissolution of carbonate rocks by acidic fluids is conducive to the development of secondary pore space in reservoirs. In contrast, the free drift experiment based on water bath instrument can simulate the dissolution process of carbonate rocks in shallow burial environment effectively. In order to study the shallow burial dissolution mechanism of carbonate rocks in different acid solutions, 14 samples of typical carbonate rocks of Sinian, Cambrian, Ordovician, Permian and Triassic ages in the Tarim and Sichuan Basins, China were used. The dissolution experiments on carbonate rocks in sulfuric acid, acetic acid, hydrochloric acid, silicic acid and carbonic acid at shallow burial temperature (30℃≤T≤90℃) were carried out using a water bath instrument. The PHREEQC software was used to simulate the dissolution of carbonate minerals, in order to compare the results of constant temperature water bath experiment. The results show that acid solutions have significant dissolution effect on shallow burial carbonate rocks when T = 50–60℃, which corresponds to the burial depth of 1500–2000 m in the Tarim Basin and 1110–1480 m in the Sichuan Basin. However, there were obvious differences in the dissolution and reformation of carbonate rocks in different acids. In particular, sulfuric acid solution produced by thermochemical sulfate reduction can significantly promote the dissolution of carbonate rocks, especially dolomitic limestone. Moreover, the dissolution of limestone reservoirs is stronger than that of dolomite reservoirs in shallow burial. The results will provide new insights into the study of dissolution laws and influencing factors of carbonate reservoir space and the evaluation and prediction of carbonate reservoir in China.
Chronology, geochemistry and isotopic compositions of the Cretaceous Zhangjiakou diabase: Magmatic derivation and geodynamic implications
peng li, Dazhao Wang, guanzhong shi
 doi: 10.1007/s12583-022-1684-3
[Abstract](151) [PDF 6259KB](27)
Abstract:
Zircon U–Pb ages, major and trace elements and Sr–Nd–Hf isotope data of the diabase in the Zhangjiakou district were studied to investigate its derivation and tectonic implications. Zircon U–Pb ages indicate that the diabase was emplaced at ~130 Ma or younger, and captured zircons cluster at ~147 Ma, ~240 Ma, ~430 Ma and ~465 Ma. The diabase is characterized by minor variations in SiO2 (49.35–52.10 wt.%), TiO2 (1.65–1.77 wt.%), Al2O3 (17.00–18.26 wt.%), MgO (4.28–4.93 wt.%), CaO (6.69–7.90 wt.%) and Mg# (48–54). It has no significant Eu anomaly and displays enrichment in large ion lithophile elements (Rb, Ba and Sr) and depletion in high field strength elements (Nb, Ta, P and Ti). The diabase exhibits homogeneous Sr ((87Sr/86Sr)i = 0.70606–0.70701) and Nd (εNd(t) =–13.6 to –13.2) isotopic compositions. These features suggest that the parental magma was derived from partial melting of the ancient lower crust, relating to mantle upwelling that triggered by stagnant slabs or lithospheric detachment associated with the westward subduction of the Paleo-Pacific Plate. The Early Paleozoic inherited igneous zircons in the diabase suggest that the northern margin of the North China Craton (NCC) likely underwent southward subduction of the Paleo-Asian Ocean.
Characteristics of connected pores and evaluation of shale oil mobility in the Qianjiang Formation, Qianjiang Sag, Jianghan Basin,China
SUN Zhongliang, LI Zhiming, HE Chencheng, ZHU Feng, SHEN Baojian, LU Longfei
 doi: 10.1007/s12583-022-1699-9
[Abstract](394) [PDF 2527KB](38)
Abstract:
The connectivity of shale pores and the occurrence of movable oil in shales have long been a focus of research. In this paper, samples from Wells BX7 and BYY2 in the Eq34-10 cyclothem of Qianjiang Formation in the Qianjiang Depression, were analyzed. A double mercury injection method was used to distinguish between invalid and effective connected pores. The pore characteristics for occurrence of retained hydrocarbons and movable shale oil were distinguished based on comparison of pore changes in low temperature nitrogen adsorption and high pressure mercury injection experiments before and after extraction and the change in the mercury injection amounts in the pores between two separate mercury injections.. The results show that less than 50% of the total connected pores in the Eq34-10 cyclothem samples are effective. The development of effective connected pores affects the mobility of shale oil but varies with different lithofacies. The main factor limiting shale oil mobility in Well BX7 is the presence of pores with throat sizes less than 15nm. In Well BYY2, residual mercury in injection testing of lamellar dolomitic mudstone facies was mainly concentrated in pores with throats of 10~200 nm, and in bulk argillaceous dolomite facies it was mainly concentrated at 60~300nm. The throats of hydrocarbon-retaining pores can be 5nm or even smaller, but pores with movable shale oil in the well were found to have have throat sizes greater than 40nm. Excluding the influence of differences in wettability, the moveability of shale oil is mainly affected by differences in lithofacies, the degree of pore deformation caused by diagenesis, the complexity of pore structures, and the connectivity of pore throats. Dissolution and reprecipitation of halite also inhibit the mobility of shale oil.
Formation Mechanism of the Paleocene basal conglomerate, southwest Tarim Basin
yong Yue, Jingchun Tian, Chuanyan Huang
 doi: 10.1007/s12583-022-1696-z
[Abstract](146) [PDF 8039KB](20)
Abstract:
Abstract: Most knowledge about the Cretaceous-Paleogene strata in the Tarim Basin is mainly inferred from the outcrops at the basin’s margin,but first time in the basin. The formation mechanism of the Paleocene basal conglomerate was determined using geochemical isotopes of the breccia from well PBX1 in the southwestern Tarim Basin. The results showed that the global K/Pg (i.e., Cretaceous/Paleogene) clay layer boundary was located in the middle of the Paleocene basal conglomerate at the depth of 7066.75m in well PBX1. In the Late Cretaceous, associated with volcanic activities and earthquakes, the caldera in the PBX1 well block formed an annular depression with large elevation differences in response to the Pamir block collision. As a result, the collapsed breccia with storm tide genesis deposited at the periphery and inside of the depression, characterized by syn-sedimentary deformation. During the Paleocene, multiple sets of interbedded carbonate and collapsed breccia deposited in response to multi-phased transient transgression-regression cycles. The transportation of breccia exhibited near-source accumulation/extremely close or in-situ rapid accumulation. The studied region is located in the eastern end of the Tethys Sea, the Late Cretaceous-Early Paleocene breccia is of great significance for reconstructing the paleogeography of the Tarim basin in Tethys. Key words: South-western Tarim;Paleogene system;Breccia;Attribution and genesis
Contrasting behavior for Li-Mg isotopes during subduction: Insights from garnet in the Yardoi schists, Tibet
Xing Li, Yilin Xiao, Olivier Nadeau, Dongyong Li, Haiyang Liu, Zhang Zeming, Zhenhui Hou
 doi: 10.1007/s12583-022-1697-y
[Abstract](224) [PDF 4022KB](66)
Abstract:
It has long been recognized that garnet has the capacity to preserve the trace element and isotopic signature of distinct metamorphic growth zones because of its high closure temperature. Combined with the large size of certain garnet porphyroblast, this allows investigating variations in metamorphic conditions such as pressure, temperature, deviatoric stress, and fluid composition, which occur during subduction-related metamorphism. Here, one garnet porphyroblast of 6 cm diameter was sampled from the Yardoi schists of Tibet, and the major-, trace-, and Li-Mg isotopic compositions of distinct growth zones were determined in situ. The δ7Li values range from +6.0 ‰ to +4.1 ‰ and follow ‘S-shape’ patterns on both sides of the garnet’s core, revealing a two-stage growth process corresponding to the fluid-assisted sequential recrystallization of chlorite and micas during prograde metamorphism. By contrast, once corrected for the overprinting by retrograde metamorphism, the δ26Mg values vary monotonously from -1.73 ‰ in the core to -1.32 ‰ in the outer rim, reflecting a single-step process interpreted to result from increasing temperature and the solid-state recrystallization of chlorite-biotite during prograde metamorphism. This different behavior of Li and Mg isotopes is interpreted to result from the fact that Li is more fluid-mobile than the major element Mg.
Provenance of the southeastern South China Block in the Late Triassic and initiation of Paleo-Pacific subduction: Evidence from detrital zircon U–Pb geochronology
Jintao Kong, zhongjie Xu, Rihui Cheng, Duo Wan
 doi: 10.1007/s12583-022-1694-1
[Abstract](132) [PDF 7438KB](23)
Abstract:
During the late Paleozoic–early Mesozoic era, the sediment transport system and tectonic regime in the southeastern margin of the South China Block (SESCB) all changed, significantly affected by the Paleo-Pacific subduction. This study uses detrital zircon geochronology to discuss the Late Triassic source-to-sink system in the SESCB and provides some references for the Paleo-Pacific subduction process. The paleogeography and similarity of detrital zircon age distribution reveal three sinks in the SESCB during the Late Triassic: 1. the Yangchun–Kaiping–Gaoming area, comprising major age ranges of 260–220, 460–400, and 1,200–800 Ma, which might be sourced from the Yunkai Terrane; 2. the Jiexi–Kanshi–Nanjing area, characterized by the significant age component of 2,000–1,800 Ma, which corresponded to the Wuyi Terrane; 3. the Xinan area, consisting of significant age groups of 290–250 Ma and 380–320 Ma, which might be sourced from the magmatic rocks formed by the Huinan Movement and Paleo-Pacific subduction. The Upper Triassic strata contain many 290–250 Ma zircons, and their trace elements suggested a magmatic arc existed near the SESCB during the 290–250 Ma. Thus, we propose that the Paleo-Pacific subduction might have begun in the Early Permian.
Ore geology, H–O–C isotopes and 40Ar–39Ar dating of the Wutonggou iron deposit, eastern Tianshan, NW China: Implications for the source, timing, and genesis of hydrothermal mineralization in a sedimentary iron deposit
Chun-Long Wang, Yi‑Tian Wang
 doi: 10.1007/s12583-022-1686-1
[Abstract](173) [PDF 6300KB](37)
Abstract:
The Wutonggou iron deposit is located in the well-known iron metallogenic belt in the eastern Tianshan, NW China, and has been regarded as a sedimentary iron deposit. Hydrothermal overprinting could play indispensable roles in the formation of high-grade iron ores in sedimentary iron deposits, thus the nature and evolution of hydrothermal fluids have important implications on the genesis of these deposits. Consequently, an integrated study of ore geology, H–O–C isotopes and 40Ar–39Ar dating, is conducted on the Wutonggou deposit, in order to reveal the features, source, and timing of hydrothermal mineralization. The studied deposit includes two mining sections namely the Jianshan and Wutonggou. The δ18O values of early magnetite from the Jianshan section range from +3.0‰ to +5.8‰ that nearly consistent with classic magmatic magnetite, while increase to 6.3‰–8.0‰ in the late stage. Quartz from the two sections shows comparable H–O isotopic compositions and identical fractionation trends, and is plotted in or periphery to the primary magmatic water area. Calcites from the two sections are broadly similar in carbon and oxygen isotopic compositions, and siderite from the Wutonggou section is plotted in the same region. Thus, comparable stable isotopic compositions and evolution trends indicate similar magmatic fluids contributed hydrothermal iron mineralization in the two mining sections. Moreover, water-rock interactions of varying degrees generated distinct mineralization styles in the Jianshan and Wutonggou sections, and caused the isotopic fractionation in late stages. Biotite extracted from a hydrothermal siderite ore yielded a 40Ar–39Ar plateau age of 299.5 ± 2.0 Ma, indicating the timing of hydrothermal iron mineralization is corresponding to the emplacement of vicinity granitoids. Taken together, the hydrothermal mineralization in the Wutonggou iron deposit was the product of remobilization and upgrading of early sedimentary iron ores, and ore-forming fluids were most probably originated from regional granitic magmatism.
Characteristics and formation analysis of earth fissure in Anren area in Wei River Basin, China
Jianwei Qiao, Zhenjiang Meng, Yuyun Xia, Cong Liu, Quanzhong Lu, Feiyong Wang, Yuanqiang Zhou, Haiyuan Zhao
 doi: 10.1007/s12583-022-1653-x
[Abstract](306) [PDF 3547KB](25)
Abstract:
Since the 1950’s, 212 earth fissures have been discovered in the Wei River Basin. During a field survey in 2016, an additional 48 earth fissures were discovered in Anren area, northeast of the Wei River Basin. The characteristics and formation mechanisms of these fissures were studied through field investigations, measurements, trench excavation, and drilling. On-site investigations indicated that these earth fissures were distributed along a fault-controlled geomorphic boundary. Fissures trended at 60°–80° NE and were divided into five groups. Trenches revealed multiple secondary fissures, exposing severe soil ruptures in the shallow earth surfaces. Drilling profiles revealed that earth fissures dislocated several strata, and resembled synsedimentary faults. Seismic reflection profiles revealed buried faults beneath the earth fissures. The Anren area fissures formed in the following three stages: regional extension that initially generated multiple buried faults; seismic activity rupturing multiple strata, resulting in multiple buried fractures; and finally, erosion processes that propagated the buried fractures to the surface, forming the current earth fissures.
Geochronology and geochemistry of Permian Dashizhai Basin in Xing’an–Inner Mongolia Orogen: Implications for the evolution of the Paleo-Asian Ocean
Chi Zhang, Guosheng Wang, Zhiguang Zhou, Shen Gao, Neng Zhang, Liudong Wang, Erqiang Bo
 doi: 10.1007/s12583-022-1651-z
[Abstract](160) [PDF 21807KB](29)
Abstract:
The Xing’an–Inner Mongolia Orogen is a critical tectonic unit for constraining the evolution of the Paleo-Asian Ocean. However, the location and time for the closure of the Paleo-Asian Ocean are still debated. Here, we select a representative basin in Dashizhai in northeastern China, using U-Pb zircon geochronology and geochemistry to analyze the sedimentary facies, depositional ages, and provenance. The results show that the age of the Dashizhai Formation range from 400 to 347 Ma, the Shoushangou Formation range from 400 to 348 Ma, the Zhesi Formation range from 307 to 252 Ma, and the Linxi Formation range from 299 to 241 Ma. The Dashizhai Formation is composed of metamorphic andesite and clastic rocks. The Shoushangou Formation comprises siltstone, rhyolite, and argillaceous siltstone. The Zhesi and Linxi Formations are composed of mudstone and argillaceous siltstone. Geochemical data shows that these rocks are enriched in light rare earth elements and depleted in Eu with various La/Sc, Th/Sc, and La/Co ratios. The Permian Dashizhai Basin is from Permian volcanic and felsic igneous rocks from the Ergun, Xing’an, and Songliao blocks. The absence of the Late Carboniferous strata in the Dashizhai Basin indicates an extension setting during this period. Furthermore, we suggest the Xing’an–Inner Mongolia Orogen was an uplifting process associated with evolution the Paleo-Asian Ocean during the Late Permian.
Effect of Reclamation on the Groundwater-Lake Water Interaction in Chen Lake
Kun Lei, Teng Ma, Liu Chen, Zhen Li, Yu Chen
 doi: 10.1007/s12583-022-1652-y
[Abstract](142) [PDF 3200KB](30)
Abstract:
Chen Lake has been seriously modified by reclamation to expand the residential and agricultural area. Lake reclamation can decrease water quantity, cause water quality problems, and degrade water ecological function. To clarify the interaction between groundwater and lake water influenced by reclamation, water level and hydrochemical characteristics of five groundwater nests and three lake sites were monitored. Results emphasize that the seasonal fluctuations of lake water level is an important factor for both recharge and maintaining groundwater levels in study area. Groundwater in reclaimed farmland have seasonal patterns following lake water with a lag time. Noteworthy, the lag time of porewater in reclaimed farmland is one month longer than confined water. HCA showed that lake water and groundwater samples in same cluster were characterized by high δD, δ18O, Cl- and K+, suggesting the provision of lake to groundwater systems and the transfer of chemical signature. Other Cluster was dominated by reclaimed farmland groundwater samples and enriched in Ca2+, HCO3-, Si. This finding interpreting that water-rock interaction is the predominant process in reclaimed farmland. As a result, there is a high degree of connectivity between lake water and underlying groundwater. However, porewater hydrodynamic conditions gradually weaken and groundwater recharge in reclaimed farmland is modified after large-scale reclamation.
3D Distinct Element Back Analysis Based on Rock Structure Modelling of SfM Point Clouds: The Case of the 2019 Pinglu Rockfall of Kaili, China
Zhen Ye, Qiang Xu, Qian Liu, Xiujun Dong, Feng Pu
 doi: 10.1007/s12583-022-1667-4
[Abstract](158) [PDF 9435KB](25)
Abstract:
This paper introduces the use of point cloud processing for extracting 3D rock structure and the 3DEC -related reconstruction of slope failure, based on a case study of the 2019 Pinglu rockfall. The basic processing procedure involves: (1) computing the point normal for HSV-rendering of point cloud; (2) automatically clustering the discontinuity sets; (3) extracting the set-based point clouds; (4) estimating of set-based mean orientation, spacing, and persistence; (5) identifying the block-forming arrays of discontinuity sets for the assessment of stability. The effectiveness of our rock structure processing has been proved by 3D distinct element back analysis. The results show that SfM modelling and rock structure computing provides enormous cost, time and safety incentives in standard engineering practice.
Late Miocene elevated horizontal karst caves and landform evolution as a response to tectonic uplift along with regional integration of fluvial drainage in Southwestern China
Min Zhai, Xinggong Kong, Yuanhai Zhang, Philip Rowsell, Zhijun Zhao, Baojian Huang, Jing Zhang
 doi: 10.1007/s12583-022-1656-7
[Abstract](262) [PDF 14363KB](21)
Abstract:
In Southwestern China, the development of karst landforms and the planation surfaces is closely related to local tectonics, fluvial incision and base level change, as well as climate change. While researches on when these karst landforms and planation surfaces formed and how they evolved along drainage development are scarce. Fortunately, horizontal caves with numerous fluvial deposits in high karst mountains can be used as time markers in landform evolution. Here we select large horizontal caves to perform studies of geomorphology, sedimentology and geochronology. Field work shows that more than 25 km long horizontal cave passages are perched 1500 m higher than the local base level, but filled with several phases of fluvial sediments and breakdown slabs. The first phase of fluvial gravels and related cave drainage were dated back to 6.4 Ma using cosmogenic nuclide burial dating, and the stalagmite covering the cave collapse was dated by the U-Pb method , older than 1.56 Ma. These results show that the continuous horizontal cave drainage system and the planation surface were developed prior to the Late Miocene. The lowering process of the base level as a result of the sharp fluvial incision and water level lowering, along with the regional uplift, led to the abandonment of the horizontal cave and the elevated planation surface at the Late Miocene . After that, the phase of cave collapse , thick fluvial sand and clay sediments in the caves from the recharge of the cave deposited at around 1.6 Ma and during the Middle Pleistocene, respectively. Subsequently, speleothems widely deposited on the collapse and clay sediment during the period from 600 to 90 ka ,whereas the deposition of cave fluvial sediments terminated suddenly. The tectonic could control the denudation of surface caprock and the development of karst conduits prior to the Late Miocene, whereas the river incision acted as the main driver for the base level lowering and the destruction of the horizontal cave drainage at high altitude. In addition, the rapid incision and the retreat of Silurian gorges finally caused the formation of karst mesa in the Middle Pleistocene.
Source-to-sink relationships between the Qaidam Basin (North Tibet) and its surrounding mountain ranges: New insights from detrital zircon U–Pb ages in modern river sediments
Xu Zhang, Bowen Song, Tinglu Yang, Yafei Hou, Yibo Yang, Keke Ai, Jiaxuan Wang, Zhang Kexin
 doi: 10.1007/s12583-022-1666-5
[Abstract](264) [PDF 7269KB](48)
Abstract:
The Cenozoic source-to-sink history of the Qaidam Basin is crucial for understanding of the basin-filling architecture, mountain-building processes and even the dynamics of the Tibetan plateau growth. However, the provenance history of Cenozoic strata in the Qaidam Basin remains ambiguous, especially in the northern Qaidam Basin. This controversy highlights the importance of obtaining the spatial source-to-sink relationships between the Qaidam Basin and its surrounding mountain ranges. In this study, we investigated the detrital zircon U–Pb ages of modern fluvial systems draining the Eastern Kunlun Shan. Their detrital zircon age distributions fall into five age groups: 300-190, 530-360, 1000-560, 2000-1100 and 2650-2000 Ma. The dominant age groups are 530-360 and 300-190 Ma, which represent the successive subduction of the Proto-Tethys and Paleo-Tethys Oceans and the subsequent continental collisions, respectively. Combining these new detrital zircon U–Pb ages with available age datasets, we finally obtained complete detrital zircon age information for modern fluvial systems in the whole Qaidam Basin. The U–Pb age distributions of modern river sands reveal that the zircon age signature of basement rocks in the Eastern Kunlun Shan is significantly different from that in the South Qilian Shan but is similar to that in the Altyn Tagh Shan. Moreover, these zircon age observations were confirmed by the significant difference in the Nd isotopic signature of modern river sands, which reveals a significant difference between the Eastern Kunlun Shan and South Qilian Shan in the formation and evolution process.
Karst trough control of solute transport processes at two karst groundwater flow systems, Western Hubei, Central China
Yi'an Wang, Ruichao Zhao, Lin Ding, Shuai Xiong, Yin Li, Jianwei Bu, Wei Chen, Hong Zhou, Wei Liu
 doi: 10.1007/s12583-022-1665-6
[Abstract](328) [PDF 3313KB](66)
Abstract:
To investigate groundwater flow and solute transport characteristics of the karst trough zone in China, tracer experiments were conducted at two adjacent typical karst groundwater flow systems (Yuquandong (YQD) and Migongquan (MGQ)) in Sixi valley, western Hubei, China. High-resolution continuous monitoring was utilized to obtain breakthrough curves (BTCs), which were then analyzed using the multi-dispersion model (MDM) and the two-region nonequilibrium model (2RNE) with basic parameters calculated by CXTFIT and QTRACER2. Results showed that: (1) YQD flow system had a complex infiltration matrix with overland flow, conduit flow and fracture flow, while the MGQ flow system was dominated by conduit flow with fast flow transport velocity, but also small amount of fracture flow there; (2) they were well fitted based on the MDM (R2=0.928) and 2RNE (R2=0.947) models, indicating that they had strong adaptability in the karst trough zone; (3) conceptual models for YQD and MGQ groundwater systems were generalized. In YQD system, the solute was transported via overland flow during intense rainfall, while some infiltrated down into fissures and conduits. In MGQ system, most were directly transported to spring outlet in the fissure-conduit network.
Physical prediction model of compound hydrodynamic unload-load response ratio and its application in reservoir colluvium landslide
Lu Guo, Keqiang HE, Honghua Liu, Fandi Meng, Xuchun Wang
 doi: 10.1007/s12583-022-1662-9
[Abstract](112) [PDF 1406KB](14)
Abstract:
It is well known that the deformation and damage of reservoir colluvium landslides are often determined by the combined dynamics of reservoir water level change and rainfall. Based on the systematic analysis of the change law of reservoir water level, rainfall and displacements of reservoir colluvium landslide, this paper proposes the compound hydrodynamic action of rainfall and reservoir water as the unload-load parameter, and the landslide displacement as the unload-load response parameter. Based on this, a physical prediction model of the compound hydrodynamic unload-load response ratio of reservoir colluvium landslide was established, and the quantitative relationship between the compound hydrodynamic unload-load response ratio and its stability evolution was in-depth analyzed and determined. On the basis of the above research, taking Shuping landslide, a typical hydrodynamic pressure landslide as an example, the unload-load response ratio model is used to systematically evaluate and predict the stability evolution law and the change trend of the landslide under compound hydrodynamic action. The prediction result shows that the variation law of the compound hydrodynamic unload-load response ratio is consistent with the dynamic evolution law of its stability. Therefore, the above studies show that the compound hydrodynamic unload-load response ratio parameter is an effective displacement dynamic evaluation parameter for reservoir colluvium landslides, so it can be used in the prediction of the reservoir colluvium landslides.
Effect of the tectonic inversion on the Source-to-sink system evolution in a lacustrine rift basin, a case study of South Yellow Sea Basin, East China.
Xue Fan, Chao Fu, Shengli Li, Shunli Li
 doi: 10.1007/s12583-022-1664-7
[Abstract](151) [PDF 10495KB](31)
Abstract:
The complex plate collision process led the South Yellow Sea Basin (SYSB) to go through an intensity tectonic inversion during the early Cenozoic, which led to a regional unconformity surface development. As a petroliferous basin, SYSB saw intensity denudation and deposition process, making it hard to characterize their source-to-sink system(S2S), and this study provided a new sight to reveal them quantitatively. According to the seismic interpretation, it was found that two types of tectonic inversion led to the strata shortening process, which was classified according to their difference in planar movements, dip-slip faults, and strike-slip ones. As for dip-slip faults, the inversion structure was primarily formed by the dip-slip movement and many fault-related folds developed, which mainly developed in the North Depression Zone of the SYSB. The strike-slip ones, accompanying developed with some negative flower structures, are dominated in the South Depression Zone of the SYSB. Then, to reveal its source-to-sink system in the tectonic inversion basin, we speculated the sediments’ provenance area and their migration distance, referring to the zircon U-Pb data and heavy mineral assemblage. As for the North Depression Zone, it is shown that fewer distal sediments from the West Sulu Orogenic Belt are infilled, and proximal slump or fan delta are prominently developed during the tectonic inversion stage. The provenance rebuild in the South Depression Zone shows increasing sediments from the proximal area (Central Uplift Zone in SYSB and Wunansha Uplift) and the prograding delta long-axis parallel to these boundary faults during the tectonic inversion stage. Calculations were conducted on the coarse sediments content, faults displacements, catchment relief, sediments migration distance, and discussions about the impact factors to the Source-to-sink system developed in various strata shortening patterns with a statistical method. It was found that, within the dip-slip faults-dominated zone, the volume of the sediment routing system and the ratio of coarse-grained sediments merely has a relationship with the amount of sediment supply and average faults broken displacement. Compared with the strike-slip faults-dominated zone, the source-to-sink system shows a lower level of sandy sediment influx, and its coarse-grained content is mainly determined by the average faults broken displacement.
System reliability analysis of reservoir landslides: Insights from long-term reservoir operation
Kang Liao, Yiping Wu, Fasheng Miao
 doi: 10.1007/s12583-022-1668-3
[Abstract](185) [PDF 4819KB](31)
Abstract:
The reservoir operation awakens numerous landslides with multiple sliding surfaces known as reservoir landslides, and the systematic stability analysis for such landslides is becoming increasingly urgent. Taking the Majiagou landslide as an example, this paper analyses the comprehensive performance of the landslide from a probabilistic point of view. Under a reservoir operation cycle, a series of numerical analyses are carried out to simulate the migration of the seepage field, then the dynamic stability of the landslide is quantified accordingly. Subsequently, the wetting-drying cycles test is used to model the weakening of strength parameters in hydro-fluctuation belt under the long-term reservoir operation. Considering the weakening effect of long-term reservoir operation on the hydro-fluctuation belt, the system reliability is evaluated using the Ditlevsen's bounds. The results suggest that the reservoir operation can affect the stability of the landslide by changing the seepage field. The system failure probability gradually rises as the number of wetting-drying cycles increases. Compared with conventional probabilistic analysis that calculates the failure probability of each sliding surface mechanically, analyzing the landslide in terms of system reliability can effectively narrow the failure probability range, which provides an insightful idea for evaluating the systematic stability of analogous reservoir landslides.
In-situ horizontal extrusion test of herbaceous root–soil with different root types
Fangcui Liu, Shengwen Qi, Shenglin Qi, Xiaokun Hou, Yanrong Li, Guangming Luo, Lei Xue, Xueliang Wang, Juanjuan Sun, Songfeng Guo, Bowen Zheng
 doi: 10.1007/s12583-022-1661-x
[Abstract](224) [PDF 7426KB](34)
Abstract:
The influence of different types of roots on the soil is complex and still remains unclear. Four in-situ extrusion tests were conducted on two types of root systems, namely fibrous and tap root system, for three plants (i.e. Eleusine indica, Potentilla anserine and Artemisia argyi), according to the classification in Botany, and the thrust–displacement curves and failure patterns of different samples were analysed by comparison to fill the aforementioned gap. Results reveal that the roots can reduce the characteristics of soil brittleness and enhance its capability to resist large deformation, and different root types contribute different effects on the strain-hardening behaviour of the root–soil mass. The contribution of the fibrous root system on strength is limited, whilst the tap root system substantially enhances strength and stiffness. Results of failure patterns show that fibrous and tap root systems affect soil solidification and surface cracking reduction. However, the effect of the tap root system depends on the composition of lateral and tap roots: long and rich lateral roots are effective for resisting the creation of cracks, but thick tap roots with few and thin lateral roots may lead to several surface cracks.
Mechanism of interaction between anchored slide-resistant piles and landslides with weak-hard interbedded bedrock:model tests and theoretical interpretation
Guihua Wang, Changdong Li, Xin He, Taijiang Chen, Jie Meng, Wenmin Yao, Yongquan Zhang, HUAWEI ZHANG
 doi: 10.1007/s12583-022-1663-8
[Abstract](293) [PDF 3551KB](19)
Abstract:
Interactions between anchored slide-resistant piles and landslides with weak-hard interbedded bedrock have not yet been systematically studied. Physical models of landslides reinforced by anchored slide-resistant piles are investigated based upon the self-developed testing system. The landslide system evolution with increasing loading force is revealed; the internal force and deformation of anchored slide-resistant piles in weak-hard interbedded bedrock are analyzed. A single anchored pile in weak-hard interbedded bedrock is analyzed theoretically, and an optimized calculation method for the axial force of the anchor cable is proposed. The results show that (1) The landslide system evolves through four stages: creeping, coordinated deformation, uncoordinated deformation, and failure. (2) The thrust sharing ratio of the pile-anchor first increases, then decreases slightly, and finally stabilizes; the maximum thrust sharing ratio is 12.22. (3) The anchoring force provided by weak-hard interbedded bedrock is between those of homogeneous hard and homogeneous weak rocks. The horizontal displacement of the pile in homogeneous hard rock is small, but more thrust is borne by the pile, and vice versa. (4) The theoretical value for a single anchored pile calculated by the optimized method is close to the measured value. These findings provide a scientific basis for landslide control projects in areas with weak-hard interbedded bedrock.
Applications of deep learning in mineral discrimination: a case study of quartz, biotite and K-feldspar from granite
Wei Lou, Dexian zhang
 doi: 10.1007/s12583-022-1672-7
[Abstract](107) [PDF 5838KB](33)
Abstract:
Mineral recognition and discrimination play a significant role in geological study. Intelligent mineral discrimination based on deep learning has the advantages of automation, low cost, less time consuming and low error rate. In this manuscript, characteristics of quartz, biotite and K-feldspar from granite thin sections under cross-polarized light were studied for mineral images intelligent classification by Inception-v3 deep learning convolutional neural network (CNN), and transfer learning method. Dynamic images from multi-angles were employed to enhance the accuracy and reproducibility in the process of mineral discrimination. Test results show that the average discrimination accuracies of quartz, biotite and K-feldspar are 100.00%, 96.88% and 90.63%. Results of this study prove the feasibility and reliability of the application of convolution neural network in mineral images classification. This study could have a significant impact in explorations of complicated mineral intelligent discrimination using deep learning methods and it will provide a new perspective for the development of more professional and practical mineral intelligent discrimination tools.
Origin of burrow-associated dolomites and its reservoir implications: A case study from the Lower-Middle Ordovician carbonates of Tarim Basin (NW China)
Chuan Guo, Daizhao Chen, Yong Fu, Xiqiang Zhou, Cunge Liu
 doi: 10.1007/s12583-022-1673-6
[Abstract](83) [PDF 11140KB](40)
Abstract:
The Yingshan Formation of the Lower-Middle Ordovician in the Tarim Basin (NW China) was mainly deposited in a shallow platform, which was intensely bioturbated with burrows filled with both dolomites and calcites. This study aims to figure out the controls on the dolomitization of burrow infills and the effects on petroleum reservoir quality based on petrographic examination, fluid inclusion microthermometry, and isotopic (C-O-Sr) geochemical analyses. The differentiation of burrow-associated carbonates (dolomites and calcites) was likely controlled by the interactions of sea-level oscillations of variable orders and depositional environments. The burrow-associated dolomites (BADs) were precipitated in a relatively restricted (i.e., lagoon) depositional environment during the lowstand of long-term sea level. In contrast, the burrow-associated calcites (BACs) were formed in a water circulation-improved lagoonal environment during the transgression of long-term sea level. Isotopic geochemical data indicate that the BADs in the Yingshan Formation were formed from slightly saline (i.e., mesosaline to penesaline) seawater, whereas the BACs were precipitated from nearly normal seawater. In addition to the anoxic condition, the presence of marine-sourced organic matter and sulfate-reducing bacteria, and a sufficient supply of dolomitizing fluids enriched in magnesium ions (Mg2+) and their Mg2+ concentration may have played a critical role in the formation of BADs. In the more permeable and disturbed burrow sediments as a result of burrowing, penetrating fluids with higher salinities and higher Mg2+ concentration relative to seawater favored dolomite precipitation. The fluids with seawater-like Mg2+ concentration, however, would lead to calcite precipitation. The progressive dolomitization of these burrowed sediments could have propagated the dolomitizing fronts and extended into ambient limestones, leading to the development of extensive dolomites. This dolomitization process can improve the petrophysical properties (porosity and permeability) and the potential as hydrocarbon reservoirs during the emplacement of hydrocarbons from underlying source rocks of the Cambrian to Lower Ordovician.
U-Pb ages and europium anomalies of detrital zircons from sediments in the West Kunlun Orogenic Belt: implications for the Proto-Tethys Ocean evolution
Yinggang Zhang, Xizhu Yao, Jin Wang, Wenqing Pan, Yongquan Chen, Baoshou Zhang, Tao Yang
 doi: 10.1007/s12583-022-1671-8
[Abstract](308) [PDF 5722KB](47)
Abstract:
The ocean crust remnants of the Proto-Tethys were preserved as the Kudi ophiolites in the West Kunlun Orogenic Belt (WKOB), and its evolutionary history was mainly constructed by research on igneous or metamorphic rocks in the WKOB. Sedimentary rocks in the WKOB received little attention in the past; however, they could provide important constraints on the evolution of the oceanic lithosphere. Here, a series of shales and greywackes found in the Kudi area of WKOB were studied to constrain their depositional ages and explore their significance in the evolution of the Proto-Tethys oceanic crust. U-Pb dating and europium anomaly (Eu/Eu*) were analyzed for detrital zircons from greywackes interlayers, while bulk rare earth elements and yttrium (REY) of the shales were measured. Detrital zircons U-Pb ages yielded a maximum depositional age of 436 Ma for the greywackes and black shales, while the REY distribution patterns of the black shales are similar to those of the Tarim Ordovician Saergan shales. Accordingly, the studied WKOB black shales were deposited in the Proto-Tethys Ocean during the Late Ordovician-Early Silurian period. The maximum depositional age at 436 Ma may represent a minimum closure time of the Proto-Tethys Ocean, which is also supported by the absence of increases in Eu/Eu* values during the Late Ordovician-Early Silurian. Besides, our Eu/Eu* values in detrital zircons indicate diminished orogenesis during the Archean to Mesoproterozoic, subduction-related accretion at the margins of the supercontinent Rodinia during the Neoproterozoic.
Fe-Ti oxide mineralization in the XV intrusion, Bafq mining district, Central Iran: insights from mineralogy, mineral chemistry and S isotopic data
Sakine Amraei, Majid Ghasemi Siani, Mohammad Yazdi, Liang Qiu, Bertrand Moine, Minghua Ren
 doi: 10.1007/s12583-022-1675-4
[Abstract](148) [PDF 5984KB](14)
Abstract:
The mafic-ultramafic intrusion in the XV anomaly area, which contains magmatic Fe-Ti oxide-(P) ore, is located in the Bafq mining district in the Central Iran. It consists of cumulate and layered Fe-Ti-bearing gabbros and pyroxenites. The mineral assemblages include clinopyroxene, Fe-Ti oxides, plagioclase, amphibole, apatite and sulfides (pyrite and chalcopyrite). The Fe-Ti oxides mainly consist of magnetite-titanomagnetite and ilmenite, which occur as disseminated, intergrowth, lamellae (trellis and sandwich textures) and inclusions. Magnetite in the gabbroic rocks is from the near end-member of Fe3O4 (<1 wt. % TiO2) to titanomagnetite containing up to 8 wt. % TiO2 (about 3.73 to 26.84 % Ulvospinel (XUsp)). Magnetite in pyroxenite rocks is characterized with TiO2 range from 0.46 to 3.14 wt. % (XUsp varied from 1.76 to 10.46 %). The abundances of V2O3 range from 0.03 to 1.29 and 0.24 to 1.00 wt. % for gabbro and pyroxenite, respectively. XUsp contents of magnetite show insignificant correlations with Al2O3 and MgO. The average XIlm in the ilmenite of gabbro is 92 %, whereas it is 90.37 % in the pyroxenite rocks. The MgO and V2O3 contents show a slightly positive correlation with TiO2 in ilmenite. The composition of clinopyroxenes in gabbro and pyroxenite rocks fall in the diopside to augite field with Mg# ranging from 67 to 98 and 74 to 96, respectively. In both rock types, amphiboles are mainly pargasite and rarely actinolite. Plagioclase in pyroxenite rocks are clustered in the labradorite to andesine fields with a compositional ranges of An46-69 and in gabboic rocks fall in two fields with compositional ranges of albite with An0.65-5.95 and labradorite with An50-63. The δ 34S isotopic values cover a limited range from +3.15 ‰ to +4.10 ‰ V-CDT consistent with magmatic origin. Fe-Ti mineralization are formed in two stages, minor inclusions of Fe–Ti oxide minerals in the pyroxene and plagioclase crystallized in the early magmatic stage, whereas interstitial oxides formed by fractional crystallization processes that accumulated by gravitational settling in the later stage as intercumulus phase. Gravitational settling process is supported by the observation of decreasing the amount of Fe-Ti oxides from Fe-Ti oxide- rich pyroxenite to weak mineralized gabbro (base to top). The high contents of H2O, phosphorate and high initial Ti-Fe in parental magma are the crucial factors controlling the Fe-Ti oxides enrichment and mineralization.
monitoring multi-temporal changes of lakes on the tibetan plateau using multi-source remote sensing data from 1992 to 2019: a case study of lake zhari namco
juan wu, chang-qing ke, yu cai, zheng duan
 doi: 10.1007/s12583-022-1639-8
[Abstract](211) [PDF 7604KB](15)
Abstract:
lake level, area and volume are sensitive indicators of climate change. at present, many studies have focused on the interannual water balance of lakes, but lake level and area can change remarkably with seasons, especially for lakes with seasonal ice cover. zhari namco, a seasonal frozen lake, was selected as an example to investigate its seasonal water balance. multi-source altimetry and landsat data were used to obtain the seasonal lake level and area from 1992 to 2019, and seasonal lake volume variations were also estimated. the results indicated the average lake level, area and volume in autumn were the largest. the lake level, area, and volume experienced three turning points approximately in 2000, 2010, and 2016, and showed an overall increasing trend from 1992 to 2019, with slopes of 0.15 m/year, 2.17 km2/year, and 0.14 km3/year, respectively. the lake area expanded significantly in autumn, which was related to the abundant precipitation. delay time of land surface runoff, increased temperature, and evaporation may be the reason for the low lake level and volume in summer. the precipitation was the dominant factor of water balance, which explained 62.09%, 62.43%, and 62.10% of the variations in lake level, area, and volume, respectively.
stochastic modeling of folded structures in scarce data scenarios using transiogram with locally varying anisotropy
yabo zhao, weihua hua, guoxiong chen, liang dong, zhipeng liu, xiuguo liu
 doi: 10.1007/s12583-022-1646-9
[Abstract](167) [PDF 3963KB](7)
Abstract:
sampling is usually scarce in geological modeling, and hence, complex and continuous geological phenomena are difficult to simulate when anisotropy changes locally. the current study aimed to present a method for modeling folded structures using transiogram with locally varying anisotropy in scarce data scenarios. based on the direction fields of locally varying anisotropy, a pathline-based algorithm was proposed to simulate the folds that are flattened and calculate the relative position of any two random points thereafter. compared to the traditional two-point spatial continuity measures (such as the variogram), the locally varying anisotropy transiogram could not only describe the high order markovian of the spatial distribution of geological bodies, but also do so with explicable physical implication. the report revealed that the locally varying anisotropy transiogram of horizontal strata can be directly obtained if the stratigraphic sequence and stratum thickness are known. in the case study, only one geological map was used in a real complex-fold area to successfully simulate the 3-d stratigraphic model.
gastropod fauna of the zuodeng permian-triassic boundary section in the nanpanjiang basin and its geometric-based morphological disparity analysis
xin sun, li tian, xincheng qiu, kaiping guan, erik tihelka, haijun song, jinnan tong, hao yang
 doi: 10.1007/s12583-022-1645-x
[Abstract](124) [PDF 4539KB](13)
Abstract:
gastropods, as one of the most common invertebrates in shallow marine environments, were heavily impacted by the permian-triassic mass extinction (ptme), with severe loss of diversity and remarkable dwarfism of body size. here, we report a new gastropod fauna from the permian‒triassic carbonates of zuodeng, guangxi province, south china. five species belonging to five genera and two indeterminate taxa are identified. the zuodeng fauna is dominated by paleozoic holdover taxa, including holopea teres, protostylus sp., and wannerispira shangganensis although most of them are found in the basal triassic microbialites. three gastropod communities have been recognized by cluster analysis. further morphological analyses show that the changing pattern of disparity, with diversity decreasing from community ⅱ to ⅲ, fits the interior-reduction model. in addition, the morphospace of community in microbialites is higher than those in non-microbialite bearing beds at zuodeng, shedding new light on the ecological role of microbialites during the permian-triassic environmental stress.
susceptibility mapping of ground collapse caused by anthropogenic activities
zhongmin mao, yuyong jiao, fei tan, xin qi, cong zeng
 doi: 10.1007/s12583-022-1644-y
[Abstract](107) [PDF 4967KB](3)
Abstract:
frequent ground collapses resulted by anthropogenic activities occur due to rapid urbanization. accurate susceptibility mapping is critical for disaster prevention and control. in this study, 1198 ground collapse cases were collected from 2017 to 2020 in shenzhen. after multicollinearity testing, eight effective factors (elevation, relief, clay proportion, average annual precipitation, distance from water, land use type, building density, and road density) were selected to construct an evaluation index system. ground collapse susceptibility was analyzed and mapped using the normalized frequency ratio (nfr), logistic regression (lr), and nfr-lr coupling models. finally, the rationality and performance of the three models were compared using the frequency ratio (fr) and receiver operating characteristic (roc) curve, respectively. all three models could effectively evaluate the ground collapse susceptibility (area under the roc curve (auc) > 0.7), though the result of nfr-lr model was more rational and had the highest performance (auc = 0.791) among the three models. shenzhen possessed ground collapses mainly in built-up areas, the greater the intensity of anthropogenic activity in a location, the higher the likelihood of a disaster. the high and very high susceptibility zones covered a total area of 546.76 km2 and involved the nanshan, luohu, and futian districts, as well as some areas of the baoan, guangming, and longgang districts.
Protoconodonts and Paraconodonts from the Machari Formation (upper Series 3 and Furongian) in the Eodungol Section, Yeongwol, Korea
Byung-su LEE
[Abstract](309) [PDF 2509KB](32)
Abstract:
The Machari Formation ranges from the “upper Series 3” (Middle Cambrian) to Furongian (Upper Cambrian) in the Yeongwol area, Korea. It has been known to yield relatively diverse invertebrate fossils. Particularly trilobite biozones of the formation have been well defined. On the other hand, little has hitherto been studied on conodont microfossils for the formation. This paper reports a diverse and well preserved protoconodonts and paraconodonts of Series 3 from the formation in the Eodungol section, exposed along a southern mountain trail of Mt. Sambangsan, Yeongwol, Korea. Five of the thirteen samples collected for conodont contain a rich protoconodont and paraconodont assemblage and numerous shelly fossils including trilobites, brachiopods, sponge spicules, hyolithids and incertae sedis. Sample Eo5 is extremely fossiliferous (465 elements, 96.5 % of total collection), and the most abundant species was Phakelodus elongatus (236 elements, 62 % of the Eo5 collection). The preservation is relatively good, but some specimens are corroded and fragmentary. Some of protoconodonts are exfoliated. Relatively larger ones were commonly preserved as phosphatized internal molds, particularly in specimens of Furnishina bigeminata, Furnishina leei n. sp., Muellerodus pomeranensis, Nogamiconus sinensis and westergaardodids. Phakelodids were commonly preserved as clusters. Among twenty species referable to nine genera, Furnishina bigeminata, Furnishina leei n. sp., Nogamiconus sinensis, Huayuanodontus tricornis, Proscandodus obliquus, and Westergaardodina grandidens were previously undescribed species in Korea. This assemblage is named herein as the Westergaardodina matsushitai Zone, which is new biozonal name replacing the old one i.e., Gapparodus bisulcatus-Westergaardodina matsushitai-Westergaardodina moessebergensis Assemblage. The W. matsushitai Zone corresponds to the Lejopyge armata trilobite Zone, and is well correlated with the upper Series 3 conodont biozones of the Westergaardodina matsushitai-Westergaardodina grandidens Zone of South China, and the Westergaardodina matsushitai Zone of North China, respectively. The present data allow a useful correlation to China and Baltica in relation to new subdivision of the Cambrian. Furnishina leei n. sp. is newly described.
Uranium Isotope Variations (234U/238U and 238U/235U) and Behavior of U-Pb Isotope System in the Vershinnoe SandstoneType Uranium Deposit, Vitim Uranium Ore District, Russia
V. N. Golubev, I. V. Chernyshev, B. T. Kochkin, N. N. Tarasov, G. V. Ochirova, A. V. Chugaev
 doi: doi.org/10.1007/s12583-021-1436-9
[Abstract](29) [PDF 5507KB](17)
Abstract:
The U-Pb isotope system and uranium isotope composition (235U/238U and 234U/238U) were studied in a number of samples from the vertical section of the uranium ore body at the Vershinnoe sandstone-type deposit, Vitim uranium ore district, Russia. These parameters were determined to broadly vary. Deviations of the 234U/238U ratio from the equilibrium value indicate that the uranium ore was not completely conserved during the postore stage, and uranium was determined to continue mi‐grating at the deposit. Comparison of the U-Pb isotope age value and 234U/238U isotope ratio provides an insight into the migrate direction of uranium in the ore body. The broad variations (137.377–137.772) in the 238U/235U ratio over the vertical section of the ore body can be explained by the different settings of the samples relative to the ore deposition front and changes in the redox conditions when this front shifted. The fact that the δ238U and K234/238 values are correlated indicates that the transfer of the 234U iso‐tope into the aqueous phase may have been coupled with isotope fractionation in the 238U-235U system during the postformation uranium migration within the orebody.
Association of Sandstone-Type Uranium Mineralization in the Northern China with Tectonic Movements and Hydrocarbons
Yin Chen, Peisen Miao, Jianguo Li, Ruoshi Jin, Hualei Zhao, Lulu Chen, CongWang, Haoyu Yu, Xiaoru Zhang
 doi: doi.org/10.1007/s12583-021-1493-0
[Abstract](77) [PDF 50719KB](27)
Abstract:
In the continental basins of Northern China (NC), a series of energy resources commonly co-exist in the same basin. As the three typical superimposed basins of different genesis in the NC, the Junggar, Ordos, and Songliao basins were chosen as the research objects. The favorable uraniumbearing structures are generally shown as a basin-margin slope or transition belt of uplifts with the de‐velopment of faults, which are conducive to a fluid circulation system. The Hercynian, Indosinian, and Yanshanian movements resulted in the development of uranium-rich intrusions which acted as the sig‐nificant uranium sources. The main hydrocarbon source rocks are developed in the Carboniferous, Permian, Jurassic and Cretaceous. The mature stage of source rocks is concentrated in the Jurassic–Cretaceous, followed by the multi-stage expulsion events. Influenced by the India-Eurasian collision and the subduction of the Pacific Plate, the tectonic transformation in the Late Yanshanian and Himala‐yan periods significantly influenced the sandstone-type uranium mineralization. The hydrocarbon reser‐voirs are spatially consistent with sandstone-type uranium deposits, while the hydrocarbon expulsionevents occur in sequence with sandstone-type uranium mineralization. In the periphery of the faults or the uplifts, both fluids met and formed uranium concentration. The regional tectonic movements moti‐vate the migration of hydrocarbon fluids and uranium mineralization, especially the Himalayan move‐ment.
An investigation of dislocation in olivine phenocrysts from the Hawaiian basalts
Zhuo-Yue Li, Da-Peng Wen, Yong-Feng Wang, Xiang-Wen Liu
 doi: 10.1007/s12583-020-1030-6
[Abstract](2065) [PDF 7048KB](158)
Abstract:
Intracrystalline distortions (like undulose extinction, dislocations, and subgrain boundaries) in olivine from naturally-deformed peridotites is generally taken as a sign of dislocation creep. However, similar features in olivine phenocrysts that were found in basaltic magmas are still not well understood. In particular, whether subgrain boundaries in olivine phenocrysts arise from plastic deformation or grain growth is still debated (In the latter case, they are essentially grain boundaries but not subgrain boundaries. Therefore, we used hereinafter subgrain-boundary-like structures instead of subgrain boundaries to name this kind of intracrystalline distortion). Here we carried out a detailed study on dislocations and subgrain-boundary-like (SG-like) structures in olivine phenocrysts from two Hawaiian basaltic lavas by means of petrographic microscopy, scanning electron microscopy, and transmission electron microscopy (TEM). Abundant and complex dislocation substructures (free dislocations, dislocation walls, and dislocation tangles) were observed in the decorated olivine grains, similar to those in olivine from peridotite xenoliths entrained by the Hawaiian basalts. The measured average dislocation density is 2.9 ± 1.3 × 1011 m-2, and is three to five orders of magnitude higher than that in laboratory-synthesized, undeformed olivine. TEM observations on samples cut across the SG-like structures by FIB (focused ion beam) demonstrated that this kind of structures is made of an array of dislocations. These observations clearly indicate that these structures are real subgrain boundaries rather than grain boundaries. These facts suggested that the observed high dislocation densities and subgrain boundaries were not resulted from crystal crystallization/growth, but were formed by plastic deformation. These deformation features do not prove that the olivine phenocrysts (and implicitly mantle xenoliths) were deformed after their capture by the basaltic magmas, but can be ascribed to a former deformation event in a dunitic cumulate, which was formed by magmatic fractionation, then plastically deformed, and finally disaggregated and captured by the basaltic magma that brought them to the surface.
Central Asia––A Global Model for the Formation of Epigenetic Deposits in a Platform Sedimentary Cover
Igor Pechenkin, Vladislav Petrov
 doi: doi.org/10.1007/s12583-021-1581-1
[Abstract](11) [PDF 8469KB](7)
Abstract:
Metallogenic specialization of sedimentary cover in Central Asia is determined by its tec‐tonic setting that governs the hydrodynamic regime (exfiltrational or infiltrational) and as a consequence, the hydrogeochemical zonality (type of water and its gaseous and microcomponent composition). Hydro‐dynamic conditions (distribution of recharge and discharge areas) determine the direction of stratal water flow and location of mineralization resulted from the change in geochemical, thermodynamic, litholog‐ical, structural and other conditions. The exfiltrational regime suggests a dependence of the epigenetic mineralization upon the distribution and degree of preservation of hydrocarbon occurrences. Often, hy‐drocarbon matter serves as a reducing barrier and ore-concentrating factor during the formation of polymineral concentrations related to stratal oxidation zone. The supergene epigenetic ore-forming pro‐cesses are induced by the interaction between the Earth’s sedimentary cover and hydrosphere. Sedimen‐tary rocks themselves commonly serve as a source of ore materials. The ore deposition zones on geochemi‐cal barriers and ore material source are often located significantly apart from each other. The trend of these processes is determined by the position of ore-bearing depressions in large tectonic blocks.
Theoretical System of Sandstone-Type Uranium Deposits in Northern China
Ruoshi Jin, Huajian Liu, Xiaoguang Li
 doi: doi.org/10.1007/s12583-021-1449-4
[Abstract](56) [PDF 19090KB](18)
Abstract:
Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented. From the source sink system of uranium-producing basins, sedimentary environment of uranium-bearing rock series, ore-forming fluid information, evolution of tectonic events, basin forma‐tion and development, we redefine and classify uranium orebodies, redox zoning, and ore-controlling structural styles. We then systematically propose a theoretical system of sandstone-type uranium depos‐its in northern China. We conclude that sandstone-type uranium deposits in northern China are main‐ly found in sedimentary environments such as rivers, deltas, and alluvial fans in the Mesozoic and Cenozoic lowstand systems tract and in gray sandstone layers in the vertical redox zoning. The orebodies are controlled by the tectonic slope belt, which is in the shape of a strip on the plane, and spreads in a layer or plate on the section. Vertical (ups and downs) tectonic movement triggers large-scale phreatic flow in the basin, which is the real driving force for controlling the ore-forming fluid. The theoretical system of sandstone-type uranium deposits in northern China should be based on global tectonic move‐ment and environmental changes and take into account factors such as basins as a unit to study miner‐alization background, ore concentration areas as objects to study mineralization, and the correlation between regional tectonic movement and metallogenic process as a breakthrough point to study tecton‐ic events and metallogenic events. It should also be based on different basin types to establish metallo‐genic models. The innovative research results and ideas are summarized with the aim of promoting the continuous improvement of sandstone-type uranium mineralization theory in northern China.
U-Blacks Mineralization in Sandstone Uranium Deposits
Olga A. Doynikova
 doi: doi.org/10.1007/s12583-021-1451-x
[Abstract](20) [PDF 18000KB](13)
Abstract:
Ores of infiltration sandstone-hosted uranium deposits in the sedimentary cover are ubiquitous composed of dispersed soot powder mineralization of black, brownish-black colour. Longterm studies of such loose U-ores by analytical transmission electron microscopy (ATEM) proved their polymineral nature. Uranium blacks are composed by at least three different U-mineral forms: oxide (uraninite), silicate (coffinite) and phosphate (ningyoite) which are present in various proportions of ore compositions. Such high dispersed friable uranium formations are difficult to diagnose by tradition‐al mineralogical methods (optical, XRD, IR and X-ray spectroscopy, etc.) which analyze total sample composition (phases mixture); their results characterize the dominant sample phase, omitting both sharply subordinate and X-ray amorphous phases. All research results are based on ATEM methods (SAED+EDS), which are optimal for crystallochemical diagnostics in the mineralogical study of such uranium ores. The article presents the diagnostic characteristics under electron microscope (EM) of uranous minerals from different sandstone deposits with their origin being discussed.
Classification of Sandstone-Related Uranium Deposits
Michel Cuney, Julien Mercadier, Christophe Bonnetti
 doi: doi.org/10.1007/s12583-021-1532-x
[Abstract](108) [PDF 1583KB](26)
Abstract:
Sandstone type deposits are the most common type of uranium deposits in the world. A large variety of sub-types have been defined, based either on the morphology of the deposits (e.g., tabu‐lar, roll front, etc), or on the sedimentological setting (e.g., paleovalley, paleochannel, unconformity), or on tectonic or lithologic controls (e.g., tectonolithologic, mafic dykes/sills), or still on a variety of others characteristics (phreatic oxidation type, interlayer permeable type, multi-element stratabound infiltra‐tional, solution front limb deposit, humate type, etc.), reflecting the diversity of the characteristics of these deposits, but making it difficult to have a clear overview of these deposits. Moreover, uranium de‐posits occurring in the same sedimentological setting (e.g., paleochannel), presenting similar morpholo‐gies (e.g., tabular), may result from different genetic mechanisms and thus can be misleading for explora‐tion strategies. The aim of the present paper is to propose a new view on sandstone-related uranium de-posits combining both genetic and descriptive criteria. The dual view is indeed of primordial importance because all the critical characteristics of each deposit type, not limited to the morphology/geometry of the ore bodies and their relationships with depositional environments of the sandstone, have to be taken into account to propose a comprehensive classification of uranium deposits. In this respect, several key ore-forming processes, like the physical-chemical characteristics of the mineralizing fluid, have to be used to integrate genetic aspects in the classification. Although a succession of concentration steps, potentially temporally-disconnected, are involved in the genesis of some uranium mineralization, the classification here proposed will focus on the main mechanisms responsible for the formation and/or the location of ore deposits. The objective of this paper is also to propose a robust and widely usable ter‐minology to define and categorize sandstone uranium deposits, considering the diversity of their origin and morphologies, and will be primarily based on the temperature of the mineralizing fluid considered as having played the critical role in the transportation of the uranium, starting from synsedimentary ura‐nium deposits to those related to higher temperature fluids.
COVER
2024, 35(2): .  
[Abstract](11) [PDF 75KB](20)
Abstract:
CONTENTS
2024, 35(2): .  
[Abstract](15) [PDF 101KB](20)
Abstract:
Stratigraphy and Sedimentology
Early Triassic Legoupil Formation in Schmidt Peninsula, Antarctic Peninsula: Provenance and Depositional Settings
Chao Zhang, Ying-Chun Cui, Chen-Guang Liu, Fang-Hua Cui, Lu-Yuan Wang, Wei-Qiang Zhang
2024, 35(2): 317-331.   doi: 10.1007/s12583-021-1601-1
[Abstract](23) [FullText HTML](23) [PDF 14895KB](26)
Abstract:

Geochemical compositions can be used to determine the tectonic setting of sedimentary basins, while where the link of source to sink is no longer preserved, detrital zircon age patterns can aid in resolving the original basin setting. The metasedimentary Legoupil Formation, located at Cape Legoupil and the Schmidt Peninsula, could give a hint for the tectonic evolution of Antarctic Peninsula. In this contribution, we constrain the sedimentary provenance of the Legoupil Formation through geochemistry and detrital zircon U-Pb geochronology. The petrography and geochemical features indicate that the provenance of the Legoupil Formation could be felsic rocks. Detrital zircon grains record a steady supply of Permian and Ordovician material into the Legoupil Formation. The youngest concordant zircon ages of 262 Ma suggest that the depositional time of Legoupil Formation is no older than Late Permian. The detrital zircon age spectrum of Legoupil Formation suggests that the Legoupil Formation sediments should be derived from regional sources endemic to western Gondwana prior to its breakup. Together with the previous studies, geochemistry and detrital zircons reflect an active continental margin tectonic setting and the detrital zircon spectra of Legoupil Formation are similar to the ones deposited in forearc tectonic setting.

Depositional and Bio-Sequence Stratigraphic Framework of Late Cretaceous Kawagarh Formation, Kala-Chitta Range, Pakistan: Equivalent of Gurpi Formation (Iran)
Muhammad Awais, Bilal Wadood, Muhammad Ishaq, Muhammad Bilal, Zeeshan Zafar, Nasar Khan, Aminullah Khan
2024, 35(2): 332-348.   doi: 10.1007/s12583-022-1703-4
[Abstract](14) [FullText HTML](14) [PDF 2102KB](16)
Abstract:

The present study is focused on evaluation of deep marine pelagic sediments of Late Cretaceous Kawagarh Formation of Kala-Chitta Range in the context of microfacies analysis, paleoenvironmental interpretation, planktonic foraminiferal biostratigraphy, sequence stratigraphy and diversification of species. A total of thirty three rock samples were collected from the measured section. Three microfacies are interpreted, namely planktonic foraminifera wackestone, planktonic foraminifera mudstone and sandy mudstone indicating low energy depositional environment i.e., outer ramp. The biostratigraphic studies show plentiful planktonic foraminifera species of Globotruncana, Heterohelix and Globotruncanita. However, no association of benthic or siliceous organisms was observed. On the basis of available species assemblage, a single local planktonic foraminifera biozone i.e., Globotruncana-Heterohelix-Globotruncanita Assemblage Biozone is established. The biozone information is combined with published literature and Lower Santonian to Middle Maastrichtian age has been assigned to the Kawagarh Formation. The trend of species occurrences evinces that species number decreases over time with pulsated rise in the Kawagarh Formation. The Kawagarh Formation carbonates show an overall Transgressive Systems Tract (TST). The Kawagarh Formation of Pakistan evinces analogous characteristics to that of the Late Cretaceous Gurpi Formation of Iran based on the geologic age, outcrop lithology, microfacies, planktonic foraminiferal assemblages, depositional setting and sequence stratigraphy.

Multi-Elemental Chemostratigraphy, Sequence Development, Depositional History, and Environmental Importance of Early Eocene Red Beds (Kuldana Formation) in NW Himalayas, Pakistan
Amir Shahzad, George Kontakiotis, Thierry Adatte, Khawaja Shoaib Ahmed, Muhammad Tayyib Riaz, Hammad Tariq Janjuhah, Evangelia Besiou
2024, 35(2): 349-375.   doi: 10.1007/s12583-023-1860-6
[Abstract](20) [FullText HTML](20) [PDF 20787KB](23)
Abstract:

The Eocene Kuldana Formation (KF) in the Yadgar area of Pakistan, comprises a diverse range of sedimentary facies, including variegated red beds of shales, mudstones, and sandstones, as well as interbedded limestone and marl. In this study, we conducted an integrated micropaleontological, sedimentological, mineralogical, and geochemical investigation to determine the depositional setting, biochronology, provenance, and paleoclimate of the KF. The study identified six lithofacies and six microfacies, which indicate a variety of environments ranging from floodplains and channels to the margins and shallow marine settings. The nannofossil biostratigraphy places the KF in the Early Eocene, more precisely the NP10 zone (Ypresian), and the fossil zone of benthic foraminifera classifies the study section as the Shallow Benthic Zone SBZ-8 (Middle Ilerdian 2). In terms of petrography, the KF sandstone was classified as litharenite and feldspathic litharenite, while the QtFL diagram suggests a recycled orogen. Geochemical proxies indicate an oxidizing environment, a high-to-low regular sedimentation rate, moderate-to-intense chemical weathering in the source region, and a warm-humid to dry climate during the deposition of KF. Overall, the findings suggest that the deposition of KF marks the end of Neo-Tethys due to the Early Eocene Indian–Kohistan collision and that the uplifting of the Himalayas provided the source for the deposition of KF in the foreland basin. The study provides new insights into the depositional environment, biochronology, provenance, and paleoclimate of KF, and highlights the potential for red beds as reliable indicators of oxygenation levels in proximity to mineral deposits.

Structural Geology and Geochemistry
Structural Geology and Chronology of Shear Zones along the Shangdan Suture in Qinling Orogenic Belt, China: Implications for Late Mesozoic Intra-Continental Deformation of East Asia
Falak Sheir, Wei Li, Le Zhang, Basil Alabowsh, Liuqing Jiang, Li Liang, Sainan Gao, Shair Baz, Umar Ashraf
2024, 35(2): 376-393.   doi: 10.1007/s12583-022-1753-7
[Abstract](25) [FullText HTML](25) [PDF 48231KB](2)
Abstract:

The Shangdan suture zone (SDZ) in the Qinling orogenic belt (QOB) is a key to understanding the East Asia tectonic evolution. The SDZ gives information about convergent processes between the North China Block (NCB) and South China Block (SCB). In the Late Mesozoic, several shear zones evolved along the SDZ boundary that helps us comprehend the collisional deformation between the NCB and SCB, which was neglected in previous studies. These shear zones play an essential role in the tectonic evolution of the East Asia continents. This study focuses on the deformation and geochronology of two shear zones distributed along the SDZ, identified in the Shaliangzi and Maanqiao areas. The shear sense indicators and kinematic vorticity numbers (0.54–0.90) suggest these shear zones have sinistral shear and sub-simple shear deformation kinematics. The quartz's dynamic recrystallization and c-axis fabric analysis in the Maanqiao shear zone (MSZ) revealed that the MSZ experienced deformation under green-schist facies conditions at ∼400–500 ℃. The Shaliangzi shear zone deformed under amphibolite facies at ~500–700 ℃. The 40Ar/39Ar (muscovite-biotite) dating of samples provided a plateau age of 121–123 Ma. Together with previously published data, our results concluded that QOB was dominated by compressional tectonics during the Late Early Cretaceous. Moreover, we suggested that the Siberian Block moved back to the south and Lhasa-Qiantang-Indochina Block to the north, which promoted intra-continental compressional tectonics.

Latest Carboniferous–Early Permian Rifting of the Northern Gondwanan Margin and the Opening of the Northern Neotethys: New Evidence from the Carboniferous and Permian Foraminiferal Assemblages from the Beyşehir-Hoyran Nappes, Central Taurides (Southern Turkey)
Cengiz Okuyucu, U. Kagan Tekin, Cagri Guzgun, Kaan Sayit
2024, 35(2): 394-415.   doi: 10.1007/s12583-022-1759-1
[Abstract](30) [FullText HTML](31) [PDF 23911KB](13)
Abstract:

The Beyşehir-Hoyran Nappes, one of the tectonostratigraphic units of the Taurides, are thought to be originated from the Izmir-Ankara Ocean (northern branch of Neotethys). In this study, Late Paleozoic rock units from the blocks of Beyşehir-Hoyran Nappes were studied in detail using foraminiferal assemblages in two different locations from the southwest of Karaman City (southern Turkey). In both places, blocks/slices and pebbles of various origins are embedded within a highly sheared matrix of Late Cretaceous Age, and the whole unit can be regarded as a sedimentary mélange. The ages of the blocks from the southwest of Karaman City range from the Late Serpukhovian (Late Mississippian) to Late Capitanian (Middle Permian) with some depositional breaks (e.g., Bashkirian, Kasimovian). Combined with the previous data from the Mersin Mélange, which also include the remnants of the Beyşehir-Hoyran Nappes, our new findings suggest that a shallowing-upward sequence, characterized by a shallow water environment with foraminifera-bearing limestones, was deposited over the Tournaisian pelagic sequence in the Beyşehir-Hoyran Nappes till the Early Moscovian (Early Middle Pennsylvanian). This shallowing-upward sequence in the Beyşehir-Hoyran Nappes could be related to the Late Paleozoic Glaciation on the Gondwana supercontinent (Glacial Ⅱ), which resulted in a sea-level drop and deposition of platform carbonates during the Viséan–Early Moscovian (Middle Mississippian to Early Middle Pennsylvanian) time interval. The absence of the main part of the Middle–Upper Pennsylvanian deposits (continental phase during the Middle Moscovian–Middle Gzhelian) in the Beyşehir-Hoyran Nappes can be mainly attributed to the occurrence of a mantle plume and partially to the effect of Late Paleozoic Gondwanan Glaciation (Glacial Ⅲ). Progressive uplifting by the buoyant mantle plume material has resulted in rifting at the center of the basin where the Beyşehir-Hoyran Nappes have deposited. The rifting process led to tectonic destabilization of the platform in the basin, causing accumulation of the Upper Gzhelian (uppermost Pennsylvanian) detrital limestone with broken and abraded foraminiferal shells. Following this, deep basinal conditions prevailed during the Late Asselian–Kungurian (Early Permian), as revealed in the Mersin Mélange, where radiolarian cherts are associated with continental within-plate lavas of extreme incompatible trace element enrichment. Similar processes were responsible for the continual deposition of detrital limestones in the same basin until the end of Late Capitanian (Middle Permian). Based on all these, the uplifting process followed by rift-related volcanic rocks and detrital limestones can be interpreted as the opening of the Izmir-Ankara Ocean (northern Neotethys).

Petrogenesis and Tectonic Implications of the Paleoproterozoic A-Type Granites in the Xiong'ershan Area along the Southern Margin of the North China Craton
Jinhong Xu, Yuping Jiang, Shuli Hu, Zhengwei Zhang, Chengquan Wu, Chaofei Zheng, Xiyao Li, Ziru Jin, Sensen Zhang, Yatao Zhou
2024, 35(2): 416-429.   doi: 10.1007/s12583-021-1424-0
[Abstract](12) [FullText HTML](12) [PDF 11865KB](12)
Abstract:

Paleoproterozoic A-type granites are widely distributed in the southern margin of the North China Craton (SNCC), providing important information for understanding the Paleoproterozoic tectonic regimes in this area. This paper reports newly obtained whole-rock compositions and zircon U-Pb ages for the Tieluping syenogranite porphyry (TLP) and Huoshenmiao alkali granite porphyry (HSM) in the SNCC. Zircons from the TLP and HSM have U-Pb ages of 1 805 ± 12 and 1 792 ± 14 Ma, respectively. These ages are taken to date the emplacement of these intrusions. They had high total alkali contents (K2O + Na2O > 7.13 wt.%), with high 10 000 × Ga/Al ratios (3.06–3.41) and Zr + Y + Nb + Ce values (709 ppm–910 ppm) as well as high zircon saturation temperatures (864–970 ℃), indicative of A-type granite affinities. High Y/Nb (1.75–3.32), Ce/Nb (7.72–9.72), and Yb/Ta (2.89–5.60) ratios suggested that TLP and HSM belonged to the A2-type granite. The negative whole rock εNd(t) values (-8.4 to -6.6) and negative zircon εHf(t) values (-15.9 to -6.3) confirmed that TLP and HSM were likely generated by the partial melting of an ancient continental crust. The εHf(t) (-7.4 to +4.0) values of inherited zircons in the TLP suggested that they were derived from the partial melting of Archean basement rocks. Considering the geochemical similarity of the 1.80 Ga A-type granitoids in the SNCC, we propose that the TLP and HSM were formed in a post-collisional regime that was likely associated with the break-off of the Paleoproterozoic subducted slab. Upwelling of the asthenosphere provided huge heat to generate the regional 1.80 Ga A-type granite in the SNCC.

Early Ordovician–Middle Silurian Subduction-Closure of the Proto-Tethys Ocean: Evidence from the Qiaerlong Pluton at the Northwestern Margin of the West Kunlun Orogenic Belt, NW China
Jinhong Xu, Zhengwei Zhang, Chengquan Wu, Taiyi Luo, Weiguang Zhu, Xiyao Li, Ziru Jin, Pengcheng Hu
2024, 35(2): 430-448.   doi: 10.1007/s12583-021-1453-8
[Abstract](14) [FullText HTML](14) [PDF 18002KB](16)
Abstract:

Early Paleozoic magmatism in the West Kunlun Orogenic Belt (WKOB) preserves important information about the tectonic evolution of the Proto-Tethys Ocean. This paper reports whole-rock compositions, zircon and apatite U-Pb dating, and zircon Hf isotopes for the Qiaerlong Pluton (QEL) at the northwestern margin of WKOB, with the aim of elucidating the petrogenesis of the pluton and shedding insights into the subduction-collision process of this oceanic slab. The QEL is mainly composed of Ordovician quartz monzodiorite (479 ± 3 Ma), quartz monzonite (467–472 Ma), and syenogranite (463 ± 4 Ma), and is intruded by Middle Silurian peraluminous granite (429 ± 20 Ma) and diabase (421 ± 4 Ma). Zircon εHf(t) values reveal that quartz monzodiorites (+2.1 to +9.9) and quartz monzonites (+0.6 to +6.8) were derived from a mixed source of juvenile crust and older lower crust, and syenogranites (-5.6 to +4.5) and peraluminous granites (-2.9 to +2.0) were generated from a mixed source of lower crust and upper crust; diabases had zircon εHf(t) values ranging from -0.3 to +4.1, and contained 463 ± 5 Ma captured zircon and 1 048 ± 39 Ma inherited zircon, indicating they originated from enriched lithospheric mantle and were contaminated by crustal materials. The Ordovician granitoids are enriched in LILEs and light rare-earth elements, and depleted in HFSEs with negative Nb, Ta, P, and Ti anomalies, suggesting that they formed in a subduction environment. Middle Silurian peraluminous granites have the characteristics of leucogranites with high SiO2 contents (74.92 wt.%–75.88 wt.%) and distinctly negative Eu anomalies (δEu = 0.03–0.14), indicating that they belong to highly fractionated granite and were formed in a post-collision extension setting. Comparative analysis of these results with other Early Paleozoic magmas reveals that the Proto-Tethys ocean closed before the Middle Silurian and its southward subduction resulted in the formation of QEL.

Sedimentary and Heavy Mineral Records for the Oligocene–Miocene Exhumation of the Easternmost Tianshan
Yan Ding, Tianyi Shen, Guocan Wang, Junliang Ji
2024, 35(2): 449-461.   doi: 10.1007/s12583-022-1757-3
[Abstract](8) [FullText HTML](8) [PDF 11522KB](9)
Abstract:

The topography of the Harlik Mountain has a strong impact on the formation of current arid climate in the Turpan-Hami Basin. However, it is still controversial if Harlik Mountain experienced significant exhumation during the Middle to Late Cenozoic according to the previous thermochronology studies. The features of the Oligocene to Miocene sediments in the foreland basin could provide productive information for resolving the debates. The peak ages of detrital apatite fission track analysis of the Oligocene–Miocene sandstone in the Turpan-Hami Basin are well comparable with the cooling age records of the Harlik Mountain rocks, indicating that the Oligocene–Miocene Taoshuyuanzi Formation in the basin was mostly derived from the Harlik Mountain. The stratigraphic sequence exhibits coarsening upward, reflecting that the source area was in a tectonically active period during the deposition process. Heavy mineral assemblages also suggest that the unstable minerals in the sediment increased significantly at the end of the deposition. Moreover, the proportion of apatite increased up-section, while the garnet content decreased significantly, indicating that the Carboniferous metamorphic rocks have been gradually eroded out and more intrusive rocks have been exposed to the surface. These observations suggest that the Harlik Mountain experienced exhumation during the Oligocene to Miocene, and the denudation depth afterward was probably less than 2.5 km according to the previously apatite (U-Th)/He data. The Oligocene–Miocene exhumation probably acted as one of the triggers for the heavy drought of the Turpan-Hami Basin during the Middle–Late Neogene.

Geochronology, Geochemistry, and Sr-Nd-Hf Isotopes of the Diorite Porphyrites from the Weining Beishan Area, Ningxia Hui Autonomous Region: Constraints on Their Source and Tectonic Implications
Anlu Liu, Lianfu Hai, Jinke Liu, Xiaojun Zhang, Haifeng Li, Fengshun Zhao, Guoliang Zhao, Jinhe Bai
2024, 35(2): 462-475.   doi: 10.1007/s12583-021-1491-2
[Abstract](10) [FullText HTML](10) [PDF 10766KB](7)
Abstract:

The Weining Beishan area of Ningxia Hui Autonomous Region is located at on the western edge of the Helanshan tectonic belt, which is a tectonic joint among Alxa Block, Ordos Block, and North Qilian orogenic belt. However, the tectonic evolution of this area remains unclear due to the lack of magmatic information. This paper conducted researches on geochronology, geochemistry, and Sr-Nd-Hf isotopes of the diorite porphyrites exposed in the Weining Beishan area. The zircon U-Pb dating yields two ages of 145.0 ± 1.1 and 146.2 ± 1.5 Ma, and the whole-rock geochemical data indicate that the diorite porphyrites are metaluminous to weakly peraluminous and high-K calc-alkaline series. The characteristics of highly initial 87Sr/86Sr ratios (0.708 16 to 0.710 47), negative εNd(t) (-8.9 to -8.4), and negative εHf(t) (-13.8 to -21.2) indicate that the diorite porphyrites originated from partial melting of the middle-lower ancient crust related to the North China Craton. Combined with the regional geology, we suggested that partial melting was triggered by a tectonic activity of deep faults cutting through the crust under the regional stress transformation from compressing to extension during the Late Jurassic–Early Cretaceous, which is probably related to the westward subduction of the Paleo-Pacific Plate.

Mineralogy and Mineral Deposits
Integrated Stratigraphy and Mineralogy of the Doushantuo Formation in Weng'an, South China, and Implications for Ediacaran Phosphogenesis
Liangxuan Jiao, Zhenbing She, Dominic Papineau, Yaguan Zhang, Matthew S. Dodd, Kenan Cao, Qun Chen, Guoyong Chen
2024, 35(2): 476-503.   doi: 10.1007/s12583-022-1765-3
[Abstract](10) [FullText HTML](10) [PDF 3184KB](11)
Abstract:

The Ediacaran–Cambrian Phosphogenic Episode is the Earth's first true phosphogenic event and resulted in worldwide phosphate deposits, which occurred during the processes of the Neoproterozoic Oxygenation Event. The Ediacaran Doushantuo Formation (ca. 635–551 Ma) of Weng'an area in central Guizhou, South China, contains two economic phosphorite beds (the Lower and Upper Phosphorite Beds). This paper presents a detailed stratigraphic, sedimentological and mineralogical study of multiple outcrop and drill core sections of the Doushantuo Formation across the Weng'an area, and identified 11 lithofacies and 4 types of phosphatic grains. Significant differences in lithofacies and grain types between the upper and lower phosphate deposits are observed, indicating that the two sets of phosphate deposits are the products of two distinct phosphogenic processes. The Lower Phosphorite Bed mainly consists of banded and laminated phosphorites, contains micro-oncoids formed by microbially-mediated precipitation and peloids formed by in-situ chemically oscillating reactions, indicating a biochemical and chemical enrichment of phosphorus to sediments during the Early Ediacaran Period. The Upper Phosphorite Bed is mainly composed of carbonaceous, massive, and stromatolitic phosphorites, contains bioclasts (phosphatized spheroidal fossils), and intraclasts formed by hydrodynamic agitation, suggesting that the major accesses of phosphorus to sediments were the remineralization of organic P. Deposition of the two economic phosphorite beds was controlled by two sea-level cycles. Such differences have also been documented in contemporaneous phosphate-bearing successions in Brazil and Mangolia, indicating a significant shift in global phosphogenic mechanism during the early and middle Ediacaran, which may be due to the changes in redox conditions in seawater, associated with the Neoproterozoic Oxygenation Event. These regional active P-cycle processes could produce more free oxygen, which may have contributed to the upcoming Phanerozoic global oxidation.

Effect of Iron on the Stability of Rhodochrosite at the Topmost Lower Mantle Conditions
Tianlei Zhai, Fei Qin, Shengxuan Huang, Shan Qin, Yu Gong
2024, 35(2): 504-513.   doi: 10.1007/s12583-022-1685-2
[Abstract](10) [FullText HTML](10) [PDF 2909KB](6)
Abstract:

Carbonates are viewed as the principal oxidized carbon carriers during subduction, and thus the stability of subducted carbonates has significant implications for the deep carbon cycle. Here we investigate the high pressure-temperature behaviors of rhodochrosite in the presence of iron up to ~34 GPa by in-situ X-ray diffraction and ex-situ Raman spectroscopy. At relatively low temperature below ~1 500 K, MnCO3 breaks down into MnO and CO2. Upon heating to ~1 800 K, however, the MnCO3-Fe0 reactions occur with the formation of Mn3O4, FeO and reduced carbon. A 'three-stage' reaction mechanism is proposed to understand the kinetics of the carbon-iron-manganese redox coupling. The results suggest that Fe0 can serve as a reductant to greatly affect the stability of rhodochrosite, which implies that the effect of Fe-metal should be seriously considered for the high pressure-temperature behaviors of other predominant carbonates at Earth's mantle conditions, particularly at depths greater than ~250 km.

Druse Calcite Crystals Formed by Mesoproterozoic Paleo-Earthquake Activity in the Northern Margin of the North China Craton
Yueshuang Du, Zhiguang Zhou, Guosheng Wang, Chen Wu, Wenchao Xu
2024, 35(2): 514-524.   doi: 10.1007/s12583-021-1416-0
[Abstract](6) [FullText HTML](6) [PDF 16286KB](7)
Abstract:

The Meso-neoproterozoic Bayan Obo rift is located along the northern margin of the North China Craton, and was associated with the break-up of the Columbia supercontinent. During rift evolution, syn-sedimentary deformation occurred due to tectonic activity and earthquakes. Seismic events are recorded in the Jianshan Formation of the Bayan Obo Group, Inner Mongolia, as soft sediment deformation structures in the central Bayan Obo rift. Druse calcite crystals and collapse breccias in the Jianshan Formation may provide information on the rift evolution. The druse calcite crystals are idiomorphic-columnar in shape and associated with graphite, pyrite, and quartz. δ13C values of the graphite are -20‰, indicative of biogenic deoxygenation and formation in water. The druse calcite crystals are inorganic in origin and formed in water at a temperature of 55 ℃, based on calcite δ13C and δ18O data. The calcite grew in paleo-caves containing fault breccias, with heat derived from faulting. As such, the druse calcite crystals are important evidence for seismic events. The collapse breccias (i.e., fault breccias) and other indicators of slip show that displacement occurred from NE to SW, which is different from the paleocurrent direction in the Jianshan Formation. The thickness of the collapse breccia is ~200 m, which represents the height of the fault scarp. The strike of the fault scarp was NE-SW, based on the distribution of the collapse breccia. The Bayan Obo and Yanliao rifts experienced rapid NW-SE extension, and developed similar deformation structures at ca. 1.6 Ga related to break-up of the Columbia supercontinent.

High-Pressure Behavior of Ferromagnesite (Mg0.81Fe0.19)CO3 by Synchrotron X-Ray Diffraction and Raman Spectroscopy up to 53 GPa
Lin Liang, Guibin Zhang, Shengxuan Huang, Jingjing Niu, Dongzhou Zhang, Jingui Xu, Wen Liang, Shan Qin
2024, 35(2): 525-535.   doi: 10.1007/s12583-021-1495-y
[Abstract](5) [FullText HTML](5) [PDF 1326KB](5)
Abstract:

Ferromagnesite (Mg, Fe)CO3 with 20 mol% iron is a potential host mineral for carbon transport and storage in the Earth mantle. The high-pressure behavior of synthetic ferromagnesite (Mg0.81Fe0.19)CO3 up to 53 GPa was investigated by synchrotron X-ray diffraction (XRD) and Raman spectroscopy. The iron bearing carbonate underwent spin transition at around 44–46 GPa accompanied by a volume collapse of 1.8%, which also demonstrated a variation in the dνi/dP slope of the Raman modes. The pressure-volume data was fitted by a third-order Birch-Murnaghan equation of state (BM-EoS) for the high spin phase. The best-fit K0 = 108(1) GPa and $ {\mathit{K}}_{0}^{\mathbf{'}} $ = 4.2(1). Combining the dνi/dP and the K0, the mode Grüneisen parameters of each vibrational mode (T, L, ν4 and ν1) were calculated. The effects of iron concentration on the Mg1-xFexCO3 system related to high-pressure compressibility and vibrational properties are discussed. These results expand the knowledge of the physical properties of carbonates and provide insights to the potential deep carbon host.

Structural Control of the Getang Carlin-Type Gold Deposit in Southwest China
Guoping Zeng, Xinlu Hu, Diwei Luo, Jianzhong Liu, Shuzhen Yao, Yongjie Jin
2024, 35(2): 536-552.   doi: 10.1007/s12583-021-1461-8
[Abstract](10) [FullText HTML](10) [PDF 44102KB](10)
Abstract:

The Getang is a representative Carlin-type gold deposit in Southwest China. It has a proven reserve of about 30 tonnes at an average grade of 5.1 g/t Au. The orebodies occur as stratabound lenses, and are structurally controlled by shallow NWW- and NE-trending fold-fault systems and the unconformity between the Upper and Middle Permian. In this study, the regional- and deposit-scale structural investigations, joints and finite strain measurements, and stress and dynamic analysis were conducted with an aim to reveal the structural process of the Getang gold deposit and clarify the relationship between the gold mineralization and structures. Three phases of deformation were identified in the deposit: (1) paleokarst was generated by a crustal uplift when the Youjiang Basin experienced extension at the end of the Middle Permian, laying the foundation for the unconformity; (2) the NW-trending structures were formed under a NNE-SSW compression during the Indochina-South China collision (Indosinian orogeny) in Triassic; (3) the NE-trending structures were generated or reactivated under a NW-SE-oriented compression during the Yanshanian intracontinental orogeny. The unconformity recorded two episodes of tectonic evolution in the NNE-SSW and NW-SE directions. Structural analyses and geochronology data suggest that the Getang gold deposit was formed as a result of tectonic transition from compression to extension during the Yanshanian intracontinental orogeny.

Engineering Geology
Study on Shear Strength Characteristics of Basalt-Concrete Bonding Interface Based on in-situ Direct Shear Test
Peng Xia, Xinli Hu, Chunye Ying, Shuangshuang Wu, Chu Xu, Xuan Wang, Hao Chen, Hang Duan
2024, 35(2): 553-567.   doi: 10.1007/s12583-021-1594-9
[Abstract](7) [FullText HTML](7) [PDF 11506KB](5)
Abstract:

In rock engineering, the shear strength of the basalt-concrete bonding interface is a key factor affecting the shear performance of hydroelectric dam foundations, embedded rock piles and rock bolts. In this study, 30 sets of in-situ direct shear tests were conducted on the basalt-concrete bond interface in the Baihetan dam area to investigate the shear strength characteristics of the basalt-concrete bonding interface. The bonding interface contains two states, i.e., the bonding interface is not sheared, termed as se (symbolic meaning see Table 1); the bonding interface is sheared with rupture surface, termed as si. The effects of lithology, Joints structure, rock type grade and concrete compressive strength on the shear strength of the concrete-basalt contact surface were investigated. The test results show that the shear strength of the bonding interface (se & si) of columnar jointed basalt with concrete is greater than that of the bonding interface (se & si) of non-columnar jointed one with the same rock type grade. When the rock type grade is Ⅲ2, fcol is 1.22 times higher than fncol and ccol is 1.13 times greater than cncol. The shear strength parameters of the basalt-concrete bonding interface differ significantly for different lithologies. The cohesion of the bonding interface (si) of cryptocrystalline basalt with concrete is 2.05 times higher than that of the bonding interface (si) of breccia lava with concrete under the same rock type grade condition. Rock type grade has a large influence on the shear strength of the non-columnar jointed basalt-concrete bonding interface (se & si). cnol increases by 33% when the grade of rock type rises from Ⅲ1 to Ⅱ1. the rock type grade has a greater effect on bonding interface (si) cohesion than the coefficient of friction. When the rock type grade is reduced from Ⅲ2 to Ⅲ1, f'ncol increases by 2% and c'ncol improves by 44%. The shear strength of the non-columnar jointed basalt-concrete bonding interface (se & si) increases with the increase of the compressive strength of concrete. When concrete compressive strength rises from 22.2 to 27.6 MPa, the cohesion increases by 94%.

Weight Analysis of Impact Factors of Interbedded Anti-Inclined Slopes Block-Flexure Toppling Based on Support Vector Regression
Bocheng Zhang, Huiming Tang, Yibing Ning, Kun Fang, Ding Xia
2024, 35(2): 568-582.   doi: 10.1007/s12583-023-1835-1
[Abstract](7) [FullText HTML](7) [PDF 15609KB](4)
Abstract:

Block-flexure toppling failure is frequently encountered in interbedded anti-inclined rock (IAR) slopes, and seriously threatens the construction of hydropower infrastructure. In this study, we first investigated the Lean Reservoir area's geological setting and the Linda landslide's characteristics. Then, uniform design and random design were used to design 110 training datasets and 31 testing datasets, respectively. Afterwards, the toppling response was obtained by using the discrete element code. Finally, support vector regression was used to obtain the influence weights of 21 impact factors. The results show that the influence weight of the slope angle and rock formation dip angle on the toppling deformation among tertiary impact factors is 25.96% and 17.28%, respectively, which are much greater than the other 19 impact factors within the research range. For the primary impact factors, the influence weight is sorted from large to small as slope geometry parameters, joints parameters, and rock mechanics parameters. Joints parameters, especially the geometric parameters, cannot be ignored when evaluating the stability of IAR slopes. Through numerical simulation, it was qualitatively determined that failure surfaces of slopes were controlled by cross joints and that the rocks in the slope toe play a role in preventing slope deformation.

Numerical Simulation of the Mass Movement Process of the 2018 Sedongpu Glacial Debris Flow by Using the Fluid-Solid Coupling Method
Xing-Yu Long, Yu-Xiang Hu, Bin-Rui Gan, Jia-Wen Zhou
2024, 35(2): 583-596.   doi: 10.1007/s12583-022-1625-1
[Abstract](14) [FullText HTML](14) [PDF 11410KB](2)
Abstract:

In the context of global warming and intensified human activities, glacier instability in plateau regions has increased, and glacier debris flows have become active, which poses a significant threat to the lives and property of people and socioeconomic development. The mass movement process of glacier debris flows is extremely complex, so this paper uses the 2018 Sedongpu glacier debris flow event on the Qinghai-Tibet Plateau as an example and applies a numerical simulation method to invert the whole process of mass movement. In view of the interaction between phases in the process of motion, we use the fluid-solid coupling method to describe the mass movement. The granular-flow model and drift-flux model are employed in FLOW3D software to study the mass movement process of glacier debris flows and explore their dynamic characteristics. The results indicate that the glacier debris flow lasted for 700 s, and the movement process was roughly divided into four stages, including initiation, scraping, surging and deposition; the depositional characteristics calculated by the fluid-solid coupling model are consistent with the actual survey results and have good reliability; strong erosion occurs during the mass movement, the clear volume amplification effect, and the first wave climbs 17.8 m across the slope. The fluid-solid coupling method can better simulate glacier debris flows in plateau regions, which is helpful for the study of the mechanism and dynamic characteristics of such disasters.

A Comprehensive Study on the Consequences of Gap-Graded Sands Considering the Loss of Fine Particles
Weiping Liu, Yu Gan, Yunwei Cui, Faming Huang, Lina Hu
2024, 35(2): 597-612.   doi: 10.1007/s12583-022-1764-4
[Abstract](8) [FullText HTML](8) [PDF 17030KB](4)
Abstract:

Water and sand leakage disasters are likely to occur during construction in water-rich sand layer areas, resulting in ground collapse. The stress-strain action characteristics of discontinuous graded sand under different internal erosion degrees, and the evolution mechanism of water and sand leakage disasters caused by the internal erosion need to be further explored. Therefore, this paper takes the discontinuous graded sand in a water rich sand layer area in Nanchang City of China as the research object. Considering the influence of different fine particle losses (0, 10%, 20% and 30%) under the internal erosion of sand, the salt solution method is used to realize the specified loss of fine particles in the internal erosion. The stress-strain behavior after the loss of fine particles due to internal erosion is studied by triaxial shear test. Meanwhile, the physical model test and PFC-CFD method are both used to study the evolution rules of water and sand leakage disaster considered the influence of internal erosion degrees. Results show that: (1) under the same confining pressure, the peak failure strength of sand samples decreases along with the increase of fine particle loss. (2) In the water and sand leakage test of saturated sand, a natural filter channel is formed above the observed soil arch. The greater the loss of fine particles, the steeper and wider the collapse settlement area. (3) The relationship between the cumulative amount of water and sand leakage and time is nonlinear. The total mass loss of sand increases along with the increase of internal erosion degree. (4) After the soil arch is formed around the damaged opening, the sand continues to converge above the soil arch under the action of water flow, resulting in the dense convergence of contact force chains.

Petroleum Geology
Hydrocarbon Charging and Accumulation Process of the Large Bozhong19-6 Condensate Gas Reservoirs in the Southwestern Bozhong Sub-Basin, Bohai Bay Basin, China
Quanyun Miao, Changgui Xu, Fang Hao, Minjunshi Xie, Qi Wang, Jie Yin, Huayao Zou
2024, 35(2): 613-630.   doi: 10.1007/s12583-021-1457-4
[Abstract](4) [FullText HTML](4) [PDF 20089KB](6)
Abstract:

The Bozhong19-6 (BZ19-6) condensate gas reservoirs, located in the southwestern Bozhong sub-basin, Bohai Bay Basin, China, were paleo-oil reservoirs in the geological past and have undergone at least three successive hydrocarbon charging events. The hydrocarbon migration and accumulation process of "early oil and late gas" has occurred in the current reservoirs. At the end of the sedimentation of the Guantao Formation (N1g, ~12 Ma), the reservoirs began to fill with first stage low-moderate mature crude oil. At the late stage of the Lower Minghuazhen Formation (N1ml) (~6.7 Ma), the reservoirs were largely charged with second stage high mature crude oil. Since the deposition of the upper Minghuazhen Formation (N2mu, ~5.1 Ma), the paleo-oil reservoirs were transformed into shallow Neogene reservoirs due to the reactivation of basement faults. From the late stage of the N2mu to the present day (~2.8-0 Ma), the reservoirs were rapidly filled by natural gas within a short period. In addition, analysis of the formation of the reservoir bitumen and the conspicuous loss of the lower molecular weight n-alkanes in the crude oil reveal that the injection of a large amount of gas in the late stage caused gas flushing of the early charged oil.

Fractal Characteristics and Main Controlling Factors of High-Quality Tight Sandstone Reservoirs in the Southeastern Ordos Basin
Ruilin Hao, Wenhui Huang, Jiu Bo, Li Yuan
2024, 35(2): 631-641.   doi: 10.1007/s12583-021-1514-z
[Abstract](6) [FullText HTML](6) [PDF 7402KB](7)
Abstract:

Due to the complex conditions and strong heterogeneity of tight sandstone reservoirs, the reservoirs should be classified and the controlling factors of physical properties should be studied. Cast thin section observations, cathodoluminescence, scanning electron microscopy (SEM), X-ray diffraction (XRD), and high-pressure mercury injection (HPMI) were used to classify and optimize the reservoir. The Brooks-Corey model and stepwise regression were used to study the fractal dimension and main controlling factors of the physical properties of the high-quality reservoir. The results show that the reservoirs in the study area can be divided into four types, and the high-quality reservoir has the best physical properties and pore-throat characteristics. In the high-quality reservoir, the homogeneity of transitional pores was the best, followed by that of micropores, and the worst was mesopores. The porosity was controlled by depth and kaolinite. The model with standardized coefficients is y = 12.454 – 0.778 × (Depth) + 0.395 × (Kaolinite). The permeability was controlled by depth, illite/montmorillonite, and siliceous cement, and the model with standardized coefficients is y = 1.689 – 0.683 × (Depth) – 0.395 × (Illite/Montmorillonite) – 0.337 × (Siliceous Cement). The pore-throat evolutionary model shows that the early-middle diagenetic period was when the reservoir physical properties were at their best, and the kaolinite intercrystalline pores and residual intergranular pores were the most important.

Geochemical Characteristics and Hydrocarbon Generation Modeling of the Paleocene Source Rocks in the Jiaojiang Sag, East China Sea Basin
Chuang Lei, Shiyan Yin, Jiaren Ye, Jingfu Wu, Zhaosheng Wang, Bin Gao
2024, 35(2): 642-654.   doi: 10.1007/s12583-021-1528-6
[Abstract](3) [FullText HTML](3) [PDF 4072KB](9)
Abstract:

Jiaojiang sag in the East China Sea Basin is at the earlier exploration stage, where characterizing hydrocarbon generation of source rocks is important to understand oil-gas exploration potential. Utilizing geochemical and basin modeling analysis, hydrocarbon generation capacity and process of the Paleocene E1y, E1l and E1m formations were investigated. Results show that E1y and E1l mudstones are high-quality source rocks with Type II kerogen, which is dominated by both aquatic organisms and terrestrial higher plants deposited in sub-reduced environment. E1m mudstone interbedded with thin carbonaceous mudstone and coal is poor-quality source rock with Type III kerogen, whose organic matter was originated from terrestrial higher plants under oxidized environment. Controlled by burial and maturity histories, E1y and E1l source rocks experienced two hydrocarbon generation stages, which took place in the Late Paleocene and in the Middle to Late Eocene, respectively, and had high hydrocarbon generation capacity with cumulative hydrocarbon volume of 363 and 328 mg/g, respectively. E1m source rock only had one hydrocarbon generation process in the Late Eocene, which had low hydrocarbon generation capacity with cumulative hydrocarbon volume of only 24 mg/g. The future oil-gas exploration in the Jiaojiang sag should focus on hydrocarbon generation center and select targets in the central uplift formed before the Miocene with high-quality traps.

Genesis and Accumulation of Paleo-Oil Reservoir in Dabei Area, Kuqa Depression, Northwest China: Implications for Tight-Gas Accumulation
Fujie Jiang, Xiao Chen, Pengwei Wang, Xinghe Shao, Haijun Yang
2024, 35(2): 655-665.   doi: 10.1007/s12583-021-1562-4
[Abstract](7) [FullText HTML](7) [PDF 9409KB](5)
Abstract:

Paleo-oil reservoir is of great importance to understand hydrocarbon enrichment mechanism and hydrocarbon exploration potential, but is yet poorly investigated in Kuqa Depression. The occurrence of the paleo-oil reservoir in Dabei area was proved by quantitative grain fluorescence (QGF) and fluid inclusion petrography. Development history of the paleo-oil reservoir was reconstructed through: (1) oil-source correlation; (2) time coupling of source rock maturation, porosity evolution and migration pathways. The impact of paleo-oil reservoir on tight-gas accumulation was consequently discussed. Results suggest that considerable oil was accumulated in the K1bs reservoir with paleo oil-water contact in Dabei 2 Well and Dabei 201 Well at 5 800 and 6 040 m, respectively. Crude oil was primarily sourced from Triassic source rocks with Jurassic source rocks of secondary importance, which was at oil generation window (0.7%–1.1% Ro) during 9–6 and 7.5–5 Ma, respectively. The occurrence of K1bs tight reservoir (porosity < 12%) was about 25 Ma, while faults and associated fractures at Kelasue structural belt were developed approximately from 8 to 3.5 Ma. Therefore, the tight oil accumulation was formed during 8–5 Ma. The paleo-oil reservoir in Dabei 1 gas field was destroyed by the evaporation fractionation in later stage.

Multi-Scale Pore Structure Heterogeneity in Tuff Reservoirs Investigated with Multi-Experimental Method and Fractal Dimensions in Chang 7 Formation, Southern Ordos Basin
Hao Lu, Qing Li, Dali Yue, Dongdong Xia, Shenghe Wu, Lang Wen, Yu He
2024, 35(2): 666-686.   doi: 10.1007/s12583-023-1857-8
[Abstract](2) [FullText HTML](2) [PDF 21566KB](4)
Abstract:

The tight tuff reservoir is an unusual type of unconventional reservoir with strong heterogeneity. However, there is a lack of research on the microscopic pore structure that causes the heterogeneity of tuff reservoirs. Using the Chang 7 Formation in Ordos Basin, China as a case study, carbon-dioxide gas adsorption, nitrogen gas adsorption and high-pressure mercury injection are integrated to investigate the multi-scale pore structure characteristics of tuff reservoirs. Meanwhile, the fractal dimension is introduced to characterize the complexity of pore structure in tuff reservoirs. By this multi-experimental method, the quantitative characterizations of the full-range pore size distribution of four tuff types were obtained and compared in the size ranges of micropores, mesopores and macropores. Fractal dimension curves derived from full-range pores are divided into six segments as D1, D2, D3, D4, D5 and D6 corresponding to fractal characteristics of micropores, smaller mesopores, larger mesopores, smaller macropores, medium macropores and larger macropores, respectively. The macropore volume, average macropore radius and fractal dimension D5 significantly control petrophysical properties. The larger macropore volume, average macropore radius and D5 correspond to favorable pore structure and good reservoir quality, which provides new indexes for the tuff reservoir evaluation. This study enriches the understanding of the heterogeneity of pore structures and contributes to unconventional oil and gas exploration and development.

Hydrogeology
Water Changes and Sources of Siling Co Using Landsat and GRACE Data since 1972
Chuya Wang, Yuande Yang, Fei Li, Junhao Wang, Leiyu Li, Huiting Yu
2024, 35(2): 687-699.   doi: 10.1007/s12583-022-1761-7
[Abstract](7) [FullText HTML](7) [PDF 4570KB](6)
Abstract:

The inland lakes on the Tibetan Plateau (TP) are undergoing significant changes due to their sensitivity to climate. The largest lake in Tibet, Siling Co, has expanded most dramatically during recent decades. Using Landsat, GRACE and meteorological data, the expansion of Siling Co was detailed in four stages and the process was further explained. The results show that the lake area increased from 1 647.30 km2 in 1972 to 2 438.99 km2 in 2020. It experienced a slow growth at a rate 6.03 km2/yr from 1972 to 1988, while fluctuating at 1.44 km2/yr during 1989–1997, then accelerated at 60.28 km2/yr between 1998 and 2005, and expanded slowly again at 11.40 km2/yr since 2006. The continued expansion led to its merger with nearby Yagain Co in 2003. Terrestrial water storage (TWS) increase was also observed from GRACE (0.65 cm/yr), with about 0.75 coefficient of determination between the TWS and lake area during 2002–2020. The long-term expansion of Siling Co is related to the increasing trends of temperature and precipitation, but their contributions vary with time span. Specifically, the accelerated stage between 1998 and 2005 can be explained by the increased temperature and precipitation accompanied by a drop in evaporation, while the slow expansion since 2006 was due to the decrease in precipitation and temperature and the rise in evaporation. There is no obvious mass loss of glaciers revealed by GRACE during 2002–2020, which may be related to the negative trend of the temperature. Furthermore, the precipitation may still make a major contribution in this phase, as its average is about 93.9 mm higher than that in 1988–1997.

Editorials
Is Deep Time Geology Scientific?
T. Mark Harrison
2024, 35(2): 700-703.   doi: 10.1007/s12583-024-1977-9
[Abstract](14) [FullText HTML](14) [PDF 587KB](3)
Abstract:
Universal Hyperthermal Model for Mass Extinctions
Michael J. Benton
2024, 35(2): 704-707.   doi: 10.1007/s12583-024-1985-9
[Abstract](10) [FullText HTML](10) [PDF 568KB](1)
Abstract:
Geological Context of the SLIM Landing Site
Yichen Wang, Zhiyong Xiao, Pei Ma, Hanxing Ouyang, Wei Cao
2024, 35(2): 708-711.   doi: 10.1007/s12583-024-1986-8
[Abstract](5) [FullText HTML](5) [PDF 6188KB](6)
Abstract:
Wavefield Separation of Distributed Acoustic Sensing Vertical Seismic Profile Data Based on Multichannel Vector Median Filtering
Zijuan Ma, Jun Lu, Feng Zhang, Pinbo Ding, Zhidong Cai
2024, 35(2): 712-716.   doi: 10.1007/s12583-024-1966-z
[Abstract](8) [FullText HTML](8) [PDF 2621KB](6)
Abstract:
Study of Seismic P Wave in Mesoscale Fracture-Induced Arbitrary Anisotropic Media
Han Xiao, Xinmin Shang, Zhentao Wang, Xiping Wang
2024, 35(2): 717-721.   doi: 10.1007/s12583-024-1967-y
[Abstract](14) [FullText HTML](14) [PDF 706KB](0)
Abstract:

Mesoscale fracture controls the permeability of shale reservoirs, it is one of the main research objectives of natural fractures. The length of the mesoscale fracture is less than 1/4 of the seismic eigen wavelength and greater than 1% of the seismic eigen wavelength, they cannot be identified in actual seismic data and are usually displayed by the azimuthal anisotropy of seismic attributes. In this paper, we propose a calculation process from fracture properties to seismic P-wave velocity and traveltime in anisotropic media induced by multiple sets of arbitrary occurring mesoscale fractures. Based on this process, the variations of the media's Anisotropic (A-) parameters with fracture properties are studied. Furthermore, variation of P-wave NMO elliptical principle axis with the relative fracture density is studied according to the arbitrary anisotropic theory based on A-parameters.

Propagation and Dispersion Characteristics of Scholte Wave in VTI Media with the Presence of Irregular Seabed
Xiaobo Liu, Yun Wang, Jianlei Zhang, Haifeng Chen, Hua Zhang
2024, 35(2): 722-725.   doi: 10.1007/s12583-024-1965-0
[Abstract](6) [FullText HTML](6) [PDF 3282KB](7)
Abstract:
In-situ U-Pb Dating of Quartz: A Preliminary Study
Entao Liu, Jian-Xin Zhao, Songqi Pan, Detian Yan, Hua Wang
2024, 35(2): 726-728.   doi: 10.1007/s12583-024-1980-1
[Abstract](19) [FullText HTML](19) [PDF 798KB](23)
Abstract:
Research Progress and Challenges on Persistent Organic Pollutants in Lakes
Wei Guo, Xiaoyu Ji, Zhengfei Yu, Hongchen Jiang, Xiangyu Guan
2024, 35(2): 729-736.   doi: 10.1007/s12583-024-1978-8
[Abstract](7) [FullText HTML](7) [PDF 972KB](6)
Abstract:

Lakes are the main reservoirs of persistent organic pollutants (POPs) from land, atmosphere and rivers. POPs in lakes undergo complex exchange, transformation, and degradation between water-air-sediment-biota interfaces, which are constrained and regulated by various physical, chemical and biological factors. POPs can affect ecological conditions, chemical properties of water and sediments, and biodiversity of the lake system. Therefore, it is important to study the sources, migration, transformation, environmental behavior and ecological impacts of POPs in lake ecosystems. This review summarizes research progress on detection technologies, diversity and origins, historical records, migration and transformation, distribution patterns, degradation and toxic effects of POPs in lakes. Finally, future directions related to POPs in lakes were summarized.

Vol 35, No 2 , 2024

ISSN 1674-487X

CN 42-1788/P

Editor in Chief: Yanxin Wang

Managing Editors: Zhong-Qiang Chen, Shao-Yong Jiang

Associate Editor:

Shu Jiang,Changdong Li,Rui Ma 
Qiliang Sun,Timothy M. Kusky,Dun Wang 
Lunche Wang,Long Xiao,Xin-Fu Zhao
Keqing ZongRenguang Zuo

2022 Impact Factor 3.3