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Volume 25 Issue 4
Aug 2014
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Article Contents
Paweł BARAN, Katarzyna ZARĘBSKA, Adam NODZEŃSKI. Energy aspects of CO2 sorption in the context of sequestration in coal deposits. Journal of Earth Science, 2014, 25(4): 719-726. doi: 10.1007/s12583-014-0459-x
Citation: Paweł BARAN, Katarzyna ZARĘBSKA, Adam NODZEŃSKI. Energy aspects of CO2 sorption in the context of sequestration in coal deposits. Journal of Earth Science, 2014, 25(4): 719-726. doi: 10.1007/s12583-014-0459-x

Energy aspects of CO2 sorption in the context of sequestration in coal deposits

doi: 10.1007/s12583-014-0459-x
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  • Corresponding author: Paweł BARAN, baranp@agh.edu.pl
  • Received Date: 12 Sep 2013
  • Accepted Date: 16 Jan 2014
  • Publish Date: 01 Aug 2014
  • This paper summarises the results of experimental testing of carbon dioxide sorption on five coal samples. Sorption tests were done at the temperature 288, 298, 313 and 323 K, in the pressure range 0-5 MPa. The analysis of sorption isotherms and the effects of temperature on sorption capacity reveal that in the case of samples NR1, Pn, Tu, Be the temperature increase from 298 to 323 K led to 1.3-fold decrease of the sorption value. In the case of coal Th the decrease of sorption capacity was 3-fold. It appears that the analysis of maceral content plays a major role. In the case of coals, porosity is associated with the petrographic composition. The values of the isosteric heat of sorption and the work of expansion and desorption were derived for the investigated sorption systems. Test data reveal that for hard coals the isosteric heat is inversely proportional to the "reserve" of volumetric work—a major parameter triggering the sudden release of gas from the coalbed, thus enabling us to assess the potential risk involved in rapid unsealing of the coalbed.

     

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  • Baran, P., Broś. M., Nodzeński, A., 2010. Studies on CO2 Sorption on Hard Coal in the Nearcritical Area with Regard to the Aspect of Sequestration. Archives of Mining Sciences, 55(1): 59-68 http://www.researchgate.net/profile/Pawel_Baran/publication/259895434_Studies_on_CO_2_sorption_on_hard_coal_in_the_near-critical_area_with_regard_to_the_aspect_of_sequestration/links/00b7d5302fe19564db000000.pdf
    Baran, P., Cygankiewicz, J., Zarębska, K., 2013. Carbon Dioxide Sorption on Polish Ortholignite Coal in Low and Elevated Pressure. Journal of CO2 Utilization, 3-4: 44-48 doi: 10.1016/j.jcou.2013.09.003
    Busch, A., Gensterblum, Y., Krooss, B. M., et al., 2006. Investigation of High-Pressure Selective Adsorption/Desorption Behaviour of CO2 and CH4 on Coals: An Experimental Study. International Journal of Coal Geology, 66: 53-68 doi: 10.1016/j.coal.2005.07.003
    Ceglarska-Stefańska, G., Zarębska, K., 2005. Sorption of Carbon Dioxide-Methane Mixtures. International Journal of Coal Geology, 62: 211-222 doi: 10.1016/j.coal.2005.01.003
    Clarkson, C. R., Bustin, R. M., 2000. Binary Gas Adsorption/Desorption Isotherms: Effect of Moisture and Coal Composition upon Carbon Dioxide Selectivity over Methane. International Journal of Coal Geology, 42: 241-271 doi: 10.1016/S0166-5162(99)00032-4
    Czepirski, L., Jagiełło, J., 1989. Virial Type Thermal Equation of Gas-Solid Adsorption. Chemial Engineering Science, 44(4): 797-806 doi: 10.1016/0009-2509(89)85253-4
    Czerw, K., 2011. Methane and Carbon Dioxide Sorption/Desorption on Bituminous Coal—Experiments on Cubicoid Sample Cut from the Primal Coal Lump. International Journal of Coal Geology, 85(1): 72-77 doi: 10.1016/j.coal.2010.10.002
    Day, S., Fry, R., Sakurovs, R., 2008. Swelling of Australian Coals in Supercritical CO2. International Journal of Coal Geology, 74: 41-52 doi: 10.1016/j.coal.2007.09.006
    Fitzgerald, J. E., Pan, Z., Sudibandriyo, M., et al., 2005. Adsorption of Methane, Nitrogen, Carbon Dioxide and Their Mixtures on Wet Tiffany Coal. Fuel, 84: 2351-2363 doi: 10.1016/j.fuel.2005.05.002
    Franus, W., 2012. Characterization of X-Type Zeolite Prepared from Coal Fly Ash. Polish Journal of Environmental Studies, 21(2): 337-343
    Gensterblum, Y., van Hemert, P., Billemont, P., et al., 2009. Europan Inter-Laboratory Comparision of High Pressure CO2 Sorption Isotherms. I: Activated Carbon. Carbon, 47: 2958-2969
    Gensterblum, Y., van Hemert, P., Billemont, P., et al., 2010. European Inter-Laboratory Comparison of High Pressure CO2 Sorption Isotherms II: Natural Coals. International Journal of Coal Geology, 84(2): 115-124 doi: 10.1016/j.coal.2010.08.013
    Goodman, A. L., Busch, A., Bustin, M., et al., 2007. Inter-Laboratory Comparison II: CO2 Isotherms Measured on Moisture-Equilibrated Argonne Premium Coals at 55℃ and 15 MPa. International Journal of Coal Geology, 72: 153-164 doi: 10.1016/j.coal.2007.01.005
    Gusev, V., Fomkin, A., 1994. High Pressure Adsorption of Xe on NaX Zeolites by Microcalorimetry and Isosteric Analysis. Journal of Colloid Interface Science, 162(2): 279-283 doi: 10.1006/jcis.1994.1040
    Iglesias, M. J., Jiménez, A., del Río, J. C., et al., 2000. Molecular Characterization of Vitrinite in Relation to Natural Hydrogen Enrichment and Depositional Environment. Organic Geochemsitry, 31: 1285-1299 doi: 10.1016/S0146-6380(00)00086-3
    Jagiełło, J., Lasoń, M., Nodzeński, A., 1992. Thermodynamic Description of the Process of Gas Liberation from a Coal Bed. Fuel, 71: 431-435 doi: 10.1016/0016-2361(92)90033-K
    Jodłowski, G. S., 2008. The Analysis of Carbon Dioxide Sorption in the Sequestration Point of View. Gospodarka Surowcami Mineralnymi-Mineral Resources Management, 24(3): 139-148 http://www.researchgate.net/publication/310767151_The_analysis_of_carbon_dioxide_sorption_in_the_sequestration_point_of_view
    Jodłowski, G. S., Baran, P., Wójcik, M., et al., 2007. Sorption of Methane and Carbon Dioxide Mixtures in Polish Hard Coals Considered in Terms of Adsorption-Absorption. Applied Surface Science, 253: 5732-5735 doi: 10.1016/j.apsusc.2006.12.058
    Jodłowski, G. S., Wójcik, M., 2013. Comparative Analysis of Sorption of Small Molecule Hydrocarbons and Polar Substances in Polish Hard Coal. Adsorption—Journal of the International Adsorption Society, 19(2-4): 813-819 doi: 10.1007/s10450-013-9523-6
    Karacan, C. O., 2003. Heterogeneous Sorption and Swelling in a Confined and Stressed Coal during CO2 Injection. Energy Fuels, 17: 1595-1608 doi: 10.1021/ef0301349
    Karacan, C. O., Mitchell, G. D., 2003. Behavior and Effect Coal Microlithotypes during Gas Transport for Carbon Dioxide Sequestration into Coal Seams. International Journal of Coal Geology, 53: 201-217 doi: 10.1016/S0166-5162(03)00030-2
    Kwiecińska, B., 2005. Classification of the Dispersed Organic Matter According to the ICCP Recommendations. Przegląd Geologiczny, 53(3): 262 (in Polish)
    Larsen, J. W., 2004. The Effects of Dissolved CO2 on Coal Structure and Properties. International Journal of Coal Geology, 57: 63-70 doi: 10.1016/j.coal.2003.08.001
    Majewska, Z., Ceglarska-Stefanska, G., Majewski, S., et al., 2009. Binary Gas Sorption/Desorption Experiments on a Bituminous Coal: Simultaneous Measurements on Sorption Kinetics, Volumetric Strain and Acoustic Emission. International Journal of Coal Geology, 77: 90-102 doi: 10.1016/j.coal.2008.09.009
    Milewska-Duda, J., Duda, J., Nodzeński, A., et al., 2000. Absorption and Adsorption of Methane and Carbon Dioxide in Hard Coal and Active Carbon. Langmuir/American Chemical Society, 16(12): 5458-5466 http://www.onacademic.com/detail/journal_1000036099943310_e136.html
    Ozdemir, E., Morsi, B. I., Schroeder, K., 2004. CO2 Adsorption Capacity of Argonne Premium Coals. Fuel, 83: 1085-1094 doi: 10.1016/j.fuel.2003.11.005
    Pan, Z., Connell, L. D., 2007. A Theoretical Model for Gas Adsorption Induced Coal Swelling. International Journal of Coal Geology, 69: 243-252 doi: 10.1016/j.coal.2006.04.006
    Prinz, D., Littke, R., 2005. Development of the Micro and Ultramicroporous Structure of Coals with Rank as Deduced from the Accessibility of Water. Fuel, 84: 1645-1652 http://opac.vimaru.edu.vn/edata/E-Journal/2005/Fuel/issue12-13/bai25.pdf
    Romanov, V. N., Goodman, A. L., Larsen, J. W., 2006. Errors in CO2 Adsorption Measurements Caused by Coal Swelling. Energy Fuels, 20: 415-416 doi: 10.1021/ef050318i
    Sakurovs, R., Day, S., Weir, S., 2009. Causes and Consequences of Errors in Determining Sorption Capacity of Coals for Carbon Dioxide at High Pressure. International Journal of Coal Geology, 77(1-2): 16-22 doi: 10.1016/j.coal.2008.07.001
    Siemons, N., Busch, A., 2007. Measurement and Interpretation of Supercritical CO2 Sorption on Various Coals. International Journal of Coal Geology, 69: 229-242 doi: 10.1016/j.coal.2006.06.004
    Span, R., Wagner, W., 1996. A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1 100 K at Pressures up to 800 MPa. Journal of Physical and Chemical Reference Data, 25: 1509-1596 doi: 10.1063/1.555991
    Tarkowski, R., Wdowin, M., 2011. Petrophysical and Mineralogical Research on the Influence of CO2 Injection on Mesozoic Reservoir and Caprocks from the Polish Lowlands. Oil & Gas Science and Technology—Rev. IFP Energies Nouvelles, 66(1): 137-150 http://ogst.ifpenergiesnouvelles.fr/articles/ogst/pdf/2011/01/ogst09118.pdf
    Wdowin, M., Franus, W., Panek, R., 2012. Preliminary Results of Usage Possibilities of Carbonate and Zeolitic Sorbents in CO2 Capture. Fresenius Environmental Bulletin, 21(12): 3726-3734 http://www.wbia.pollub.pl/files/102/attachment/2222_2012,W.F.,PRELIMINARY,RESULTS,OF,USAGE.pdf
    Weniger, P., Kalkreuth, W., Busch, A., et al., 2010. High-Pressure Methane and Carbon Dioxide Sorption on Coal and Shale Samples from the Parana Basin, Brazil. International Journal of Coal Geology, 84(3-4): 190-205 doi: 10.1016/j.coal.2010.08.003
    Zarębska, K., Baran, P., Cygankiewicz, J., et al., 2012. Sorption of Carbon Dioxide on Polish Coals in Low and Elevated Pressure. Fresenius Environmental Bulletin, 21(12b): 4003-4008 http://www.researchgate.net/profile/Pawel_Baran/publication/259895195_SORPTION_OF_CARBON_DIOXIDE_ON_POLISH_COALS_IN_LOW_AND_ELEVATED_PRESSURE/links/004635303044b40589000000
    Zhou, L., 2002. Adsorption Isotherms for the Supercritical Region. In: Toth, J., ed., Adsorption: Theory, Modeling and Analysis. Surfactant Science Series, 211-250
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