Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 14 Issue 2
Jun 2003
Turn off MathJax
Article Contents
Shucheng Xie, Hongmei Wang, Jianqiu Guo, Bin Liang, Xiugao Zhou. Organic Geochemistry Characteristics in Ores and Host Rocks from Qixiashan Lead-Zinc Deposit, Nanjing, China. Journal of Earth Science, 2003, 14(2): 127-136.
Citation: Shucheng Xie, Hongmei Wang, Jianqiu Guo, Bin Liang, Xiugao Zhou. Organic Geochemistry Characteristics in Ores and Host Rocks from Qixiashan Lead-Zinc Deposit, Nanjing, China. Journal of Earth Science, 2003, 14(2): 127-136.

Organic Geochemistry Characteristics in Ores and Host Rocks from Qixiashan Lead-Zinc Deposit, Nanjing, China

Funds:  This work is financially supported by the project of the Ministry of Education in China
  • Received Date: 20 Feb 2003
  • Accepted Date: 28 Mar 2003
  • Organic matter, associated with ores, host rocks, ore source rocks and present in fluid inclusions in the Qixiashan lead zinc polymetallic deposit hosted in Upper Carboniferous dolomites and limestones in East China, was systematically analyzed using Fourier transform infrared spectroscopy, gas chromatography (GC), GC/mass spectrometry and proton induced X-ray emission. The biomarker ratios of nC21--/nC22+-alkanes, C23-tricyclic/C30-hopane and the tricyclic terpane parameters including C21/C23, C19-20/C21-29 and C19-25/C26-29 can effectively discriminate ores from host rocks. Extractable organic matter present in fluid inclusions displays similarities to those enclosed in the ore source rocks in the biomarker ratios, suggesting that a proportion of organic matter was introduced into the deposit from the ore source strata. The presence of copper and zinc in stage Ⅱ pyrobitumen indicates that some metals may have been transported by an organic fluid or removed from an aqueous fluid by organic matter.

     

  • loading
  • Aquino Neto F R, Trendel J M, Restle A, et al, 1983. Occurrence and Formation of Tricyclic and Tetracyclic Terpanes in Sediments and Petroleums. In: Bjoröy M, ed. Advances in Organic Geochemistry1981. New York: J Wiley and Sons. 659-676
    Bao J P, Wang T G, Wang J Y, 1996. Organic Geochemistry of Marine Paleozoic and Mesozoic in Lower Yangtze. Chongqing: Chongqing University. 1-140(in Chinese)
    Barton P B, 1967. Possible Role of Organic Matter in the Precipitation of the Mississippi Valley Ores. Econ Geol Monogr, 3: 371-378
    Brassell S C, Eglinton G, Maxwell J R, et al, 1978. Natural Background of Alkanes in the Aquatic Environment. In: Hutzinger O, Van Lelyveld I H, Zoeteman B C J, eds. Aquatic Pollutants. Oxford: Pergamon Press. 69-86
    Brooks J D, Gould K, Smith J W, 1969. Isoprenoid Hydrocarbons in Coal and Petroleum. Nature, 222: 257-259 doi: 10.1038/222257a0
    Burnham R, Clarkson J E, Singleton M F, et al, 1982. Biological Markers from Green River Kerogen Decomposition. Geochimica et Cosmochimica Acta, 46: 1243-1251 doi: 10.1016/0016-7037(82)90009-6
    Connan J, 1984. Biodegradation of Crude Oils in Reservoirs. In: Brooks J, Welte D H, eds. Advances in Petroleum Geochemistry. v. 1. London: Academic Press. 299-335
    Connan J, Restle A, Albrecht P, 1980. Biodegradation of Crude Oil in the Aquitaine Basin. Physics and Chemistry of the Earth, 12: 1-17 doi: 10.1016/0079-1946(79)90084-3
    Didyk B M, Simoneit B R T, Brassell S C, et al, 1978. Organic Geochemical Indicators of Palaeoenvironmental Conditions of Sedimentation. Nature, 272: 216-222 doi: 10.1038/272216a0
    Disnar J R, 1996. A Comparison of Mineralization Histories for Two MVT Deposits, Treves and Les Malines (Causses Basin, France), Based on the Geochemistry of Associated Organic Matter. Ore Geology Reviews, 11: 133-156 doi: 10.1016/0169-1368(95)00019-4
    Disnar J R, Sureau J F, 1990. Organic Matter in Ore Genesis, Progress and Perspective. Org Geochem, 16: 577-599 doi: 10.1016/0146-6380(90)90072-8
    Giordano T H, 1994. Metal Transport in Ore Fluids by Organic Ligand Complexation. In: Pittman E D, Lean M D, eds. The Role of Organic Acids in Geological Processes. New York: SpringerVerlag. 319-354
    Giordano T H, 1996. A Special Issue Devoted to Organics and Ore Deposits-Introduction. Ore Geology Reviews, 11: vii-ix doi: 10.1016/0169-1368(95)00012-7
    Grantham P J, Wakefield L L, 1988. Variations in the Sterane Carbon Number Distributions of Marine Source Rock Derived Crude Oils through Geological Time. Org Geochem, 12: 61-73 doi: 10.1016/0146-6380(88)90115-5
    Ho E S, Meyers P A, Mauk J L, 1990. Organic Geochemical Study of Mineralization in the Keweenawan Nonesuch Formation at White Pine, Michigan. Org Geochem, 16: 229-234 doi: 10.1016/0146-6380(90)90043-Y
    Kribek B, 1989. The Role of Organic Matter in the Metallogeny of the Bohemian Massif. Econ Geol, 84: 1525-1540 doi: 10.2113/gsecongeo.84.6.1525
    Leventhal J S, Daws T A, Frye J S, 1986. Organic Geochemistry Analysis of Sedimentary Organic Matter Associated with Uranium. Appl Geochem, 1: 241-247 doi: 10.1016/0883-2927(86)90008-9
    Mackenzie A S, Patience R I, Maxwell J R, et al, 1980. Molecular Parameters of Maturation in the Toarcian Shales, Paris Basin. I. Changes in the Configurations of Acyclic Isoprenoid, Steranes and Triterpanes. Geochim Cosmochim Acta, 44: 1709-1721 doi: 10.1016/0016-7037(80)90222-7
    Macqueen R W, Powell T G, 1983. Organic Geochemistry of the Pine Point Lead-Zinc Ore Field and Region, Northwest Territories. Canada Econ Geol, 78: 1-25 doi: 10.2113/gsecongeo.78.1.1
    Manning D A C, 1986. Assessment of the Role of Organic Matter in Ore Transport Processes in Low-Temperature Base-Metal Systems. Trans Inst Min Metall Sect B, 96: B115-B200
    Manning D A C, Gize A P, 1993. The Role of Organic Matter in Ore Transport Processes. In: Engel M H, Macko S A, eds. Organic Geochemistry-Principles and Applications. New York: Plenum Press. 547-564
    Moldowan J M, Seifert W K, Gallegos E J, 1985. Relationship between Petroleum Composition and Depositional Environment of Petroleum Source Rocks. Am Assoc Petrol Geol Bull, 69: 1255-1268
    Parnell J, Kucha H, Landais P, 1993. Bitumens in Ore Deposits. Berlin: Springer-Verlag. 520
    Peters K E, Moldowan J M, Sundararaman P, 1990. Effects of Hydrous Pyrolysis on Biomarker Thermal Maturity Parameters: Monterey Phosphatic and Siliceous Members. Org Geochem, 15: 249-265 doi: 10.1016/0146-6380(90)90003-I
    Pütmann W, Hagemann H W, Merz C, et al, 1988. Influences of Organic Material on Mineralization Processes in the Permian Kupferschiefer Formation, Poland. Organic Geochemistry, 13: 357-363 doi: 10.1016/0146-6380(88)90056-3
    Radke M, Schaefer R G, Leythaeuser D, et al, 1980. Composition of Soluble Organic Matter in Coals: Relation to Rank and Liptinite Fluorescence. Geochimica et Cosmochimica Acta, 44: 1787-1800 doi: 10.1016/0016-7037(80)90228-8
    Saxby J D, 1976. The Significance of Organic Matter in Ore Genesis. In: Wolf K H, ed. Handbook of Strata-Bound and Stratiform Ore Deposits, v. 1. New York: Elsevier. 111-133
    Sierra M G, Cravero R M, Laborde M A, et al, 1984. Stereoselective Synthesis of (+/-)-18, 19-Dinor-13(H), 14(H)-Cheilanthane: The Most Abundant Tricyclic Compound from Petroleums and Sediments. Journal of the Chemical Society, Chemical Communications, 417-418
    Simoneit B R T, 1990. Organic Matter in Hydrothermal Systems. Appl Geochem, 5: 1-248 doi: 10.1016/0883-2927(90)90030-9
    Ten Haven H L, De Leeuw J W, Rullkotter J, et al, 1987. Restricted Utility of the Pristane/Phytane Ratio as a Palaeoenvironmental Indicator. Nature, 330: 641-643 doi: 10.1038/330641a0
    Tu G C, 1988. Geochemistry of Stratabound Deposits in China v. 3. Beijing: Science Press. 255-297(in Chinese)
    Van Graas G W, 1990. Biomarker Maturity Parameters for High Maturites: Calibration of the Working Range up to the Oil/Condensate Threshold. Organic Geochemistry, 16: 1025-1032 doi: 10.1016/0146-6380(90)90139-Q
    Xiao Z M, 1996. Geology and Prospecting Model for Lead-Zinc Deposit of Qixiashan in Nanjing. Beijing: Geological Publishing House. 160(in Chinese)
    Zhou Z Y, Fan S F, Xia J X, 1991. Enclosed Organic Matter: Another Oil Source in Carbonate Rocks. Sedimentary Acta, (Suppl): 112-119(in Chinese with English Abstract)
    Zumberge J E, 1983. Tricyclic Diterpane Distributions in the Correlation of Paleozoic Crude Oils from the Williston Basin. In: Bjoröy M, ed. Advances in Organic Geochemistry 1981. New York: J Wiley and Sons. 738-745
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(5)  / Tables(1)

    Article Metrics

    Article views(1068) PDF downloads(21) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return