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Volume 25 Issue 3
Jun 2014
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Journal of Earth Science  > 2014  >  25(3): 431-444.
Haizhen Wei, Shaoyong Jiang, Yingkai Xiao, N. Gary Hemming. Boron Isotopic Fractionation and Trace Element Incorporation in Various Species of Modern Corals in Sanya Bay, South China Sea. Journal of Earth Science, 2014, 25(3): 431-444. doi: 10.1007/s12583-014-0438-2
Citation: Haizhen Wei, Shaoyong Jiang, Yingkai Xiao, N. Gary Hemming. Boron Isotopic Fractionation and Trace Element Incorporation in Various Species of Modern Corals in Sanya Bay, South China Sea. Journal of Earth Science, 2014, 25(3): 431-444. doi: 10.1007/s12583-014-0438-2
shu

Boron Isotopic Fractionation and Trace Element Incorporation in Various Species of Modern Corals in Sanya Bay, South China Sea

doi: 10.1007/s12583-014-0438-2
  • 1.

    State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, China

  • 2.

    State Key Laboratory of Geological Processes and Mineral Resources, Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, China

  • 3.

    Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810003, China

  • 4.

    Lamont-Doherty Earth Observatory of Columbia University, Palisades NY 10964-8000, USA

  • 5.

    Queens College School of Earth and Environmental Sciences, Flushing NY 11367, USA

More Information
  • Corresponding author: Shaoyong Jiang, shyjiang@cug.edu.cn
  • Received Date: 22 Jul 2013
  • Accepted Date: 13 Nov 2013
  • Publish Date: 01 Jun 2014
    Abstract
  • The boron isotope paleo-pH proxy has been extensively studied due to its potential for understanding past climate change,and further calibrations were considered for accurate applications of the proxy because of significant variability related to biocarbonate microstructure. In this work,we studied the boron isotopic fractionation between modern marine corals and their coexisting seawater collected along shallow area in Sanya Bay,South China Sea. The apparent partition coefficient of boron (KD) ranged from 0.83×10−3 to 1.69×10−3,which are in good agreement with previous studies. As the analyzed coral skeleton (~5 g) spanned the growth time period of 1–2 years,we discussed the boron isotopic fractionation between pristine corals and modern seawater using the annual mean seawater pH of 8.12 in this sea area. Without taking the vital effect into account,(11B/10B)coral values of all living corals spread over the curves of (11B/10B)borate vs. (11B/10B)sw with the α4−3 values ranging from 0.974 to 0.982. After calibrating the biological effect on the calcifying fluid pH,the field-based calcification on calcifying fluid pH (i.e.,Δ(pHbiol-pHsw)) for coral species of Acropora,Pavona,Pocillopora,Faviidae,and others including Proites are 0.42,0.33,0.36,0.19,respectively,and it is necessary to be validated by coral culturing experiment in the future. Correlations in B/Ca vs. Sr/Ca and B/Ca vs. pHbiol approve temperature and calcifying fluid pH influence on skeletal B/Ca. Fundamental understanding of the thermodynamic basis of the boron isotopes in marine carbonates and seawater will strengthen the confidence in the use of paleo-pH proxy as a powerful tool to monitor atmospheric CO2 variations in the past.

     

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