Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 26 Issue 1
Feb 2015
Turn off MathJax
Article Contents
Journal of Earth Science  > 2015  >  26(1): 149-156.
Xiang Long, Ziyong Sun, Aiguo Zhou, Deliang Liu. Hydrogeochemical and Isotopic Evidence for Flow Paths of Karst Waters Collected in the Heshang Cave, Central China. Journal of Earth Science, 2015, 26(1): 149-156. doi: 10.1007/s12583-015-0522-2
Citation: Xiang Long, Ziyong Sun, Aiguo Zhou, Deliang Liu. Hydrogeochemical and Isotopic Evidence for Flow Paths of Karst Waters Collected in the Heshang Cave, Central China. Journal of Earth Science, 2015, 26(1): 149-156. doi: 10.1007/s12583-015-0522-2
shu

Hydrogeochemical and Isotopic Evidence for Flow Paths of Karst Waters Collected in the Heshang Cave, Central China

doi: 10.1007/s12583-015-0522-2

  • School of Environmental Studies, China University of Geosciences, Wuhan 430074, China

More Information
  • Corresponding author: Ziyong Sun, ziyong.sun@gmail.com
  • Received Date: 11 Aug 2014
  • Accepted Date: 01 Dec 2014
  • Publish Date: 01 Jan 2015
    Abstract
  • Understanding of hydrological processes in caves is important to help us interpret paleoclimate records from speleothems. In this study, we integrated hydrogeological and hydrogeochemical properties to characterize the hydraulic behavior of karst waters in the Heshang Cave, Central China. Using geological and topographical analyses, we identified regional watershed boundaries and hydrogeological connections that were controlled by anticlinal geometry and faults. Water samples were collected from the Heshang Cave and potential recharge sites. Geochemical data of c(Sr2+)/c(Ca2+) and c(Mg2+)/c(Ca2+) ratios suggest that the drainage system in Heshang Cave consists of two flow paths. For vadose waters, including drip water and rimstone pool water, c(Sr2+)/c(Ca2+) ratio ranges from 0.000 6 to 0.001 1, and c(Mg2+)/c(Ca2+) ratio ranges from 0.97 to 1.1, indicating that recharge was mainly from rainfall infiltration through the overlying Cambrian dolomite stratum. In contrast, slope current and underground river waters have higher c(Sr2+)/c(Ca2+) ratios (values from 0.002 2 to 0.002 8), and lower c(Mg2+)/c(Ca2+) ratios (values from 0.50 to 0.64). These waters show homogeneous isotopic composition (δ18O: −7.15‰– −6.95‰; δD: −52.73‰– −51.31‰), implying recharge of allogeneic water from the Xiaoer River via karst conduits that pass through Ordovician limestone and Cambrian dolomite stratum.

     

    • FullText(HTML)
  • loading
    • References(28)
  • Bakalowicz, M., 2005. Karst Groundwater: A Challenge for New Resources. Hydrogeology Journal, 13(1): 148-160 doi: 10.1007/s10040-004-0402-9
    Bakers, A., Brunsdon, C., 2003. Non-Linearities in Drip Water Hydrology: An Example from Stump Cross Caverns, Yorkshire. Journal of Hydrology, 277(3-4): 151-163 doi: 10.1016/S0022-1694(03)00063-5
    Baldini, J. U. L., McDermott, F., Fairchild, I. J., 2006. Spatial Variability in Cave Drip Water Hydrochemistry: Implications for Stalagmite Paleoclimate Records. Chemical Geology, 235(3-4): 390-404 doi: 10.1016/j.chemgeo.2006.08.005
    Barbieri, M., Boschetti, T., Petitta, M., et al., 2005. Stable Isotope (2H, 18O and 87Sr/86Sr) and Hydrochemistry Monitoring for Groundwater Hydrodynamics Analysis in a Karst Aquifer (Gran Sasso, Central Italy). Applied Geochemistry, 20(11): 2063-2081 doi: 10.1016/j.apgeochem.2005.07.008
    Fairchild, I. J., Borsato, A., Tooth, A. F., et al., 2000. Controls on Trace Element (Sr-Mg) Compositions of Carbonate Cave Waters: Implications for Speleothem Climatic Records. Chemical Geology, 166(3-4): 255-269 doi: 10.1016/S0009-2541(99)00216-8
    Fairchild, I. J., Tuckwell, G. W., Baker, A., et al., 2006. Modelling of Dripwater Hydrology and Hydrogeo- chemistry in a Weakly Karstified Aquifer (Bath, UK): Implications for Climate Change Studies. Journal of Hydrology, 321(1-4): 213-231 doi: 10.1016/j.jhydrol.2005.08.002
    Genty, D., Deflandre, G., 1998. Drip Flow Variations under a Stalactite of the Pere Noel Cave (Belgium). Evidence of Seasonal Variations and Air Pressure Constraints. Journal of Hydrology, 211(1-4): 208-232 doi: 10.1016/S0022-1694(98)00235-2
    Han, G. L., Liu, C. Q., 2004. Water Geochemistry Controlled by Carbonate Dissolution: A Study of the River Waters Draining Karst-Dominated Terrain, Guizhou Province, China. Chemical Geology, 204(1-2): 1-21 doi: 10.1016/j.chemgeo.2003.09.009
    Hu, C. Y., Henderson, G. M., Huang, J. H., et al., 2008a. Report of a Three-Year Monitoring Programme at Heshang Cave, Central China. International Journal of Speleology, 37(3): 143-151 doi: 10.5038/1827-806X.37.3.1
    Hu, C. Y., Henderson, G. M., Huang, J. H., et al., 2008b. Quantification of Holocene Asian Monsoon Rainfall from Spatially Separated Cave Records. Earth and Planetary Science Letters, 266(3-4): 221-232 doi: 10.1016/j.epsl.2007.10.015
    Hu, C. Y., Huang, J. H., Fang, N. Q., et al., 2005. Adsorbed Silica in Stalagmite Carbonate and Its Relationship to Past Rainfall. Geochimica et Cosmochimica Acta, 69(9): 2285-2292 doi: 10.1016/j.gca.2004.10.029
    Johnson, K. R., Hu, C. Y., Belshaw, N. S., et al., 2006. Seasonal Trace-Element and Stable-Isotope Variations in a Chinese Speleothem: The Potential for High-Resolution Paleomonsoon Reconstruction. Earth and Planetary Science Letters, 244(1-2): 394-407 doi: 10.1016/j.epsl.2006.01.064
    Karst Research Group, 1978. Karst Research of China. Science Press, Beijing (in Chinese)
    Kattan, Z., 2001. Use of Hydrochemistry and Environmental Isotopes for Evaluation of Groundwater in the Paleogene Limestone Aquifer of the Ras Al-Ain Area (Syrian Jezireh). Environmental Geology, 41(1-2): 128-144 doi: 10.1007/s002540100354
    Katz, B. G., Bullen, T. D., 1996. The Combined Use of Sr-87/Sr-86 and Carbon and Water Isotopes to Study the Hydrochemical Interaction between Groundwater and Lakewater in Mantled Karst. Geochimica et Cosmochimica Acta, 60(24): 5075-5087 doi: 10.1016/S0016-7037(96)00296-7
    Li, B., Yuan, D. X., Qin, J. M., et al., 2000. Oxygen and Carbon Isotopic Characteristics of Rainwater, Drip Water and Present Speleothems in a Cave in Guilin Area, and Their Environmental Meanings. Science in China Series D: Earth Sciences, 43(3): 277-285 doi: 10.1007/BF02906823
    Ma, T., Wang, Y. X., Guo, Q. H., et al., 2009. Hydrochemical and Isotopic Evidence of Origin of Thermal Karst Water at Taiyuan, Northern China. Journal of Earth Science, 20(5): 879-889 doi: 10.1007/s12583-009-0074-4
    Marfia, A. M., Krishnamurthy, R. V., Atekwana, E. A., et al., 2004. Isotopic and Geochemical Evolution of Ground and Surface Waters in a Karst Dominated Geological Setting: A Case Study from Belize, Central America. Applied Geochemistry, 19(6): 937-946 doi: 10.1016/j.apgeochem.2003.10.013
    McDonald, J., Drysdale, R., Hill, D., 2004. The 2002-2003 El Nino Recorded in Australian Cave Drip Waters: Implications for Reconstructing Rainfall Histories Using Stalagmites. Geophysical Research Letters, 31(22): L22202
    Partin, J. W., Cobb, K. M., Adkins, J. F., et al., 2013. Trace Metal and Carbon Isotopic Variations in Cave Dripwater and Stalagmite Geochemistry from Northern Borneo. Geochemistry, Geophysics, Geosystems, 14(9): 3567-3585 doi: 10.1002/ggge.20215
    Perez, J. J., Sanz, E., 2011. Hydrodynamic Characteristics and Sustainable Use of a Karst Aquifer of High Environmental Value in the Cabrejas Range (Soria, Spain). Environmental Earth Sciences, 62(3): 467-479 doi: 10.1007/s12665-010-0540-4
    Pu, J. B., Yuan, D. X., Zhang, C., et al., 2012. Tracing the Sources of Strontium in Karst Groundwater in Chongqing, China: A Combined Hydrogeochemical Approach and Strontium Isotope. Environmental Earth Sciences, 67(8): 2371-2381 doi: 10.1007/s12665-012-1683-2
    Ravbar, N., Barbera, J. A., Petric, M., et al., 2012. The Study of Hydrodynamic Behaviour of a Complex Karst System under Low-Flow Conditions Using Natural and Artificial Tracers (the Catchment of the Unica River, SW Slovenia). Environmental Earth Sciences, 65(8): 2259-2272 doi: 10.1007/s12665-012-1523-4
    Ruan, J. Y., Hu, C. Y., 2010. Seasonal Variations and Environmental Controls on Stalagmite Calcite Crystal Growth in Heshang Cave, Central China. Chinese Science Bulletin, 55(34): 3929-3935 doi: 10.1007/s11434-010-4193-1
    Wan, J. W., Shen, J. F., Chao, N., 1997. The Characteristics of Karst Cave Development and Tourism Resources in Banxia Area of the Qingjiang River. Carsologica Sinica, 16(3): 268-278 (in Chinese with English Abstract)
    Wu, P., Tang, C. Y., Zhu, L. J., et al., 2009. Hydrogeochemical Characteristics of Surface Water and Groundwater in the Karst Basin, Southwest China. Hydrological Processes, 23(14): 2012-2022 doi: 10.1002/hyp.7332
    Yamada, M., Ohsawa, S., Matsuoka, H., et al., 2008. Derivation of Travel Time of Limestone Cave Drip Water Using Tritium/Helium 3 Dating Method. Geophysical Research Letters, 35(8): L08405 doi: 10.1029/2008GL033237/full
    Zhao, J. C., Wei, B. H., Xiao, S. B., 2009. Stable Isotopic Characteristics of Atmospheric Precipitation from Yichang, Hubei. Tropical Geography, 29(6): 526-531 (in Chinese with English Abstract)
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(7)  / Tables(1)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views(745) PDF downloads(196) Cited by()
    Proportional views
    Related

    Copyright © 2013-2020 Journal of Earth Science 鄂ICP备15021562号-2

    Tel: +86-27-67885075 Fax: +86-27-67885075 E-mail: xbb@cug.edu.cn

    Address: Editorial Office of Journal, China University of Geosciences, Yujiashan, Wuhan, Hubei 430074, P. R. China

    Supported by: Beijing Renhe Information Technology Co. Ltd  E-mail: info@rhhz.net  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return