Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 27 Issue 2
Mar 2016
Turn off MathJax
Article Contents
Hong Xin, Shaoyong Jiang, Jinghong Yang, Heping Wu, Daohui Pi. Rare Earth Element Geochemistry of Phosphatic Rocks in Neoproterozoic Ediacaran Doushantuo Formation in Hushan Section from the Yangtze Gorges Area, South China. Journal of Earth Science, 2016, 27(2): 204-210. doi: 10.1007/s12583-015-0653-5
Citation: Hong Xin, Shaoyong Jiang, Jinghong Yang, Heping Wu, Daohui Pi. Rare Earth Element Geochemistry of Phosphatic Rocks in Neoproterozoic Ediacaran Doushantuo Formation in Hushan Section from the Yangtze Gorges Area, South China. Journal of Earth Science, 2016, 27(2): 204-210. doi: 10.1007/s12583-015-0653-5

Rare Earth Element Geochemistry of Phosphatic Rocks in Neoproterozoic Ediacaran Doushantuo Formation in Hushan Section from the Yangtze Gorges Area, South China

doi: 10.1007/s12583-015-0653-5
More Information
  • Corresponding author: Shaoyong Jiang, shyjiang@cug.edu.cn
  • Received Date: 19 Apr 2015
  • Accepted Date: 01 Jul 2015
  • Publish Date: 01 Apr 2016
  • Phosphatic rocks are widely distributed in Neoproterozoic Ediacaran Doushantuo Formation in Yangtze Gorges Area, South China. In this study, rare earth element geochemistry of eight phosphatic rock samples from the Hushan Section has been studied. All the samples display typical hat-shaped REE patterns, moderate negative Ce anomalies (Ce/Ce*=0.55 to 0.67), slightly positive Eu anomalies (Eu/Eu*=1.05 to 1.22) and low Y/Ho ratios (38.2±5.6). The hat-shaped REE patterns indicate diagenetic alteration of the primary REE signatures, which coincides with detrital siliciclastic sources of REE based on the Y/Ho ratios. The degree of Negative Ce anomalies and positive Eu anomalies may have recorded the redox features of diagenetic fluids, suggesting an anoxic environment during the phosphogenesis processes in Neoproterozoic Ediacaran Doushantuo Formation, South China. The geochemical comparison between the Lower Phosphorite Layer and Upper Phosphorite Layer at Hushan indicates a greater degree of diagenesis occurred in the Upper Layer than the Lower one. Besides the terrigenous sources of REE, organic materials could have also played a role on the REE characteristics.

     

  • loading
  • Alibo, D. S., Nozaki, Y., 1999. Rare Earth Elements in Seawater: Particle Association, Shale-Normalization, and Ce Oxidation. Geochimica Et Cosmochimica Acta, 63: 363-372 doi: 10.1016/S0016-7037(98)00279-8
    Bau, M., Dulski, P., 1996. Distribution of Yttrium and Rare-Earth Elements in the Penge and Kuruman Iron-Formations, Transvaal Supergroup South Africa. Precambrian Research, 79: 37-55 doi: 10.1016/0301-9268(95)00087-9
    Condon, D., Zhu, M., Bowring, S., et al., 2005. U-Pb Ages from the Neoproterozoic Doushantuo Formation, China. Science, 308: 95-98 doi: 10.1126/science.1107765
    De Baar, H. J. W., Bacon, M. P., Brewer, P. G., 1985. Rare Earth Elements in Pacific and Atlantic Oceans. Geochimica et Cosmochimica Acta, 49: 1943-1959 doi: 10.1016/0016-7037(85)90089-4
    Felitsyn, S., Morad, S., 2002. REE Patterns in Latest Neoproterozoic-Early Cambrian Phosphate Concretions and Associated Organic Matter. Chemical Geology, 187: 257- 265 doi: 10.1016/S0009-2541(02)00046-3
    Gnandi, K., Tobschall, H. J., 2003. Distribution Patterns of Rare-Earth Elements and Uranium in Tertiary Sedimentary Phosphorites of HahotoÉ-KpogamÉ, Togo. Journal of African Earth Sciences, 37: 1-10 doi: 10.1016/j.jafrearsci.2003.08.002
    German, C. R., Holliday, B. P., Elderfield, H., 1991. Redox Cycling of Rare-Earth Ele-Ments in the Suboxic Zone of the Black-Sea. Geochimica Et Cosmochimica Acta, 55: 3553-3558 doi: 10.1016/0016-7037(91)90055-A
    Ilyin, A. V., 1998. Rare-Earth Geochemistry of 'Old' Phosphorites and Probability of Syngenetic Precipitation and Accumulation of Phosphate. Chemical Geology, 144: 243-256 doi: 10.1016/S0009-2541(97)00134-4
    Jarvis, I., Burnett, W., Nathan, Y., et al., 1994. Phosphorite Geochemistry: State-of-the-Art and Environmental Concerns. Eclogae Geologicae Helvetiae, 87: 643-700 http://www.researchgate.net/publication/279905385_Phosphorite_geochemistry_state-of-the-art_and_environmental_concerns
    Jiang, S. Y., Zhao, H. X., Chen, Y. Q., et al., 2007. Trace and Rare Earth Element Geochemistry of Phosphate Nodules from the Lower Cambrian Black Shale Sequence in the Mufu Mountain of Nanjing, Jiangsu Province, China. Chemical Geology, 244: 584-604 doi: 10.1016/j.chemgeo.2007.07.010
    Kidder, D., Krishnaswamy, R., Mapes, R. H., 2003. Elemental Mobility in Phosphatic Shales during Concretion Growth and Implication for Provenance Analysis. Chemical Geology, 198: 335-353 doi: 10.1016/S0009-2541(03)00036-6
    Li, C., Chen, J., Hua, T., 1998. Precambrian Sponges with Cellular Structures. Science, 279: 879-882 doi: 10.1126/science.279.5352.879
    Ling, H. F., Chen, X., Li, D., et al., 2013. Cerium Anomaly Variations in Ediacaran-Earliest Cambrian Carbonates from the Yangtze Gorges Area, South China: Implications for Oxygenation of Coeval Shallow Seawater. Precambrian Research, 225: 110-127 doi: 10.1016/j.precamres.2011.10.011
    Liu, P., Yin, C., Gao, L., et al., 2009. New Material of Microfossils from the Ediacaran Doushantuo Formation in the Zhangcunping Area, Yichang, Hubei Province and Its Zircon SHRIMP U-Pb Age. Chinese Science Bulletin, 54(6): 1058-1064 http://www.bioone.org/servlet/linkout?suffix=i0022-3360-88-1-1-Liu7&dbid=16&doi=10.1666%2F12-157R&key=10.1007%2Fs11434-008-0589-6
    Mazumdar A., Banerjee D. M., Schidlowski M., Balaram V., 1999. Rare-Earth Elements and Stable Isotope Geochemistry of Early Cambrian Chert-Phosphorite Assemblages from the Lower Tal Formation of the Krol Belt (Lesser Himalaya, india). Chemical Geology, 156: 275-297 doi: 10.1016/S0009-2541(98)00187-9
    McArthur, J. M., Walsh, J. N., 1984. Rare-Earth Element Geochemistry of Phosphorites. Chemical Geology, 47: 191-220 doi: 10.1016/0009-2541(84)90126-8
    McLennan, S. M., 1989. Rare-Earth Elements in Sedimentary-Rocks-Influence of Provenance and Sedimentary Processes. Review in Mineralogy, 21: 169-200 http://www.researchgate.net/publication/313503357_Rare_earth_elements_in_sedimentary_rocks_influence_of_provenance_and_sedimentary_processes
    Morad, S., Felitsyn, S., 2001. Identification of Primary Ce-Anomaly Signatures in Fossil Biogenic Apatite: Implication for the Cambrian Oceanic Anoxia and Phosphogenesis. Sedimentary Geology, 143: 259-264 doi: 10.1016/S0037-0738(01)00093-8
    Muscente, A. D., Hawkins, A. D., Xiao, S., 2014. Fossil Preservation through Phosphatization and Silicification in the Ediacaran Doushantuo Formation (South China): A Comparative Synthesis. Palaeogeography, Palaeoclimatology, Palaeoecology, 434: 46-62 http://www.sciencedirect.com/science/article/pii/S0031018214005173
    Ogihara, S., 1999. Geochemical Characteristics of Phosphorite and Carbonate Nodules from the Miocene Funakawa Formation, Western Margin of the Yokote Basin, Northeast Japan. Sedimentary Geology, 125: 69-82 doi: 10.1016/S0037-0738(98)00136-5
    Paytan, A., McLaughlin, K., 2007. The Oceanic Phosphorus Cycle. Chemical Review, 107: 563-576 doi: 10.1021/cr0503613
    Pi, D. H., Liu, C. Q., Graham A. et al., 2013. Trace and Rare Earth Element Geochemistry of Black Shale and Kerogen in the Early Cambrian Niutitang Formation in Guizhou Province, South China: Constraints for Redox Environments and Origin of Metal Enrichments. Precambrian Research, 225: 218-229 doi: 10.1016/j.precamres.2011.07.004
    Rasmussen, B., Buick, R., Taylor, W. R., 1998. Removal of Oceanic REE by Authigenic Precipitation of Phosphatic Minerals. Earth and Planetary Science Letters, 164: 135-149 doi: 10.1016/S0012-821X(98)00199-X
    Reynard, B., LÉCuyer, C., Grandjean, P., 1999. Crystal-Chemical Controls on Rare-Earth Element Concentrations in Fossil Biogenic Apatites and Implications for Paleoenvironmental Reconstructions. Chemical Geology, 155: 233-241 doi: 10.1016/S0009-2541(98)00169-7
    Sawaki, Y., Ohno, T., Tahata, M., et al., 2010. The Ediacaran Radiogenic Sr Isotope Excursion in the Doushantuo Formation in the Three Gorges Area, South China. Precambrian Research, 176 (1-4): 46-64 doi: 10.1016/j.precamres.2009.10.006
    Shields, G., Stille, P., 2001. Diagenetic Constraints on the Use of Cerium Anomalies as Palaeoseawater Redox Proxies: An Isotopic and REE Study of Cambrian Phosphorites. Chemical Geology, 175: 29-48 doi: 10.1016/S0009-2541(00)00362-4
    Sholkovitz, E. R., Landing, W. M., Lewis, B. L., 1994. Ocean Particle Chemistry-the Fractionation of Rare-Earth Elements between Suspended Particles and Seawater. Geochimica Et Cosmochimica Acta, 58: 1567-1579 doi: 10.1016/0016-7037(94)90559-2
    Shields, G. A., Webb G. E., 2004. Has the REE Composition of Seawater Changed over Geological Time? Chemical Geology, 204: 103-107 doi: 10.1016/j.chemgeo.2003.09.010
    Trappe, J., 1998. Phanerozoic Phosphorite Depositional Systems. Lecture Notes in Earth Sciences, 76. Springer, Berlin. http://adsabs.harvard.edu/abs/1998LNES...76.....T
    Wang, X. F., Erdtmann, B. D., Chen, X. H., et al., 1998. Integrated Sequence, Bio-and Chemo-Stratigraphy of the Terminal Proterozoic to Lowermost Cambrian Black Rock Series from Central South China. Episodes, 21 (3): 178-189 doi: 10.18814/epiiugs/1998/v21i3/007
    Webb, G. E., Kamber, B. S., 2000. Rare Earth Elements in Holocene Reefal Microbialites: A New Shallow Seawater Proxy. Geochimica et Cosmochimica Acta, 64: 1557-1565 doi: 10.1016/S0016-7037(99)00400-7
    Wei, H. Z., Jiang, S. Y., Xiao, Y. K., et al., 2014. Boron Isotopic Fractionation and Trace Element Incorporation in Various Species of Modern Corals in Sanya Bay, South China Sea. Journal of Earth Science, 25(3): 431-444 doi: 10.1007/s12583-014-0438-2
    Wright, J., Schrader, H., Holser, W. T., 1987. Paleoredox Variations in Ancient Oceans Recorded by Rare Earth Elements in Fossil Apatite. Geochimica Et Cosmochimica Acta, 51: 631-644 doi: 10.1016/0016-7037(87)90075-5
    Xiao, S., Yuan, X., Steiner, M., Knoll, A. H., 2002. Macroscopic Carbonaceous Compressions in a Terminal Proterozoic Shale: A Systematic ReAssessment of the Miaohe Biota, South China. Journal of Paleontology, 76: 347-376 doi: 10.1017/S0022336000041743
    Xiao, S., Zhang, Y., Knoll, A. H., 1998. Three-Dimensional Preservation of Algae and Animal Embryos in a Neoproterozoic Phosphorite. Nature, 391: 553-558 doi: 10.1038/35318
    Xin, H., Jiang, S. Y., Yang, J. H., et al., 2015. Rare Earth Element and Sr-Nd Isotope Geochemistry of Phosphatic Rocks in Neoproterozoic Ediacaran Doushantuo Formation in Zhangcunping Section from Western Hubei Province, South China. Palaeogeography, Palaeoclimatology, Palaeoecology, 440: 712-724 doi: 10.1016/j.palaeo.2015.09.034
    Yin, L., Zhu, M., Knoll, A. H., et al., 2007. Doushantuo Embryos Preserved inside Diapause Egg Cysts. Nature, 446: 661-663 doi: 10.1038/nature05682
    Yuan, X., Chen, Z., Xiao, S., Zhou, C., Hua, H., 2011. An Early Ediacaran Assemblage of Macroscopic and Morphologically Differentiated Eukaryotes. Nature, 470: 390-393 doi: 10.1038/nature09810
    Zhang, J., Nozaki, Y., 1996. Rare Earth Elements and Yttrium in Seawater: ICP-MS Determinations in the East Caroline, Coral Sea, and South Fiji Basins of the Western South Pacific Ocean. Geochimica Et Cosmochimica Acta, 60: 4631-4644 doi: 10.1016/S0016-7037(96)00276-1
    Zhao, L. S., Chen, Z. Q., Algeo, T. J., et al., 2013. Rare-Earth Element Patterns in Conodont Albid Crowns: Evidence for Massive Inputs of Volcanic Ash during the Latest Permian Biocrisis? Global and Planetary Change, 105: 135-151 doi: 10.1016/j.gloplacha.2012.09.001
    Zhou, C., Xie, G., Xiao, S., 2005. New Data of Microfossils from Doushantuo Formation at Zhangcunping in Yichang, Hubei Province. Acta Micropalaeontologica Sinica, 22(3): 217-224 (in Chinese with English Abstract) http://europepmc.org/abstract/cba/596008
    Zhu, B., Becker, H., Jiang, S. Y., et al., 2013. Re-Os Geochronology of Black Shales from the Neoproterozoic Doushantuo Formation, Yangtze Platform, South China. Precambrian Research, 225: 69-76 http://www.sciencedirect.com/science/article/pii/S0301926812000460
    Zhu, B., Jiang S. Y., Yang, J. H., et al., 2014. Rare Earth Element and Sr-Nd Isotope Geochemistry of Phosphate Nodules from the Lower Cambrian Niutitang Formation, NW Hunan Province, South China. Palaeogeography, Palaeoclimatology, Palaeoecology, 398: 132-143 doi: 10.1016/j.palaeo.2013.10.002
    Zhu, M. Y., Lu, M., Zhang, J. M., et al., 2013. Carbon Isotope Chemostratigraphy and Sedimentary Facies Evolution of the Ediacaran Doushantuo Formation in Western Hubei, South China. Precambrian Research, 225: 7-28 doi: 10.1016/j.precamres.2011.07.019
    Zhu, M. Y., Zhang, J. M., Steiner, M., et al., 2003. Sinian-Cambrian Stratigraphic Framework for Shallow-to Deep-Water Environments of the Yangtze Platform: an Integrated Approach. Progress in Natural Science, 13: 951-960 doi: 10.1080/10020070312331344710
    Zhu, M. Y., Zhang, J. M., Yang, A. H, 2007. Integrated Ediacaran (Sinian) Chronostratigraphy of South China. Palaeogeography, Palaeoclimatology, Palaeoecology, 254: 7-61 doi: 10.1016/j.palaeo.2007.03.025
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(5)  / Tables(1)

    Article Metrics

    Article views(950) PDF downloads(214) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return