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Volume 29 Issue 2
Mar 2018
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Yang Yang, Fuhong Gao, Changwei Chen, Xiugang Pu. A Transgressive Depositional Setting for the Paleogene Shahejie Formation in the Qikou Depression, Eastern China: Inferences from the REE Geochemistry of Carbonates. Journal of Earth Science, 2018, 29(2): 326-341. doi: 10.1007/s12583-017-0759-z
Citation: Yang Yang, Fuhong Gao, Changwei Chen, Xiugang Pu. A Transgressive Depositional Setting for the Paleogene Shahejie Formation in the Qikou Depression, Eastern China: Inferences from the REE Geochemistry of Carbonates. Journal of Earth Science, 2018, 29(2): 326-341. doi: 10.1007/s12583-017-0759-z

A Transgressive Depositional Setting for the Paleogene Shahejie Formation in the Qikou Depression, Eastern China: Inferences from the REE Geochemistry of Carbonates

doi: 10.1007/s12583-017-0759-z
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  • Corresponding author: Fuhong Gao, gaofh@jlu.edu.cn
  • Received Date: 05 Mar 2016
  • Accepted Date: 14 Dec 2016
  • Publish Date: 01 Feb 2018
  • Rare earth element (REE) and Y concentrations, and 87Sr/86Sr ratios were analyzed in 33 carbonate samples from the Paleogene Shahejie Formation in the Qikou depression, eastern China, with the goal of determining depositional environments and post-depositional conditions of carbonates in the region. The REE and Y concentrations were normalized to the post-Archean Australian shale (PAAS) standard. The La *PAAS/Yb*PAAS ratios of 0.35–1.52, where *PAAS indicates values for the PAAS standard, show light REE enrichment and heavy REE depletion in most samples. Values of La *PAAS (0.775–1.284) and Ce *PAAS (0.822–1.224), coupled with a relatively flat REE distribution, indicate that the Shahejie carbonates were deposited in lacustrine environments. Values of Y anomalies (1.009–1.527) and Y/Ho ratios (28.43–45.00) in the Shahejie Formation are greater than those of lacustrine carbonates and closer to those of marine carbonates, indicating that diagenetic fluids were probably influenced by seawater. In the carbonates from Well Kou-42, Eu anomalies (1.171–1.604), 87Sr/86Sr ratios (0.708 001–0.710 893), and high homogenization temperatures (104–151 C) suggest that the carbonates were affected by hydrothermal fluids. The REEs and Sr isotope ratios show that the carbonates from the Shahejie Formation in the Qikou depression were deposited in lacustrine environments, and were influenced by seawater and hydrothermal fluids.

     

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