Sphalerite Rb-Sr Dating and <i>in situ</i> Sulfur Isotope Analysis of the Daliangzi Lead-Zinc Deposit in Sichuan Province, SW China

Wenhao Liu; Xiaojun Zhang; Jun Zhang; Manrong Jiang

doi:10.1007/s12583-018-0785-5

Volume 29 Issue 3

Aug 2018

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Journal of Earth Science > 2018 > 29(3): 573-586.

Wenhao Liu, Xiaojun Zhang, Jun Zhang, Manrong Jiang. Sphalerite Rb-Sr Dating and in situ Sulfur Isotope Analysis of the Daliangzi Lead-Zinc Deposit in Sichuan Province, SW China. Journal of Earth Science, 2018, 29(3): 573-586. doi: 10.1007/s12583-018-0785-5

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Wenhao Liu, Xiaojun Zhang, Jun Zhang, Manrong Jiang. Sphalerite Rb-Sr Dating and in situ Sulfur Isotope Analysis of the Daliangzi Lead-Zinc Deposit in Sichuan Province, SW China. Journal of Earth Science, 2018, 29(3): 573-586. doi: 10.1007/s12583-018-0785-5

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Sphalerite Rb-Sr Dating and in situ Sulfur Isotope Analysis of the Daliangzi Lead-Zinc Deposit in Sichuan Province, SW China

doi: 10.1007/s12583-018-0785-5

1.
Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, China
2.
Institute of Geological Survey, China University of Geosciences, Wuhan 430074, China

More Information

Corresponding author: Xiaojun Zhang, xjzhang01@cug.edu.cn
Received Date: 15 May 2017
Accepted Date: 17 Sep 2017
Publish Date: 01 Jun 2018

Abstract

Abstract

This study reports the sphalerite Rb-Sr age and LA-MC-ICP-MS in situ sulfur isotope analysis results of the Daliangzi Lead-Zinc Deposit in the Sichuan-Yunnan-Guizhou (SYG) triangle. Sphalerite Rb-Sr dating yields a Mississippian age of 345.2±3.6 Ma (MSWD=1.4), which is older than the published Late Triassic mineralization ages (230-200 Ma) of some other deposits. This indicates that at least two stages of lead-zinc mineralization have occurred in the SYG lead-zinc triangle. The first stage occurred in the Mississippian under an extensional environment, while the second stage occurred in the Late Triassic under a compressional environment. In situ sulfur isotope analysis of sphalerite growth zoning presents relatively large δ³⁴S values of 11.3‰-15.2‰ with small variations. The large δ³⁴S values indicate a reduced sulfur source of thermochemical reduction of seawater sulfates. Abundant organic matter in the black fracture zone possibly supplied reductants for thermochemical sulfate reduction (TSR) at the mineralization site. The small variation of δ³⁴S values suggests a slow and stable TSR process that could prevent the sudden supersaturation of sphalerite in the fluid and the resulting of fast participation. This is consistent with the well-crystallized characteristic of the sphalerite of the Daliangzi Deposit.
- sphalerite Rb-Sr,
- in situ sulfur isotope,
- thermochemical reduction,
- Daliangzi,
- Mississippi Valley-type

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References(77)

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