Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone

Tianlei Zhai; Shengxuan Huang; Shan Qin; Jingjing Niu; Yu Gong

doi:10.1007/s12583-021-1410-6

Volume 32 Issue 4

Aug 2021

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Journal of Earth Science > 2021 > 32(4): 880-886.

Tianlei Zhai, Shengxuan Huang, Shan Qin, Jingjing Niu, Yu Gong. Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone. Journal of Earth Science, 2021, 32(4): 880-886. doi: 10.1007/s12583-021-1410-6

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Tianlei Zhai, Shengxuan Huang, Shan Qin, Jingjing Niu, Yu Gong. Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone. Journal of Earth Science, 2021, 32(4): 880-886. doi: 10.1007/s12583-021-1410-6

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Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone

doi: 10.1007/s12583-021-1410-6

1.
Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Sciences, Peking University, Beijing 100871, China
2.
Key Laboratory of Continental Collision and Plateau Uplift, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China
3.
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100094, China

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Corresponding author: Shan Qin, sqin@pku.edu.cn
Received Date: 14 Oct 2020
Accepted Date: 03 Jan 2021
Publish Date: 16 Aug 2021

Abstract

Abstract

Carbonates are considered to be important hosts of oxidized carbon during subduction processes. Here we investigate the redox interactions between dolomite and metallic iron in laser-heated diamond anvil cells up to ~20 GPa. The identification of recovered samples via in-situ synchrotron X-ray diffraction and ex-situ Raman spectroscopy shows that the reaction occurs with the formation of ferropericlase, graphite and hexagonal diamond, while CaCO₃ remains stable. The experimental results indicate dolomite and metallic iron phases cannot coexist and demonstrate a possible formation mechanism of ultradeep diamonds via redox reaction between dolomite and iron under the mantle transition zone conditions. The results are significant for understanding carbon transportation during subduction processes and have further implications to the processes in the more complex systems regarding to carbonate-silicate-metal phase relations.
- deep carbon cycle,
- carbonates,
- interaction,
- dolomite,
- high pressure

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References(57)

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Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone

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Redox-Induced Destabilization of Dolomite at Earth's Mantle Transition Zone

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