Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 33 Issue 1
Feb 2022
Turn off MathJax
Article Contents
Journal of Earth Science  > 2022  >  33(1): 82-91.
Dandan Li, Sheng-Ao Liu. Copper Isotope Fractionation during Basalt Leaching at 25℃ and pH=0.3, 2. Journal of Earth Science, 2022, 33(1): 82-91. doi: 10.1007/s12583-021-1499-7
Citation: Dandan Li, Sheng-Ao Liu. Copper Isotope Fractionation during Basalt Leaching at 25℃ and pH=0.3, 2. Journal of Earth Science, 2022, 33(1): 82-91. doi: 10.1007/s12583-021-1499-7
shu

Copper Isotope Fractionation during Basalt Leaching at 25℃ and pH=0.3, 2

doi: 10.1007/s12583-021-1499-7

  • State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China

More Information
  • Corresponding author: Dandan Li, ldd@cugb.edu.cn
  • Received Date: 26 Apr 2021
  • Accepted Date: 13 Jun 2021
  • Publish Date: 28 Feb 2022
    Abstract
  • The geochemical cycling of copper in the hydrosphere and soil environments primarily involves the transport of Cu from rocks to rivers via weathering. Understanding the factors controlling Cu isotope fractionation during weathering is crucial for the purpose of using Cu isotopes as a tracer of geochemical cycling. Here, we performed acid-leaching experiments on natural basalts (BHVO-2 and GBW07105) and chalcopyrite in Erlenmeyer flasks at T=25 ℃ and different pH values (0.3 and 2). Our results reveal substantial Cu isotope fractionations (Δ65Cusolution-initial) between leachates (Cusolution) and starting materials (Cuinitial). The leachates released from GBW07105 and chalcopyrite are consistently enriched in heavier Cu isotopes relative to the starting materials at pH=2. However, the δ65Cusolution values decrease to about -0.6‰ first, then increase to >0 for BHVO-2 at pH=2 and GBW07105 at pH=0.3. Our results indicate that leaching of natural rocks by acidic liquids can produce both positive and negative Cu isotope fractionation, depending on pH values and the types of minerals in starting materials. X-ray power diffraction analysis (XRD) patterns reveal similar mineral assemblages between starting basalts and residues after each reaction round. The most likely mechanisms responsible for such Cu isotope fractionation are the relative rates of Cu oxidation at the surface and Cu release into solution, and the sequence of mineral dissolution. Our study represents an important step for future studies to use Cu isotopes to explain Cu isotopic variations in natural rocks and waters.

     

    • Electronic Supplementary Materials: Supplementary materials (Tables S1-S4) are available in the online version of this article at https://doi.org/10.1007/s12583-021-1499-7.
    FullText(HTML)
  • loading
    • References(67)
  • An, H. K., Park, B. Y., Kim, D. S., 2001. Crab Shell for the Removal of Heavy Metals from Aqueous Solution. Water Research, 35(15): 3551-3556. https://doi.org/10.1016/s0043-1354(01)00099-9
    Balistrieri, L. S., Borrok, D. M., Wanty, R. B., et al., 2008. Fractionation of Cu and Zn Isotopes during Adsorption onto Amorphous Fe(III) Oxyhydroxide: Experimental Mixing of Acid Rock Drainage and Ambient River Water. Geochimica et Cosmochimica Acta, 72(2): 311-328. https://doi.org/10.1016/j.gca.2007.11.013
    Balistrieri, L. S., Mebane, C. A., 2014. Predicting the Toxicity of Metal Mixtures. Science of the Total Environment, 466/467: 788-799. https://doi.org/10.1016/j.scitotenv.2013.07.034
    Bermin, J., Vance, D., Archer, C., et al., 2006. The Determination of the Isotopic Composition of Cu and Zn in Seawater. Chemical Geology, 226(3/4): 280-297. https://doi.org/10.1016/j.chemgeo.2005.09.025
    Bigalke, M., Weyer, S., Wilcke, W., 2011. Stable Cu Isotope Fractionation in Soils during Oxic Weathering and Podzolization. Geochimica et Cosmochimica Acta, 75(11): 3119-3134. https://doi.org/10.1016/j.gca.2011.03.005
    Borrok, D. M., Nimick, D. A., Wanty, R. B., et al., 2008. Isotopic Variations of Dissolved Copper and Zinc in Stream Waters Affected by Historical Mining. Geochimica et Cosmochimica Acta, 72(2): 329-344. https://doi.org/10.1016/j.gca.2007.11.014
    Brugger, J., McPhail, D. C., Black, J., et al., 2001. Complexation of Metal Ions in Brines: Application of Electronic Spectroscopy in the Study of the Cu(II)-LiCl-H2O System between 25 and 90 ℃. Geochimica et Cosmochimica Acta, 65(16): 2691-2708. https://doi.org/10.1016/s0016-7037(01)00614-7
    Buckley, A. N., Woods, R., 1984. An X-Ray Photoelectron Spectroscopic Study of the Oxidation of Chalcopyrite. Australian Journal of Chemistry, 37(12): 2403-2413. https://doi.org/10.1071/ch9842403
    Chapman, J. B., Weiss, D. J., Shan, Y., et al., 2009. Iron Isotope Fractionation during Leaching of Granite and Basalt by Hydrochloric and Oxalic Acids. Geochimica et Cosmochimica Acta, 73(5): 1312-1324. https://doi.org/10.1016/j.gca.2008.11.037
    Chi Fru, E., Rodríguez, N. P., Partin, C. A., et al., 2016. Cu Isotopes in Marine Black Shales Record the Great Oxidation Event. Proceedings of the National Academy of Sciences, 113(18): 4941-4946. https://doi.org/10.1073/pnas.1523544113
    Colman, S. M., 1982. Chemical Weathering of Basalts and Andesites: Evidence from Weathering Rinds. USGPO. https://doi.org/10.3133/pp1246
    Czamanske, G. K., Moore, J. G., 1977. Composition and Phase Chemistry of Sulfide Globules in Basalt from the Mid-Atlantic Ridge Rift Valley near 37°N Lat. Geological Society of America Bulletin, 88(4): 587-599. https://doi.org/10.1130/0016-7606(1977)88587:capcos>2.0.co;2 doi: 10.1130/0016-7606(1977)88587:capcos>2.0.co;2
    Eggleton, R. A., Foudoulis, C., Varkevisser, D., 1987. Weathering of Basalt: Changes in Rock Chemistry and Mineralogy. Clays and Clay Minerals, 35(3): 161-169. https://doi.org/10.1346/ccmn.1987.0350301
    Ehrlich, S., Butler, I., Halicz, L., et al., 2004. Experimental Study of the Copper Isotope Fractionation between Aqueous Cu(II) and Covellite, CuS. Chemical Geology, 209(3/4): 259-269. https://doi.org/10.1016/j.chemgeo.2004.06.010
    Fernandez, A., Borrok, D. M, 2009. Fractionation of Cu, Fe, and Zn Isotopes during the Oxidative Weathering of Sulfide-Rich Rocks. Chemical Geology, 264(1/2/3/4): 1-12. https://doi.org/10.1016/j.chemgeo.2009.01.024
    Frost, B. R., Frost, C. D., 2019. Essentials of Igneous and Metamorphic Petrology. Cambridge University Press, Cambridge. https://doi.org/10.1017/9781108685047
    Fujii, T., Moynier, F., Abe, M., et al., 2013. Copper Isotope Fractionation between Aqueous Compounds Relevant to Low Temperature Geochemistry and Biology. Geochimica et Cosmochimica Acta, 110: 29-44. https://doi.org/10.1016/j.gca.2013.02.007
    Ghuniem, M. M., Khorshed, M. A., Souaya, E. R., 2019. Method Validation for Direct Determination of Some Trace and Toxic Elements in Soft Drinks by Inductively Coupled Plasma Mass Spectrometry. International Journal of Environmental Analytical Chemistry, 99(6): 515-540. https://doi.org/10.1080/03067319.2019.1599878
    Gislason, S. R., Oelkers, E. H., 2003. Mechanism, Rates, and Consequences of Basaltic Glass Dissolution: II. an Experimental Study of the Dissolution Rates of Basaltic Glass as a Function of pH and Temperature. Geochimica et Cosmochimica Acta, 67(20): 3817-3832. https://doi.org/10.1016/s0016-7037(03)00176-5
    Helios-Rybicka, E., Wójcik, R., 2012. Competitive Sorption/Desorption of Zn, Cd, Pb, Ni, Cu, and Cr by Clay-Bearing Mining Wastes. Applied Clay Science, 65/66: 6-13. https://doi.org/10.1016/j.clay.2012.06.006
    Ikhsan, J., Johnson, B. B., Wells, J. D., 1999. A Comparative Study of the Adsorption of Transition Metals on Kaolinite. Journal of Colloid and Interface Science, 217(2): 403-410. https://doi.org/10.1006/jcis.1999.6377
    Jang, J. H., Dempsey, B. A., Catchen, G. L., et al., 2003. Effects of Zn(II), Cu(II), Mn(II), Fe(II), NO3-, or SO42- at pH 6.5 and 8.5 on Transformations of Hydrous Ferric Oxide (HFO) as Evidenced by Mössbauer Spectroscopy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 221(1/2/3): 55-68. https://doi.org/10.1016/s0927-7757(03)00134-1
    Jaouen, K., Pons, M. L., Balter, V., 2013. Iron, Copper and Zinc Isotopic Fractionation up Mammal Trophic Chains. Earth and Planetary Science Letters, 374: 164-172. https://doi.org/10.1016/j.epsl. 2013.05.037 doi: 10.1016/j.epsl.2013.05.037
    Jiang, M. Q., Jin, X. Y., Lu, X. Q., et al., 2010. Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto Natural Kaolinite Clay. Desalination, 252(1/2/3): 33-39. https://doi.org/10.1016/j.desal.2009.11.005
    Kimball, B. E., Mathur, R., Dohnalkova, A. C., et al., 2009. Copper Isotope Fractionation in Acid Mine Drainage. Geochimica et Cosmochimica Acta, 73(5): 1247-1263. https://doi.org/10.1016/j.gca.2008.11.035
    Komárek, M., Antelo, J., Králová, M., et al., 2018. Revisiting Models of Cd, Cu, Pb and Zn Adsorption onto Fe(III) Oxides. Chemical Geology, 493: 189-198. https://doi.org/10.1016/j.chemgeo.2018.05.036
    Larson, P. B., Maher, K., Ramos, F. C., et al., 2003. Copper Isotope Ratios in Magmatic and Hydrothermal Ore-Forming Environments. Chemical Geology, 201(3/4): 337-350. https://doi.org/10.1016/j.chemgeo. 2003.08.006 doi: 10.1016/j.chemgeo.2003.08.006
    Lee, M. E., Park, J. H., Chung, J. W., 2019. Comparison of the Lead and Copper Adsorption Capacities of Plant Source Materials and Their Biochars. Journal of Environmental Management, 236: 118-124. https://doi.org/10.1016/j.jenvman.2019.01.100
    Li, D. D., Liu, S. A., Li, S. G, 2015. Copper Isotope Fractionation during Adsorption onto Kaolinite: Experimental Approach and Applications. Chemical Geology, 396: 74-82. https://doi.org/10.1016/j.chemgeo.2014.12.020
    Liaghati, T., Preda, M., Cox, M., 2004. Heavy Metal Distribution and Controlling Factors within Coastal Plain Sediments, Bells Creek Catchment, Southeast Queensland, Australia. Environment International, 29(7): 935-948. https://doi.org/10.1016/s0160-4120(03)00060-6
    Linge, H. G., 1976. A Study of Chalcopyrite Dissolution in Acidic Ferric Nitrate by Potentiometric Titration. Hydrometallurgy, 2(1): 51-64. https://doi.org/10.1016/0304-386x(76)90013-x
    Little, S. H., Munson, S., Prytulak, J., et al., 2019. Cu and Zn Isotope Fractionation during Extreme Chemical Weathering. Geochimica et Cosmochimica Acta, 263: 85-107. https://doi.org/10.1016/j.gca.2019.07.057
    Little, S. H., Vance, D., Walker-Brown, C., et al., 2014. The Oceanic Mass Balance of Copper and Zinc Isotopes, Investigated by Analysis of Their Inputs, and Outputs to Ferromanganese Oxide Sediments. Geochimica et Cosmochimica Acta, 125: 673-693. https://doi.org/10.1016/j.gca.2013.07.046
    Liu, S. -A., Teng, F. Z., Li, S. G., et al., 2014a. Copper and Iron Isotope Fractionation during Weathering and Pedogenesis: Insights from Saprolite Profiles. Geochimica et Cosmochimica Acta, 146: 59-75. https://doi.org/10.1016/j.gca.2014.09.040
    Liu, S. -A., Li, D. D., Li, S. G., et al., 2014b. High-Precision Copper and Iron Isotope Analysis of Igneous Rock Standards by MC-ICP-MS. Journal of Analytical Atomic Spectrometry, 29(1): 122-133. https://doi.org/10.1039/c3ja50232e
    Liu, S. -A., Huang, J., Liu, J. G., et al., 2015. Copper Isotopic Composition of the Silicate Earth. Earth and Planetary Science Letters, 427: 95-103. https://doi.org/10.1016/j.epsl.2015.06.061
    Liu, S. -A., Liu, P. P., Lü, Y. W., et al., 2019. Cu and Zn Isotope Fractionation during Oceanic Alteration: Implications for Oceanic Cu and Zn Cycles. Geochimica et Cosmochimica Acta, 257: 191-205. https://doi.org/10.1016/j.gca.2019.04.026
    Lü, Y. W, Liu, S. -A., Zhu, J. M., et al., 2016. Copper and Zinc Isotope Fractionation during Deposition and Weathering of Highly Metalliferous Black Shales in Central China. Chemical Geology, 445: 24-35. https://doi.org/10.1016/j.chemgeo.2016.01.016
    Lü, Y. W., Liu, S. -A., Teng, F. Z., et al., 2020. Contrasting Zinc Isotopic Fractionation in Two Mafic-Rock Weathering Profiles Induced by Adsorption onto Fe (Hydr)Oxides. Chemical Geology, 539: 119504. https://doi.org/10.1016/j.chemgeo.2020.119504
    Markl, G., Lahaye, Y., Schwinn, G., 2006. Copper Isotopes as Monitors of Redox Processes in Hydrothermal Mineralization. Geochimica et Cosmochimica Acta, 70(16): 4215-4228. https://doi.org/10.1016/j.gca.2006.06.1369
    Mathez, E. A., 1976. Sulfur Solubility and Magmatic Sulfides in Submarine Basalt Glass. Journal of Geophysical Research Atmospheres, 81(23): 4269-4276. https://doi.org/10.1029/jb081i023p04269
    Mathur, R., Fantle, M. S., 2015. Copper Isotopic Perspectives on Supergene Processes: Implications for the Global Cu Cycle. Elements, 11(5): 323-329. https://doi.org/10.2113/gselements.11.5.323
    Mathur, R., Jin, L., Prush, V., et al., 2012. Cu Isotopes and Concentrations during Weathering of Black Shale of the Marcellus Formation, Huntingdon County, Pennsylvania (USA). Chemical Geology, 304/305: 175-184. https://doi.org/10.1016/j.chemgeo.2012.02.015
    Mathur, R., Munk, L., Nguyen, M., et al., 2013. Modern and Paleofluid Pathways Revealed by Cu Isotope Compositions in Surface Waters and Ores of the Pebble Porphyry Cu-Au-Mo Deposit, Alaska. Economic Geology, 108(3): 529-541. https://doi.org/10.2113/econgeo.108.3.529
    Mathur, R., Ruiz, J., Titley, S., et al., 2005. Cu Isotopic Fractionation in the Supergene Environment with and without Bacteria. Geochimica et Cosmochimica Acta, 69(22): 5233-5246. https://doi.org/10.1016/j.gca.2005.06.022
    Mathur, R., Titley, S., Barra, F., et al., 2009. Exploration Potential of Cu Isotope Fractionation in Porphyry Copper Deposits. Journal of Geochemical Exploration, 102(1): 1-6. https://doi.org/10.1016/j.gexplo.2008.09.004
    Meybeck, M., 1986. Composition Chimique des Ruisseaux non Pollués en France. Chemical Composition of Headwater Streams in France. Sciences Géologiques, Bulletins et Mémoires, 39(1): 3-77 http://www.researchgate.net/publication/316930437_Chemical_composition_of_headwater_streams_in_France
    Pasquarello, A., Petri, I., Salmon, P. S., et al., 2001. First Solvation Shell of the Cu(II) Aqua Ion: Evidence for Fivefold Coordination. Science, 291(5505): 856-859. https://doi.org/10.1126/science.291.5505.856
    Peacock, C. L., Sherman, D. M., 2005. Surface Complexation Model for Multisite Adsorption of Copper(II) onto Kaolinite. Geochimica et Cosmochimica Acta, 69(15): 3733-3745. https://doi.org/10.1016/j.gca.2004.12.029
    Pei, Z. G., Shan, X. Q., Kong, J. J., et al., 2010. Coadsorption of Ciprofloxacin and Cu(II) on Montmorillonite and Kaolinite as Affected by Solution pH. Environmental Science & Technology, 44(3): 915-920. https://doi.org/10.1021/es902902c
    Pękala, M., Asael, D., Butler, I. B., et al., 2011. Experimental Study of Cu Isotope Fractionation during the Reaction of Aqueous Cu(II) with Fe(II) Sulphides at Temperatures between 40 and 200 ℃. Chemical Geology, 289(1/2): 31-38. https://doi.org/10.1016/j.chemgeo. 2011.07.004 doi: 10.1016/j.chemgeo.2011.07.004
    Pokrovsky, O. S., Viers, J., Emnova, E. E., et al., 2008. Copper Isotope Fractionation during Its Interaction with Soil and Aquatic Microorganisms and Metal Oxy(Hydr)Oxides: Possible Structural Control. Geochimica et Cosmochimica Acta, 72(7): 1742-1757. https://doi.org/10.1016/j.gca.2008.01.018
    Pratesi, G., Cipriani, C., 2000. Selective Depth Analyses of the Alteration Products of Bornite, Chalcopyrite and Pyrite Performed by XPS, AES, RBS. European Journal of Mineralogy, 12(2): 397-409. https://doi.org/10.1127/ejm/12/2/0397
    Revels, B. N., Zhang, R. F., Adkins, J. F., et al., 2015. Fractionation of Iron Isotopes during Leaching of Natural Particles by Acidic and Circumneutral Leaches and Development of an Optimal Leach for Marine Particulate Iron Isotopes. Geochimica et Cosmochimica Acta, 166: 92-104. https://doi.org/10.1016/j.gca.2015.05.034
    Rubio, B., Nombela, M. A., Vilas, F., 2000. Geochemistry of Major and Trace Elements in Sediments of the Ria de Vigo (NW Spain): An Assessment of Metal Pollution. Marine Pollution Bulletin, 40(11): 968-980. https://doi.org/10.1016/s0025-326x(00)00039-4
    Sherman, D. M., 2001. Quantum Chemistry and Classical Simulations of Metal Complexes in Aqueous Solutions. Reviews in Mineralogy and Geochemistry, 42(1): 273-317. https://doi.org/10.2138/rmg.2001.42.8
    Singovszka, E., Balintova, M., Demcak, S., et al., 2017. Metal Pollution Indices of Bottom Sediment and Surface Water Affected by Acid Mine Drainage. Metals, 7(8): 284. https://doi.org/10.3390/met7080284
    Song, S. M., Mathur, R., Ruiz, J., et al., 2016. Fingerprinting Two Metal Contaminants in Streams with Cu Isotopes near the Dexing Mine, China. Science of the Total Environment, 544: 677-685. https://doi.org/10.1016/j.scitotenv.2015.11.101
    Srivastava, P., Singh, B., Angove, M., 2005. Competitive Adsorption Behavior of Heavy Metals on Kaolinite. Journal of Colloid and Interface Science, 290(1): 28-38. https://doi.org/10.1016/j.jcis.2005.04.036
    Stone, W. E., Fleet, M. E., 1991. Nickel-Copper Sulfides from the 1959 Eruption of Kilauea Volcano, Hawaii: Contrasting Compositions and Phase Relations in Eruption Pumice and Kilauea Iki Lava Lake. American Mineralogist, 76(7/8): 1363-1372 http://ci.nii.ac.jp/naid/80006079820
    Suchet, P. A., Probst, J. L., 1993. Modelling of Atmospheric CO2 Consumption by Chemical Weathering of Rocks: Application to the Garonne, Congo and Amazon Basins. Chemical Geology, 107(3/4): 205-210. https://doi.org/10.1016/0009-2541(93)90174-H
    Todd, E. C., Sherman, D. M., Purton, J. A., 2003. Surface Oxidation of Chalcopyrite (CuFeS2) under Ambient Atmospheric and Aqueous (pH 2-10) Conditions: Cu, Fe L- and O K-Edge X-Ray Spectroscopy. Geochimica et Cosmochimica Acta, 67(12): 2137-2146. https://doi.org/10.1016/s0016-7037(02)01371-6
    Vance, D., Archer, C., Bermin, J., et al., 2008. The Copper Isotope Geochemistry of Rivers and the Oceans. Earth and Planetary Science Letters, 274(1/2): 204-213. https://doi.org/10.1016/j.epsl.2008.07.026
    Vance, D., Matthews, A., Keech, A., et al., 2016. The Behaviour of Cu and Zn Isotopes during Soil Development: Controls on the Dissolved Load of Rivers. Chemical Geology, 445: 36-53. https://doi.org/10.1016/j.chemgeo.2016.06.002
    Wall, A., Heaney, P. J., Mathur, R., et al., 2007. Insights into Copper Isotope Fractionation during the Oxidative Phase Transition of Chalcocite, Using Time-Resolved Synchrotron X-Ray Diffraction. Geochimica et Cosmochimica Acta, 71(15): A1081-A1081
    Wall, A. J., Mathur, R., Post, J. E., et al., 2011. Cu Isotope Fractionation during Bornite Dissolution: An in situ X-Ray Diffraction Analysis. Ore Geology Reviews, 42(1): 62-70. https://doi.org/10.1016/j.oregeorev. 2011.01.001 doi: 10.1016/j.oregeorev.2011.01.001
    Zeng, J., Han, G. L., 2020. Preliminary Copper Isotope Study on Particulate Matter in Zhujiang River, Southwest China: Application for Source Identification. Ecotoxicology and Environmental Safety, 198: 110663. https://doi.org/10.1016/j.ecoenv.2020.110663
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(5)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views(229) PDF downloads(62) Cited by()
    Proportional views
    Related

    Copyright © 2013-2020 Journal of Earth Science 鄂ICP备15021562号-2

    Tel: +86-27-67885075 Fax: +86-27-67885075 E-mail: xbb@cug.edu.cn

    Address: Editorial Office of Journal, China University of Geosciences, Yujiashan, Wuhan, Hubei 430074, P. R. China

    Supported by: Beijing Renhe Information Technology Co. Ltd  E-mail: info@rhhz.net  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return