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Volume 34 Issue 4
Aug 2023
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Gong Cheng, Hongrui Zhang, Huan Li, Xiaoqing Deng, Safiyanu Muhammad Elatikpo, Jiaxuan Li, Zhenguang Hu, Guangqiang Li. Quantitative Inversion of REEs in Ion-Adsorbed Rare Earth Ores from the Liutang Area (South China), Based on Measured Hyperspectral Data. Journal of Earth Science, 2023, 34(4): 1068-1082. doi: 10.1007/s12583-021-1504-1
Citation: Gong Cheng, Hongrui Zhang, Huan Li, Xiaoqing Deng, Safiyanu Muhammad Elatikpo, Jiaxuan Li, Zhenguang Hu, Guangqiang Li. Quantitative Inversion of REEs in Ion-Adsorbed Rare Earth Ores from the Liutang Area (South China), Based on Measured Hyperspectral Data. Journal of Earth Science, 2023, 34(4): 1068-1082. doi: 10.1007/s12583-021-1504-1

Quantitative Inversion of REEs in Ion-Adsorbed Rare Earth Ores from the Liutang Area (South China), Based on Measured Hyperspectral Data

doi: 10.1007/s12583-021-1504-1
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  • Corresponding author: Huan Li, lihuan@csu.edu.cn
  • Received Date: 05 Jan 2021
  • Accepted Date: 04 Jul 2021
  • Available Online: 01 Aug 2023
  • Issue Publish Date: 30 Aug 2023
  • Rare earth minerals are important strategic resources to economic development all over the world. In this study, multiple linear regression and back propagation (BP) neural network methods are used to invert the contents of ion adsorbed rare earth elements (REEs) and exploring the feasibility of quantitative inversion of REEs through measured hyperspectral data in Liutang rare earth mines, South China. The result shows that the spectral curve of the rare earth ore samples has obvious absorption characteristics around 390, 930, 1 400, 1 900 and 2 200 nm, and continuum removal and the 1st derivative treatment can highlight the absorption characteristics. The modeling accuracies of BP neural network are higher than that of multiple linear regression model. The BP neural network model of the 1st derivative data in 400–1 000 nm bands has the best inversion result of the total content of REEs, R2 reaches 0.98, the ratio of the performance to deviation (RPD) is larger than 3.0. The quantitative inversion model of each REE (except for Ce) has high precision, R2 is greater than 0.90 and RPD is greater than 3.0. The results indicate that quantitative inversion of REEs using measured spectra not only has great potential and feasibility in the exploration of rare earth minerals, but also provides a rapid test method for the content of ion-adsorbed rare earth elements.

     

  • Electronic Supplementary Materials: Supplementary material is available in the online version of this article at https://doi.org/10.1007/s12583-021-1504-1.
    Conflict of Interest
    The authors declare that they have no conflict of interest.
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  • Adams, J. W., 1965. The Visible Region Absorption Spectra of Rare-Earth Minerals. American Mineralogist, 50: 356–366
    Ardanova, L. I., Get'man, E. I., Loboda, S. N., et al., 2010. Isomorphous Substitutions of Rare Earth Elements for Calcium in Synthetic Hydroxyapatites. Inorganic Chemistry, 49(22): 10687–10693. https://doi.org/10.1021/ic1015127
    Batsanov, S. S., Derbeneva, S. S., Batsanova, L. R., 1969. Electronic Spectra of Fluorides, Oxyfluorides, and Oxides of Rare-Earth Metals. Journal of Applied Spectroscopy, 10(2): 240–242. https://doi.org/10.1007/BF00615368
    Boesche, N. K., Rogass, C., Lubitz, C., et al., 2015. Hyperspectral REE (Rare Earth Element) Mapping of Outcrops—Applications for Neodymium Detection. Remote Sensing, 7(5): 5160–5186. https://doi.org/10.3390/rs70505160
    Bünzli, J. -C. G., Eliseeva, S. V., 2010. Basics of Lanthanide Photophysics. In: Hänninen, P., Härmä, H., eds., Lanthanide Luminescence. Springer Series on Fluorescence, 7: 1–45. Springer, Berlin, Heidelberg. https://doi.org/10.1007/4243_2010_3
    Chakraborty, S., Li, B., Deb, S., et al., 2017. Predicting Soil Arsenic Pools by Visible near Infrared Diffuse Reflectance Spectroscopy. Geoderma, 296: 30–37. https://doi.org/10.1016/j.geoderma.2017.02.015
    Cheng, G., Li, J. X., Wang, C. P., et al., 2019. Study on Hyperspectral Quantitive Inversion of Ionic Rare Earth Ores. Spectoscopy and Spectral Analysis, 39(5): 1571–1578 (in Chinese with English Abstract)
    Cheng, H., Shen, R. L., Chen, Y. Y., et al., 2019. Estimating Heavy Metal Concentrations in Suburban Soils with Reflectance Spectroscopy. Geoderma, 336: 59–67. https://doi.org/10.1016/j.geoderma.2018.08.010
    Chi, R. A., 1988. Geological Characteristics and Prospecting Criteria of Ion Adsorption Rare Earth Deposits in Fujian. Chinese Rare Earths, 9(4): 49–52. https://doi.org/10.16533/j.cnki.15-1099/tf.1988.04.011 (in Chinese with English Abstract)
    Chi, R., Tian, J., 2007. Review of Weathered Shell Leaching Rare Earth Minerals. Journal of Chinese Society Rare Earths, (6): 641–650 (in Chinese with English Abstract)
    Cozzolino, D., 2016. Near Infrared Spectroscopy as a Tool to Monitor Contaminants in Soil, Sediments and Water—State of the Art, Advantages and Pitfalls. Trends in Environmental Analytical Chemistry, 9: 1–7. https://doi.org/10.1016/j.teac.2015.10.001
    Cozzolino, D., Moron, A., 2004. Exploring the Use of near Infrared Reflectance Spectroscopy (NIRS) to Predict Trace Minerals in Legumes. Animal Feed Science and Technology, 111(1/2/3/4): 161–173. https://doi.org/10.1016/j.anifeedsci.2003.08.001
    Dai, J. J., 2013. Quantitative Evaluation of Rare Earth Concentration in Solution Based on Ground Reflection Spectrum: [Dissertation]. China University of Geosciences, Beijing. 115 (in Chinese with English Abstract)
    Dai, J. J., Wang, D. H., Chen, Z. H., 2021. Dissolved Rare Earth Elements Estimation of Ion-Absorption Rare Earth Ores Using Reflectance Spectroscopy in South Jiangxi Province, China. Journal of Rare Earths, 39(10): 1300–1310. https://doi.org/10.1016/j.jre.2020.09.016
    Dai, J. J., Wu, Y. N., Ling, T. Y., 2018. Reflectance Spectroscopy and Hyperspectral Detection of Rare Earth Element. Spectroscopy and Spectral Analysis, 38(12): 3801–3808 (in Chinese with English Abstract)
    Ding, M. Q., Xiao, H., Chen, S., et al., 2012. Remote Sensing Quantitative Retrieval of Soil Organic Matter Content in the Land Development and Consolidation Region Based on BP Neural Network. Journal of Natural Science of Xiangtan University, 34 (2): 103–106 (in Chinese with English Abstract)
    Durbha, S. S., King, R. L., Younan, N. H., 2007. Support Vector Machines Regression for Retrieval of Leaf Area Index from Multiangle Imaging Spectroradiometer. Remote Sensing of Environment, 107(1/2): 348–361. https://doi.org/10.1016/j.rse.2006.09.031
    Guo, B. J., Zhang, J. L., Wu, D., 2018. Thermal Hyperspectral Remote Rensing for the Quantitative Inversion of Quartz Content by Regression Analysis. Science Technology and Engineering, 18(17): 125–130 (in Chinese with English Abstract)
    Huang, C. J., Han, L. J., Yang, Z. L., et al., 2009. Exploring the Use of near Infrared Reflectance Spectroscopy to Predict Minerals in Straw. Fuel, 88(1): 163–168. https://doi.org/10.1016/j.fuel.2008.07.031
    Hunt, G. R., 1977. Spectral Signatures of Particulate Minerals in the Visible and near Infrared. Geophysics, 42(3): 501–513. https://doi.org/10.1190/1.1440721
    Li, J., 2018. Research on Spectral Modeling of Ion-Type Rare Earth Ore Content: [Dissertation]. Central South University, Changsha (in Chinese with English Abstract)
    Li, J., Tian, Q., Wu, Y., 2005. Spectral Response of Fe, Zn, Se in Farmland Soil on Both Sides of Fuyang River. Remote Sensing Information, 3: 10–13 (in Chinese with English Abstract)
    Lin, J., Pan, Y., Yang, M., et al., 2018. Remote Sensing Quantitative Inversion of Vegetation Leaf Area Index Based on BP Neural Network from 1988 to 2013. Acta Ecologica Sinica, 38(10): 3534–3542 (in Chinese with English Abstract)
    Liu, H., Zhang, L., 2007. Hyperspectral Estimation Model of Heavy Metal Content in Salt Marsh Soil of Chongming Dongtan. Acta Ecologica Sinica, 27(8): 3427–3434 (in Chinese with English Abstract)
    Luce, M. St., Ziadi, N., Gagnon, B., et al., 2017. Visible near Infrared Reflectance Spectroscopy Prediction of Soil Heavy Metal Concentrations in Paper Mill Biosolid- and Liming by-Product-Amended Agricultural Soils. Geoderma, 288: 23–36. https://doi.org/10.1016/j.geoderma.2016.10.037
    Luo, X., 2011. The Metallogenic Conditions of Rare Earth Minerals in Hunan Province and the Formation Mechanism of Ion-Adsorbed Rare Earth Ore. Acta Mineralogica Sinica, 31(S1): 332–333 (in Chinese with English Abstract)
    Lypaczewski, P., Rivard, B., 2018. Estimating the Mg# and AlVI Content of Biotite and Chlorite from Shortwave Infrared Reflectance Spectroscopy: Predictive Equations and Recommendations for Their Use. International Journal of Applied Earth Observation and Geoinformation, 68: 116–126. https://doi.org/10.1016/j.jag.2018.02.003
    Mohamed, E. S., Saleh, A. M., Belal, A. B., et al., 2018. Application of Near-Infrared Reflectance for Quantitative Assessment of Soil Properties. The Egyptian Journal of Remote Sensing and Space Science, 21(1): 1–14. https://doi.org/10.1016/j.ejrs.2017.02.001
    Pan, H., 2011. Characteristics and Metallogenic Models of Weathering Shell Ion-Adsorbed Rare Earth Ore Deposits in Yunkai Area, Guangxi. Southern Land Resources, (9): 37–40 (in Chinese with English Abstract)
    Ramaroson, V. H., Becquer, T., Sá, S. O., et al., 2018. Mineralogical Analysis of Ferralitic Soils in Madagascar Using NIR Spectroscopy. CATENA, 168: 102–109. https://doi.org/10.1016/j.catena.2017.07.016
    Saeys, W., Mouazen, A. M., Ramon, H., 2005. Potential for Onsite and Online Analysis of Pig Manure Using Visible and near Infrared Reflectance Spectroscopy. Biosystems Engineering, 91(4): 393–402. https://doi.org/10.1016/j.biosystemseng.2005.05.001
    Song, L., Jian, J., Tan, D. J., et al., 2015. Estimate of Heavy Metals in Soil and Streams Using Combined Geochemistry and Field Spectroscopy in Wan-Sheng Mining Area, Chongqing, China. International Journal of Applied Earth Observation and Geoinformation, 34: 1–9. https://doi.org/10.1016/j.jag.2014.06.013
    Tappert, M. C., Rivard, B., Giles, D., et al., 2013. The Mineral Chemistry, Near-Infrared, and Mid-Infrared Reflectance Spectroscopy of Phengite from the Olympic Dam IOCG Deposit, South Australia. Ore Geology Reviews, 53: 26–38. https://doi.org/10.1016/j.oregeorev.2012.12.006
    Turner, D. J., Rivard, B., Groat, L. A., 2014. Visible and Short-Wave Infrared Reflectance Spectroscopy of REE Fluorocarbonates. American Mineralogist, 99(7): 1335–1346. https://doi.org/10.2138/am.2014.4674
    Vohland, M., Besold, J., Hill, J., et al., 2011. Comparing Different Multivariate Calibration Methods for the Determination of Soil Organic Carbon Pools with Visible to near Infrared Spectroscopy. Geoderma, 166(1): 198–205. https://doi.org/10.1016/j.geoderma.2011.08.001
    Wang, X., Zheng, X., Han, Z., et al., 2018. Hyperspectral Inversion of Soil Potassium Content in Mixed Random Forest. Spectroscopy and Spectral Analysis, 38(12): 3883–3889 (in Chinese with English Abstract)
    Wang, X. P., Zhang, F., Ding, J. L., et al., 2018. Estimation of Soil Salt Content (SSC) in the Ebinur Lake Wetland National Nature Reserve (ELWNNR), Northwest China, Based on a Bootstrap-BP Neural Network Model and Optimal Spectral Indices. Science of the Total Environment, 615: 918–930. https://doi.org/10.1016/j.scitotenv.2017.10.025
    Xu, J. R., Dong, J. H., Yang, Y. X., et al., 2014. Support Vector Machine Model for Predicting the Cadmium Concentration of Soil-Wheat System in Mine Reclamation Farmland Using Hyperspectral Data. Acta Photonica Sinica, 43(5): 530001. https://doi.org/10.3788/gzxb20144305.0530001
    Xu, Q., Guo, J., Qin, F., 2011. Application of Extraneous Spectral Mineral Analysis Technique in Mapping Altered Minerals in Panan Copper-Steel-He Mining Area. Geology and Exploration, 47(1): 107–112 (in Chinese with English Abstract)
    Yan, D., Wu, Y., Ma, H., 2010. Predicting the Content of Heavy Metal Elements in Soil Based on Mid-Infrared Diffuse Reflectance Spectroscopy. Spectroscopy and Spectral Analysis, 30(6): 1498–1502 (in Chinese with English Abstract)
    Yan, Y., Wang, Z., Ding, Y., et al., 2018. Research on the Inversion Model of Iron Content in Walnut Leaves Based on Hyperspectral Data. Xinjiang Agricultural Sciences, 55(7): 1264–1273 (in Chinese with English Abstract)
    Yang, D., Xiao, G., 2011. Study on the Metallogenic Regularity of Ion-Adsorbed Rare Earth Ore in Guangdong Province. Geology and Resources, 20(6): 462–468 (in Chinese with English Abstract)
    Yang, S. X., Feng, Q. S., Liang, T. G., et al., 2018. Modeling Grassland Above-Ground Biomass Based on Artificial Neural Network and Remote Sensing in the Three-River Headwaters Region. Remote Sensing of Environment, 204: 448–455. https://doi.org/10.1016/j.rse.2017.10.011
    Yang, T., Hu, L., 2018. Study on the Distribution Law of Ion-Adsorbed Rare Earth Ore in Guangxi and Prediction of Ore Prospecting Area. Mineral Exploration, 9(6): 1179–1184 (in Chinese with English Abstract)
    Yu, F., Zhao, Y., Li, H., 2012. Soil Moisture Retrieval Using Active and Passive Remote Sensing Based on Genetic BP Neural Network. Journal of Infrared and Millimeter Wave, 31(3): 283–288 (in Chinese with English Abstract)
    Zhang, M., He, X., Tan, W., et al., 2022. Geochemical Characteristics and Genesis of Ion-Adsorption Type REE Deposit in the Lincang Granite, Yunnan Province. Geology in China, 49(1): 201–214 (in Chinese with English abstract)
    Zhang, Q. Y., Zhang, D. R., Huang, G. C., et al., 2012. The Remote Sensing Prospecting Information Extraction and Mineral Resources Prognosis in the Banqiao Rare Earth Mineral Deposit. Remote Sensing for Natural Resources, 1: 120–126. https://doi.org/10.6046/gtzyyg.2012.01.21
    Zhang, S. W., Shen, Q., Nie, C. J., et al., 2019. Hyperspectral Inversion of Heavy Metal Content in Reclaimed Soil from a Mining Wasteland Based on Different Spectral Transformation and Modeling Methods. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 211: 393–400. https://doi.org/10.1016/j.saa.2018.12.032
    Zhao, T., Wang, D., Wang, Z., et al., 2014. Study on the Method of Extracting Hyperspectral Remote Sensing Information from Ion-Adsorbed Rare Earth Ore in Yunnan-Burma Region. Mineral Deposits, 33(S): 1205–1206 (in Chinese with English Abstract)
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