Trace element mobility in subducted marble and associated eclogite: constraints from UHP rocks in the Shuanghe area, central-east China

In order to decipher element mobility in UHP meta-sedimentary rocks in the continental subduction zone, major and trace element compositions are investigated for a continuous profile from a representative UHP region in the Dabie Mountains. Among the lithologic contact zone, contents of K, Ca, LREE, and LILE exhibit varying degrees of downward trends in both marble and eclogite toward the contact zone, indicating that marble and their associated eclogite can release a large amount of K, Ca, and a small amount of LILEs and LREEs. Titanite is the main Ti phase in both marble and eclogite. Titanite rims around rutile can occasionally be seen in eclogite. Contents of Ti and HFSE exhibit a well-coupled relation among marble and eclogite, indicating that substantial Ti and HFSEs were migrated from eclogite to marble, in accord with the capacity of a melt medium. Rutiles and titanites in marble exhibit a relatively limited variation in Nb/Ta ratios (12.9-16.2), similar to those of titanites in eclogite (14.2-16.7), which demonstrates that rutiles and titanites in marble were sourced from eclogite because of short-distance migrations of Ti and HFSEs. According to the P-T path and the temperature and pressure conditions of the peak metamorphism reported by previous studies, the eclogite associated with marble may not form supercritical fluids in the subduction zone because of the addition of carbonate minerals.