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Journal of Earth Science  > 2024  > Accepted Manuscript
Meysam Hemmati, Yaser Ahmadi, Behzad Vaferi, Ali Hosin Alibak, David A. Wood. Surveying organic matter, thermal maturity level, and paleo-environmental conditions by considering biomarker and stable carbon isotopic analysis. Journal of Earth Science. doi: 10.1007/s12583-024-1984-x
Citation: Meysam Hemmati, Yaser Ahmadi, Behzad Vaferi, Ali Hosin Alibak, David A. Wood. Surveying organic matter, thermal maturity level, and paleo-environmental conditions by considering biomarker and stable carbon isotopic analysis. Journal of Earth Science. doi: 10.1007/s12583-024-1984-x
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Surveying organic matter, thermal maturity level, and paleo-environmental conditions by considering biomarker and stable carbon isotopic analysis

doi: 10.1007/s12583-024-1984-x

  • 1 School of Geology, College of Science, University of Tehran, Tehran, Iran;

  • 2 Chemical and Petroleum Engineering Department, Ilam University, Ilam, Iran;

  • 3 Department of Chemical Engineering, Shiraz Branch, Islamic Azad University, Shiraz, Iran;

  • 4 Petroleum Engineering Department, Faculty of Engineering, Soran University, Soran, Kurdistan Region, Iraq;

  • 5 DWA Energy Limited, Lincoln, United Kingdom

  • Available Online: 07 Mar 2024
    Abstract
  • Biomarker and stable carbon isotope analyses are presented for the Garau formation of the Cretaceous age, an important source rock in western Iran, to reveal its potential as an oil-prone source rock. The C28/C29sterane ratio value range (0.72 to 0.83) of bitumen samples from the formation suggests that they were likely formed during phytoplankton blooms. Sterane, hopane, and isoprenoid/n-alkane ratios indicate that the formation's organic matter predominantly consists of algae, and bacteria, accompanied by some reworked material derived from higher plants. Due to the predominance of anoxic conditions and the actions of sulfate-reducing bacteria, the bitumen present is enriched with sulfur compounds. The percentages of saturates, aromatics, and nitrogen-sulfur-oxygen (NSO) fractions in the bitumen samples classify them as naphthenic oils. Isotope analysis reveals that biodegradation and water-washing have reduced the concentrations of some volatile saturates and low molecular weight aromatics in the bitumen samples. These actions have resulted in distinctive δ13C values for the formation's kerogen and bitumen fractions. The formation's organic matter has been subjected to high-temperature thermal regimes and has entered the oil-generation window at the sampled localities, with vitrinite reflectance (%RC) varying between 0.7 % and 0.75 %.

     

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