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Pu Zhang, Shitou Wu, Tingyong Li, Zhe Zhang, Zhaofeng Zhang. Improving U-Pb Dating Accuracy for High-U Stalagmites in Quaternary Records. Journal of Earth Science. doi: 10.1007/s12583-025-0262-x
Citation: Pu Zhang, Shitou Wu, Tingyong Li, Zhe Zhang, Zhaofeng Zhang. Improving U-Pb Dating Accuracy for High-U Stalagmites in Quaternary Records. Journal of Earth Science. doi: 10.1007/s12583-025-0262-x

Improving U-Pb Dating Accuracy for High-U Stalagmites in Quaternary Records

doi: 10.1007/s12583-025-0262-x
Funds:

This study was supported by the National Natural Science Foundation of China (Nos. 42173027, 42272214, and 41888101), the Everest Talent Plan Project (Grant No. 10912-KYQD2022-09482), the Yunnan Fundamental Research Projects (Grant No. 202201AS070022), and the Reserve Talent of the Young and Middle-age Academic and Technical Leader in Yunnan Province (No. 202205AC160025) to T.-Y Li.

  • Available Online: 07 May 2025
  • This paper explores the accuracy of U-Pb dating of stalagmites with high uranium contents and high μ values of > 10000, focusing on Quaternary records. Isotope dilution thermal ionization mass spectrometry (ID-TIMS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb dating methods are compared, and it is found that LA-ICP-MS U-Pb dating yields a better precision, especially for samples up to 3 Ma. This research highlights the importance of correcting 234U/238U disequilibrium for accurate dating, though 230Th/238U calibration is not necessary for Quaternary samples. Common lead correction has a minimal effect on high-uranium samples regardless of whether 2-D or 3-D linear regression is applied to the U-Pb concordia data. The results of the LA-ICP-MS U-Pb method are consistent with those of the ID-TIMS U-Pb method for samples up to 2 Ma, and the error can reach 1.1-2.9%. Ultimately, this study provides a framework for improving the accuracy of U-Pb dating of high-resolution stalagmite records, which is crucial for paleoenvironment reconstruction.

     

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