Paleogeographic reconstruction provides a key surface boundary condition for the study of many first-order Earth systems and geodynamic processes. However, scarcity of robust Early Paleozoic paleomagnetic data leads to a controversial reconstruction between South China Block (SCB) and Gondwana. Here, we performed rock-magnetic, mineralogical and paleomagnetic analyses on the Ediacaran and Cambrian strata in Jiulongwan and Gunshi’ao sections in the Three Gorges area, Hubei province in South China. Rock-magnetic and mineralogical analyses suggested that the secondary magnetite - formed via pyrite oxidation - is the main remanence carriers, recording a post-tilting remagnetization event associated with fluid alterations. Paleomagnetic measurements showed a new Early Silurian paleopole (5.0° N, 194.1° E, A
95 = 3.0°) from the overprinted Ediacaran-Cambrian carbonates. These results indicated that the SCB was positioned in the equatorial region during the Early Silurian. Comparison of the Early Paleozoic apparent polar wander paths between the SCB and Gondwana further suggests that the SCB was united to northwest Australia, part of Gondwana, from late Cambrian to early Devonian. These findings refine the paleogeographic reconstructions of the Early Silurian and favor the proximity between South China and Gondwana during the Early Paleozoic.