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Paleogeographic reconstruction provides a key surface boundary condition for the study of many first-order Earth systems and geodynamic processes. However, scarcity of robust Early Paleozoic paleomagnetic data leads to a controversial reconstruction between the South China Block (SCB) and Gondwana. Here, we performed rock-magnetic, mineralogical and paleomagnetic analyses on the Ediacaran and Cambrian strata in the Jiulongwan and Gunshi’ao sections in the Three Gorges area, Hubei province in South China. Rock-magnetic and mineralogical analyses suggested that the secondary magnetite—formed via pyrite oxidation—is the main remanence carrier, recording a post-tilting remagnetization event associated with fluid alterations. Paleomagnetic measurements showed a new Early Silurian paleopole (5.0°N, 194.1°E,
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