Citation: | Li-qiang YANG, Jun DENG, Jing ZHANG, Chun-ying GUO, Bang-fei GAO, Qing-jie GONG, Qing-fei WANG, Shao-qing JIANG, Hai-jun YU. Decrepitation Thermometry and Compositions of Fluid Inclusions of the Damoqujia Gold Deposit, Jiaodong Gold Province, China: Implications for Metallogeny and Exploration. Journal of Earth Science, 2008, 19(4): 378-390. |
The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO42--K+ type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na+/Ca2+ type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.
Baker, T., 2002. Emplacement Depth and Carbon Dioxide-Rich Fluid Inclusions in Intrusion-Related Gold Deposits. Economic Geology and the Bulletin of the Society of Economic Geologists, 97(5): 1111–1117 doi: 10.2113/gsecongeo.97.5.1111 |
Beuchat, S., Moritz, R., Pettke, T., 2004. Fluid Evolution in the W-Cu-Zn-Pb San Cristobal Vein, Peru: Fluid Inclusion and Stable Isotope Evidence. Chemical Geology, 210: 201–224 doi: 10.1016/j.chemgeo.2004.06.008 |
Chen, Y. J., Pirajno, F., Lai, Y., et al., 2004. Metallogenic Time and Tectonic Setting of the Jiaodong Gold Province, Eastern China. Acta Petrologica Sinica, 20(4): 907–922 (in Chinese with English Abstract) |
Chen, Z. S., 1997. Oxygen and Hydrogen Isotope Behavior in Hydrothermal Water-Rock Interaction Process. Geotectonica et Metallogenia, 21(1): 51–61 (in Chinese with English Abstract) |
Clayton, R. N., O'Neil, J. R., Mayeda, T. K., 1972. Oxygen Isotope Exchange between Quartz and Water. Journal of Geophysical Research, 77(17): 3057–3067 doi: 10.1029/JB077i017p03057 |
Cun, G., Chen, J. M., 1992. Atalas of Gold Deposits in China. Institute of Gold Geology of Metallurgical Ministry of China, Langfang. 62 (in Chinese) |
Deng, J., Liu, W., Sun, Z. S., et al., 2003a. Evidence of Mantle-Rooted Fluids and Multi-level Circulation Ore-Forming Dynamics: A Case Study from the Xiadian Gold Deposit, Shandong Province, China. Science in China (Series D), 46(Suppl. ): 138–142 |
Deng, J., Yang, L. Q., Sun, Z. S., et al., 2003b. A Metallogenic Model of Gold Deposits of the Jiaodong Granite-Greenstone Belt. Acta Geologica Sinica, 77(4): 537–546 |
Deng, J., Xu, S. L., Fan, Y., et al., 1996. Structural System and Gold Ore-Forming Dynamics in the Northwestern Part of Jiaodong Peninsula. Geological Publishing House, Beijing (in Chinese with English Abstract) |
Deng, J., Yang, L. Q., Ge, L. S., et al., 2006. Research Advances in the Mesozoic Tectonic Regimes during the Formation of Jiaodong Ore Cluster Area. Progress in Natural Sciences, 16(8): 777–784 doi: 10.1080/10020070612330069 |
Fan, H. R., Zhai, M. G., Xie, Y. H., et al., 2003. Ore-Forming Fluid Associated with Granite-Hosted Gold Mineralization at the Sanshandao Deposit, Jiaodong Gold Province, China. Mineralium Deposita, 38(6): 739–750 doi: 10.1007/s00126-003-0368-x |
Fan, H. R., Xie, Y. H., Wang, Y. L., 1997. Fluid Inclusion Evidences in the Processes and Environments of Gold Deposition. Journal of Precious Metallic Geology, 6(3): 204–213 (in Chinese with English Abstract) |
Faure, G., Mensing, T. M., 2005. Isotopes: Principles and Applications. Third Edition. John Wiley & Sons, Inc., Hoboken, New Jersey. 776 |
Goldfarb, R. J., Groves, D. I., Gardoll, S., 2001. Orogenic Gold and Geological Time: A Global Synthesis. Ore Geology Reviews, 18: 1–75 doi: 10.1016/S0169-1368(01)00016-6 |
Groves, D. I., Goldfarb, R. J., Gebre-Mariam, M., et al., 1998. Orogenic Gold Deposits: A Proposed Classification in the Context of Their Crustal Distribution and Relationship to Other Gold Deposit Types. Ore Geology Reviews, 13: 7–27 doi: 10.1016/S0169-1368(97)00012-7 |
Groves, D. I., Goldfarb, R. J., Robert, F., et al., 2003. Gold Deposits in Metamorphic Belts: Overview of Current Understanding, Outstanding Problems, Future Research, and Exploration Significance. Economic Geology and the Bulletin of the Society of Economic Geologists, 98(1): 1–29 |
Halter, W. E., Pettke, T., Heinrich, C. A., 2004. Laser-Ablation ICP-MS Analysis of Silicate and Sulfide Melt Inclusions in an Andesitic Complex; I, Analytical Approach and Data Evaluation. Contributions to Mineralogy and Petrology, 147(4): 385–396 doi: 10.1007/s00410-004-0562-6 |
Heinrich, C. A., 2007. Fluid-Fluid Interactions in Magmatic-Hydrothermal Ore Formation. Review in Mineralogy & Geochemistry, 65(1): 363–387 |
Hoefs, J., 1997. Stable Isotope Geochemistry. Springer, Heidelberg. 1–201 |
Lang, J. R., Baker, T., 2001. Intrusion-Related Gold Systems: The Present Level of Understanding. Mineralium Deposita, 36(6): 477–489 doi: 10.1007/s001260100184 |
Li, C. Y., Shi, L. D., 1999. The Reason and Exploring Significance of α-β Peak of Quartz in Decrepitation Test. Journal of Precious Metallic Geology, 8(1): 35–37 (in Chinese with English Abstract) |
Li, Z. L., Yang, M. Z., 1993. Geochemistry of Jiaodong Gold Deposits. Tianjin Science and Technology Press, Tianjin. 1–293 (in Chinese with English Abstract) |
Liu, J. M., Ye, J., Xu, J. H., et al., 2003. C-O and Sr-Nd Isotopic Geochemistry of Carbonate Minerals from Gold Deposits in East Shandong, China. Acta Petrologica Sinica, 19(4): 775–784 (in Chinese with English Abstract) |
Lü, G. X., Kong, Q. C., 1993. Geology of Linglong-Jiaojia Type of Gold Deposits in Jiaodong Area. Science Press, Beijing. 1–253 (in Chinese) |
Lü, G. X., Lin, W. W., Luo, Y. H., et al., 1999. Tectono-physicochemistry and Gold Metallogenic Prognosis. Geological Publishing House, Beijing. 1–458 (in Chinese with English Abstract) |
Lu, H. Z., Guo, D. J., 2000. Progress and Trends in Research on Fluid Inclusions. Geological Review, 46(4): 385–392 (in Chinese with English Abstract) |
Lu, H. Z., Fan, H. R., Ni, P., et al., 2004. Fluid Inclusions. Science Press, Beijing. 161–171 (in Chinese) |
Luo, Z. K., Miao, L. C., 2002. Granites and Gold Deposits in Zhaoyuan-Laizhou Area, Eastern Shandong Province. Metallurgical Industry Press, Beijing. 84–117 (in Chinese with English Abstract) |
Mernagh, T. P., Bastrakov, E. N., Zaw, K., et al., 2007. Comparison of Fluid Inclusion Data and Mineralization Processes for Australian Orogenic Gold and Intrusion-Related Gold Systems. Acta Petrologica Sinica, 23(1): 21–32 |
Nelson, D. R., Chivas, A. R., Chappell, B. W., et al., 1988. Geochemical and Isotopic Systematic in Carbonatites and Implications for the Evolution of Oceanic-Island Sources. Geochimica et Cosmochimica Acta, 52(1): 1–17 doi: 10.1016/0016-7037(88)90051-8 |
Ohmoto, H., 1986. Stable Isotope Geochemistry of Ore Deposits. In: Valley, J. W., Taylor, H. P. Jr., O'Neil, J. R., eds., Stable Isotopes on High Temperature Geological Processes. Reviews in Mineralogy, 16: 491–559 |
Qiu, Y. M., Groves, D. I., McNaughton, N. J., et al., 2002. Nature, Age and Tectonic Setting of Granitoid-Hosted, Orogenic Gold Deposits of the Jiaodong Peninsula, Eastern North China Craton, China. Mineralium Deposita, 37: 283–305 doi: 10.1007/s00126-001-0238-3 |
Rankin, A. H., 2007. Fluid Inclusion Anomalies as Exploration Guides for Granite-Hosted Sn-W Mineralization: Prospects for the Future? Acta Petrologica Sinica, 23(1): 3–14 |
Ray, J. S., Ramesh, R., Pande, K., 1999. Carbon Isotopes in Kerguelen Plume-Derived Carbonatites: Evidence for Recycled Inorganic Carbon. Earth and Planetary Science Letters, 170(3): 205–214 doi: 10.1016/S0012-821X(99)00112-0 |
Schmidt, M. A., Clark, C., Skirrow, R., 2006. Mineral Exploration under Cover: Characterizing Mineralizing Fluid System. Journal of Geochemical Exploration, 89: 359–362 doi: 10.1016/j.gexplo.2005.11.064 |
Stefansson, A., Seward, T. M., 2003. Stability of Chloridogold (Ⅰ) Complexes in Aqueous Solutions from 300 to 600 ℃ and from 500 to 1 800 bar. Geochimica et Cosmochimica Acta, 67(23): 4559–4576 doi: 10.1016/S0016-7037(03)00391-0 |
Thompson, J. F. H., Sillitoe, R. H., Baker, T., et al., 1999. Intrusion-Related Gold Deposits Associated with Tungsten-Tin Provinces. Mineralium Deposita, 34(4): 323–334 doi: 10.1007/s001260050207 |
Valley, J. W., 1986. Stable Isotope Geochemistry of Metamorphic Rocks. In: Valley, J. W., Taylor, H. P. Jr., O'Neil, J. R., eds., Stable Isotopes on High Temperature Geological Processes. Reviews in Mineralogy, 16: 445–489 |
Wang, B. C., 1994. Metallogenic Physico-chemical Conditions of the Gold Deposits in the Northwest Region of Eastern Shandong. Geology in Shandong, 10(1): 1–10 (in Chinese with English Abstract) |
Wang, L. G., Qiu, Y. M., McNaughton, N. J., et al., 1998. Constraints on Crustal Evolution and Gold Metallogeny in the Northwestern Jiaodong Peninsula, China, from SHRIMP U-Pb Zircon Studies of Granitoids. Ore Geology Reviews, 13: 275–291 doi: 10.1016/S0169-1368(97)00022-X |
Wang, L. J., Zhu, H. P., Wang, M., 2007. Application of Decrepitation Method in Ore Deposits. Geology and Prospecting, 43(5): 88–91 (in Chinese with English Abstract) |
Wang, Y. W., Zhu, F. S., Gong, R. T., 2002. Study on the Metallogenic Chronology of Gold Deposits in Jiaodong Gold Concentration Zone. Gold Geology, 8(4): 48–55 (in Chinese with English Abstract) |
Wilkinson, J. J., 2001. Fluid Inclusions in Hydrothermal Ore Deposits. Lithos, 55: 229–272 doi: 10.1016/S0024-4937(00)00047-5 |
Williams-Jones, A. E., Heinrich, C. A., 2005. Vapor Transport of Metals and Formation of Magmatic-Hydrothermal Ore Deposits. Economic Geology and the Bulletin of the Society of Economic Geologists, 100(7): 1287–1312 doi: 10.2113/gsecongeo.100.7.1287 |
Xia, L. Q., Xia, Z. C., Xu, X. Y., 1999. Fluids and Melts in the Upper Mantle. Acta Geologica Sinica, 73(3): 330–340 doi: 10.1111/j.1755-6724.1999.tb00841.x |
Xie, Y. H., Fan, H. R., 2001. Minerageny Typomorphic Characteristic of Fluid Inclusions. Geoscience, 15(2): 202–204 (in Chinese with English Abstract) |
Xu, J. H., Xie, Y. L., Shen, S. L., 1997. A Comparison of Ore Forming Fluids between Gold Deposits in Xiaoqinling Mountains and Those in Jiaodong Peninsula. Mineral Deposits, 16(2): 151–162 (in Chinese with English Abstract) |
Yang, L. Q., Deng, J., Guo, C. Y., et al., 2008. Ore-Forming Fluid Characteristics of the Dayingezhuang Gold Deposit, Jiaodong Gold Province, China. Resource Geology, 58 (in Press) |
Yang, L. Q., Deng, J., Wang, J. G., et al., 2004. Control of Deep Tectonics on the Superlarge Deposits in China. Acta Geologica Sinica, 78(2): 358–367 |
Yang, L. Q., Deng, J., Wang, Q. F., et al., 2006. Coupling Effects on Gold Mineralization of Deep and Shallow Structures in the Northwestern Jiaodong Peninsula, Eastern China. Acta Geologica Sinica, 80(3): 400–411 |
Yang, L. Q., Deng, J., Zhang, J., et al., 2007a. Preliminary Studies of Fluid Inclusions in Damoqujia Gold Deposit along Zhaoping Fault Zone, Shandong Province, China. Acta Petrologica Sinica, 23(1): 153–160 (in Chinese withEnglish Abstract) |
Yang, L. Q., Deng, J., Ge, L. S., et al., 2007b. Metallogenic Age and Genesis of Gold Ore Deposits in Jiaodong Peninsula, Eastern China: A Regional Review. Progress in Natural Sciences, 17(2): 138–143 doi: 10.1080/10020070612331343237 |
Zhai, M. G., Yang, J. H., Liu, W. J., 2001. Large Gold Deposit Concentrating Area and Large-Scale Mineralization in Jiaodong Area. Science in China (Series D), 31(7): 545–552 |
Zhang, L. G., Chen, Z. S., Liu, J. X., et al., 1994. Water-Rock Exchange in the Jiaojia Type Gold Deposit: A Study of Hydrogen and Oxygen Isotopic Composition of Ore-Forming Fluids. Mineral Deposits, 13(3): 193–200 (in Chinese with English Abstract) http://www.researchgate.net/publication/284481894_Water-rock_exchange_in_the_Jiaojia_type_gold_deposit_A_study_of_hydrogen_and_oxygen_isotopic_composition_of_ore-forming_fluids |
Zhao, H. G., Sun, J. G., Ling, H. F., et al., 2005. Characteristics and Geological Significance of Ore-Forming Fluids in the Jiaodong Gold Deposits. Geology and Prospecting, 41(5): 27–33 (in Chinese with English Abstract) |
Zheng, Y. F., Chen, J. F., 2000. Geochemistry of Stable Isotopes. Science Press, Beijing. 50–57, 143–217 (in Chinese with English Abstract) |
Zhou, T. H., Lü, G. X., 2000. Tectonics, Granitoids and Mesozoic Gold Deposits in East Shandong, China. Ore Geology Reviews, 16: 71–90 doi: 10.1016/S0169-1368(99)00023-2 |
Zhou, T. H., Goldfarb, R. J., Phillips, G. N., 2002. Tectonics and Distribution of Gold Deposits in China: An Overview. Mineralium Deposita, 37: 249–282 doi: 10.1007/s00126-001-0237-4 |
Zhu, H. P., Wang, L. J., Liu, J. M., 2003. Determination of Quadrupole Mass Spectrometer for Gaseous Composition of Fluid Inclusion from Different Mineralization Stages. Acta Petrologica Sinica, 19(2): 314–318 (in Chinese with English Abstract) |