Citation: | Xiaowen Guo, Sheng He. Aromatic Hydrocarbons as Indicators of Origin and Maturation for Light Oils from Panyu Lower Uplift in Pearl River Mouth Basin. Journal of Earth Science, 2009, 20(5): 824-835. doi: 10.1007/s12583-009-0063-7 |
Aromatic fractions of six light oils and two source rock samples from Panyu (番禺) lower uplift of Pearl River Mouth basin were analyzed using GC-MS (gas chromatography-mass spectrometric) technique. Thirteen aromatic series of hydrocarbons detected such as biphenyls, naphthalenes, phenanthrenes, dibenzothiophenes (more than two hundred aromatic hydrocarbon compounds) were used to analyze the origin and maturity of the light oils. This study indicates that the distribution of aromatic hydrocarbon compounds in the light oils of wells L1 and P1 differs from those of wells P2, P3 and P4. The light oil samples from wells L1 and P1 contain more dibenzofuran and fluorence hydrocarbons and less naphthalene hydrocarbons. The contents of fluorene, dibenzothiophene and dibenzofuran in the two groups of light oils also show their difference in sedimentary environment. Moreover, the diversity of the relative distributions of biphenyl and naphthalene is apparent between the two groups of light oils. As mentioned above, the origin of the light oils from wells L1 and P1 varies from that of wells P2, P3 and P4. According to the result of oil-source correlation, the light oils from wells P2, P3 and P4 mainly originated from the source rocks in the Enping (恩平) Formation. Accordingly, the light oils from wells L1 and P1 may have been derived from the lacustrine shales in the Wenchang (文昌) Formation or from the mixed source of the Wenchang Formation and the Enping Formation. Applying maturity parameters of methylnaphthalenes, methylphenanthrenes and methyldibenzothiophenes from the aromatic hydrocarbons to the study of the maturity of light oils from Panyu lower uplift indicates that the maturity has reached the high mature stage.
Alexander, C., Masaru, S., Kuniaki, T., 1997. Distribution of Alkylated Dibenzothiophenes in Petroleum as a Tool for Maturity Assessments. Organic Geochemistry, 26(7): 483–490 |
Alexander, C., Noriyuki, S., 1995. Aromatic Sulfur Compounds as Maturity Indicators for Petroleums from the Buzuluk Depression, Russia. Organic Geochemistry, 23(7): 617–625 doi: 10.1016/0146-6380(95)00050-O |
Alexander, R., Kagi, R. I., Rowland, S. J., et al., 1985. The Effects of Thermal Maturity on Distribution of Dimethylnaphthalenes and Trimethylnaphthalenes in Some Ancient Sediments and Petroleums. Geochimica et Cosmochimica Acta, 49: 385–395 doi: 10.1016/0016-7037(85)90031-6 |
Budzinski, H., Garrigues, P. H., Connan, J., 1995. Alkylated Phenanthrene Distributions as Maturity and Origin Indicators in Crude Oils and Rock Extracts. Geochimica et Cosmochimica Acta, 59(10): 2043–2056 doi: 10.1016/0016-7037(95)00125-5 |
Chen, C. M., Shi, H. S., Xu, S. C., et al., 2003. Formation Conditions of Tertiary Oil and Gas Reservoir in Pearl River Mouth Basin. Science Press, Beijing (in Chinese) |
Chen, Z. L., Li, S. J., Wang, Z., 1997. A Study on Maturity Indicators of Some Aromatics in Low-Mid Maturity Thermal Evolution Zones. Acta Sedimentologica Sinica, 15: 192–197 (in Chinese with English Abstract) |
Fan, P., Philp, R. P., Li, Z., et al., 1990. Geochemical Characteristics of Aromatic Hydrocarbons in Crude Oil Sand Source Rocks from Different Sedimentary Environments. Organic Geochemistry, 16: 427–435 doi: 10.1016/0146-6380(90)90059-9 |
Guo, X. W., He, S., 2006. Geochemical Characteristics and Origin of Light Crude Oils in Panyu Lower Uplift, Pearl River Mouth Basin. Geological Science and Technology Information, 25: 63–67 (in Chinese with English Abstract) |
Heppenheimer, H., Steffens, K., Piittmann, W., et al., 1992. Comparison of Resinite-Related Aromatic Biomarker Distributions in Cretaceous-Tertiary Coals from Canada and Germany. Organic Geochemistry, 18: 273–287 doi: 10.1016/0146-6380(92)90069-A |
Hughes, W. B., 1984. Use of Thiophenic Organosulfur Compounds in Characterizing Crude Oils Derived from Carbonate versus Siliciclastic Sources. In: Palacas, J. G., ed., Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks. AAPG Stud. Geol., 18: 181–196 |
Hughes, W. B., Holba, A. G., Dzou, L. I. P., 1995. The Ratios of Dibenzothiophene to Phenanthrene and Pristane to Phytane as Indicators of Depositional Environment and Lithology of Petroleum Source Rocks. Geochimica et Cosmochimica Acta, 59: 3581–3598 doi: 10.1016/0016-7037(95)00225-O |
Isaksen, G. H., 1991. Molecular Indicators of Lacustrine Freshwater Depositional Environments. In: Manning, D. ed., Advances and Applications in Energy and the Natural Environment. Manchester Univ. Press, Manchester. 361–364 |
Meng, Q. X., Ji, L. M., Li, Y. L., et al., 1999. Distribution of Aromatic Hydrocarbons in Remain Extracts from Pinus Pollen Thermal Experiment. Acta Sedimentologica Sinica, 17: 827–831 (in Chinese with English Abstract) |
Radke, M., Welte, D. H., 1983. The Methylphenanthrene Index (MPI): A Maturity Parameter Based on Aromatic Hydrocarbons. Proceedings of the International Meeting on Organic Geochemistry, 10: 504–512 |
Radke, M., Welte, D. H., Willsch, H., 1982. Geochimical Study on a Well in the Western Canada Basin: Relation of the Aromatic Distribution Pattern to Maturity of Organic Matter. Geochimica et Cosmochimica Acta, 46: 1–10 doi: 10.1016/0016-7037(82)90285-X |
Radke, M., Welte, D. H., Willsch, H., 1986. Maturity Parameters Based on Aromatic Hydrocarbons: Influence of the Organic Matter Type. Organic Geochemistry, 10: 51–63 doi: 10.1016/0146-6380(86)90008-2 |
Stojanovic, K., Jovanc, B., Pevneva, G. S., et al., 2001. Maturity Assessment of Oils from the Sakhalin Oil Fields in Russia: Phenanthrene Content as a Tool. Organic Geochemistry, 32: 721–731 doi: 10.1016/S0146-6380(01)00004-3 |
Tuo, J. C., 1996. Geochemistry of the Tertiary Aromatic Hydrocarbons in the Qaidam Basin—Relationship between Dicylic and Polycyclic Aromatic Hydrocarbons. Petroleum Geology & Experiment, 18: 406–412 (in Chinese with English Abstract) |
van Aarssen, B. G. K., Bastow, T. P., Alexander, R., et al., 1999. Distributions of Methylated Naphthalenes in Crude Oils: Indicators of Maturity, Biodegradation and Mixing. Organic Geochemistry, 30: 1213–1227 doi: 10.1016/S0146-6380(99)00097-2 |
Wilhelms, A., Telnes, N., Steen, A., et al., 1998. A Quantitative Study of Aromatic Hydrocarbons in a Natural Maturity Shale Sequence—The 3-Methylphenanthrene/Retene Ratio, a Pragmatic Maturity Parameter. Organic Geochemistry, 29: 97–105 doi: 10.1016/S0146-6380(98)00112-0 |
Zhang, M., Zhang, J., 1999. Composition Characteristics and Geochemical Significance of Thiophene-Type Compounds for Crude Oils in Tarim Basin. Acta Sedimentologica Sinica, 17: 122–126 (in Chinese with English Abstract) |
Zhu, J. Z., Shi, H. S., Pang, X., et al., 2005. Nature Gas Origins and Gas Source Studies of Panyu Low Uplift in Pear River Mouth Basin. Nature Gas Geoscience, 16: 456–459 (in Chinese with English Abstract) |
Zhu, Y. M., Zhang, H. B., Fu, J. M., et al., 1998. Distribution and Composition of Aromatic Hydrocarbon in Various Oils from Tarim Basin. Acta Petrolei Sinica, 19: 33–37 (in Chinese with English Abstract) |