Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure

Weihua Huang; Yan Yang; Zeming Qi; Wendi Liu; Zhongping Wang; Yan Liu; Qunke Xia

doi:10.1007/s12583-020-1113-4

Volume 32 Issue 5

Oct 2021

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Journal of Earth Science > 2021 > 32(5): 1278-1286.

Weihua Huang, Yan Yang, Zeming Qi, Wendi Liu, Zhongping Wang, Yan Liu, Qunke Xia. Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure. Journal of Earth Science, 2021, 32(5): 1278-1286. doi: 10.1007/s12583-020-1113-4

Citation:

Weihua Huang, Yan Yang, Zeming Qi, Wendi Liu, Zhongping Wang, Yan Liu, Qunke Xia. Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure. Journal of Earth Science, 2021, 32(5): 1278-1286. doi: 10.1007/s12583-020-1113-4

Citation:

Weihua Huang, Yan Yang, Zeming Qi, Wendi Liu, Zhongping Wang, Yan Liu, Qunke Xia. Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure. Journal of Earth Science, 2021, 32(5): 1278-1286. doi: 10.1007/s12583-020-1113-4

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Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure

doi: 10.1007/s12583-020-1113-4

1.
School of Earth Sciences, Zhejiang University, Hangzhou 310027, China
2.
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, China
3.
Department of Physics, University of Science and Technology of China, Hefei 230026, China

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Corresponding author: Yan Yang, yanyang2005@zju.edu.cn
Received Date: 11 Aug 2020
Accepted Date: 07 Nov 2020
Publish Date: 01 Oct 2021

Abstract

Abstract

Dehydration in hydrous phases of the downgoing slab controls water release processes in subduction zones. Interplay between volatiles in hydrous minerals has complicated the previous knowledge of their dehydration. Phengite is an essential mineral carrying both hydrogen and nitrogen to the deep Earth. To further understand the link between nitrogen and dehydration process of phengite at an atomic level, we here carry out high temperature and high pressure vibrational spectroscopic investigations on hydroxyl and lattice of ammonium-bearing and ammonium-free phengites. The results show that heating to 800 ℃ hardly influences hydroxyl bonding strength, whereas pressure induces strengthening of hydrogen bonding until 10 GPa. Moreover, hydrogen transits between the sites with increasing temperature and pressure. The lattice modes soften with increasing temperature and stiffen under compression. Ammonium has no effect on hydroxyl bonding strength, but hinders hydrogen transition at high temperatures and high pressures. Ammonium does not influence the lattice at high pressures either, but delays softening of the lattice at high temperatures. These data unveil behavior of hydroxyl and lattice in phengite at high temperature and high pressure, and also evaluate ammonium impacts, shedding new lights on dehydration processes of phengite during subduction.
- hydroxyl,
- lattice,
- ammonium,
- phengite,
- high temperature,
- high pressure

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References(64)

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Ammonium Impacts on Vibrations of Hydroxyl and Lattice of Phengite at High Temperature and High Pressure

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