Genesis of Manganese Deposits in the Ali Khanzai Block of the Zhob Ophiolite, Pakistan: Inferences from Geochemistry and Mineralogy

Khan Muhammad Ayoub; Kakar Muhammad Ishaq; Thomas Ulrich; Liaqat Ali; Andrew C. Kerr; Khalid Mahmood; Siddiqui Rehanul Haq

doi:10.1007/s12583-020-1337-3

Volume 31 Issue 5

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Journal of Earth Science > 2020 > 31(5): 884-895.

Khan Muhammad Ayoub, Kakar Muhammad Ishaq, Thomas Ulrich, Liaqat Ali, Andrew C. Kerr, Khalid Mahmood, Siddiqui Rehanul Haq. Genesis of Manganese Deposits in the Ali Khanzai Block of the Zhob Ophiolite, Pakistan: Inferences from Geochemistry and Mineralogy. Journal of Earth Science, 2020, 31(5): 884-895. doi: 10.1007/s12583-020-1337-3

Citation:

Khan Muhammad Ayoub, Kakar Muhammad Ishaq, Thomas Ulrich, Liaqat Ali, Andrew C. Kerr, Khalid Mahmood, Siddiqui Rehanul Haq. Genesis of Manganese Deposits in the Ali Khanzai Block of the Zhob Ophiolite, Pakistan: Inferences from Geochemistry and Mineralogy. Journal of Earth Science, 2020, 31(5): 884-895. doi: 10.1007/s12583-020-1337-3

Citation:

Khan Muhammad Ayoub, Kakar Muhammad Ishaq, Thomas Ulrich, Liaqat Ali, Andrew C. Kerr, Khalid Mahmood, Siddiqui Rehanul Haq. Genesis of Manganese Deposits in the Ali Khanzai Block of the Zhob Ophiolite, Pakistan: Inferences from Geochemistry and Mineralogy. Journal of Earth Science, 2020, 31(5): 884-895. doi: 10.1007/s12583-020-1337-3

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Genesis of Manganese Deposits in the Ali Khanzai Block of the Zhob Ophiolite, Pakistan: Inferences from Geochemistry and Mineralogy

doi: 10.1007/s12583-020-1337-3

1.
Center of Excellence in Mineralogy, University of Balochistan, Quetta, Pakistan
2.
Department of Geoscience, Aarhus University, Høegh-Guldbergs Gade 2, DK-8000 Aarhus C, Denmark
3.
National Center of Excellence in Geology, University of Peshawar, Peshawar, Pakistan
4.
School of Earth and Ocean Sciences, Cardiff University, Cardiff, Wales CF10 3YE, UK
5.
Department of Earth Sciences, University of Sargodha, Sargodha, Pakistan
6.
Balochistan University of Information Technology, Engineering and Management Sciences, Quetta, Pakistan

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Corresponding author: Muhammad Ayoub Khan, ayoub.cemuob@gmail.com
Received Date: 07 Oct 2019
Accepted Date: 25 Apr 2020
Publish Date: 20 Oct 2020

Abstract

Abstract

The Zhob ophiolite comprises the Naweoba,Omzha and Ali Khanzai blocks,which are surrounded by the sediments of the Alozai Group and Loralai Formation. The Ali Khanzai Block contains metamorphic,ultramafic,gabbroic,volcanic and volcaniclastic rocks with associated chert. The Zhob manganese deposits found in the Ali Khanzai Block,occur in banded,lenticular and massive forms within red to brown coloured metachert. Braunite and pyrolusite are the main constituent manganese-bearing minerals with minor hausmannite,hematite and barite while quartz is the major gangue mineral with some carbonate minerals. Geochemical evidence from the major oxides indicates that the manganese mineralization and associated metachert at Zhob were formed by hydrothermal activity with little contribution from contemporaneous volcanic materials and this is confirmed by high Fe/Mn and low Co/Zn ratios and trace element patterns. These deposits formed along with seafloor spreading centres and were later obducted as part of Ali Khanzai Block of Zhob ophiolite.
- Zhob ophiolite,
- manganese ore,
- hydrothermal,
- genesis

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References(62)

References

Abs-Wurmbach, I., Peters, T. J., Langer, K., et al., 1983. Phase Relations in the System Mn-Si-O and Experimental and Petrological Study. Neues Jahrbuchfür Mineralogie-Abhandlungen, 146: 258-279 http://www.researchgate.net/publication/281545488_Phase_relations_in_the_system_Mn-Si-O_an_experimental_and_petrological_study

Ahmad, Z., 1975. Geology and Petrochemistry of a Part of the Zhob Valley Igneous Complex, Balochistan, Pakistan. Geological Survey of Pakistan Record, 24: 1-35

Ahmed, Z., 1969. Directory of Mineral Deposits of Pakistan. Geological Survey of Pakistan Record, 15(3): 2000 http://www.getcited.org/pub/101372031

Ahmed, Z., 1992. Manganese Occurrences in Ophiolitic Rocks of Khuzdar District, Pakistan. Acta Mineralogica Pakistanica, 6: 65-73

Asif, M., 2014. Mineralogy, Geochemistry and Genesis of Manganese Deposit of Takht Area, Bajaur AGENCY, NW Pakistan: [Dissertation]. University of Peshawar, Peshawar

Bannert, D., Cheema, A., Ahmad, A., 1992. The Geology of the Western Fold Felt: Structural Interpretation of the Landsat-MSS Satellite Imagery 1 : 500 000. Federal Institute of Geosciences and Natural Resources, Han., Germany

Bilgrami, S. A., 1964a. Mineralogy and Petrology of the Central Part of the Hindubagh Igneous Complex, Hindubagh Mining District, Zhob Valley, West Pakistan. Geological Survey of Pakistan Record, 10: 28

Bilgrami, S. A., 1964b. Regional Distribution of the Chemically Different Chromites from Zhob Valley, West Pakistan. Geological Bulletin Punjab University, 4: 1-16

Bolton, B. R., Both, R., Exon, N. F., et al., 1988. Geochemistry and Mineralogy of Seafloor Hydrothermal and Hydrogenetic Mn Oxide Deposits from the Manus Basin and Bismarck Archipelago Region of the Southwest Pacific Ocean. Marine Geology, 85(1): 65-87. https://doi.org/10.1016/0025-3227(88)90084-9

Bonatti, E., Kraemer, T., Rydell, H., 1972. Classification and Genesis of Submarine Iron-Manganese Deposits. In: Horn, D. R., ed., Ferromanganese Deposits of the Ocean Floor. National Science Foundation, Washington, DC. 149-166

Bonatti, E., Zerbi, M., Kay, R., et al., 1976. Metalliferous Deposits from the Apennine Ophiolites: Mesozoic Equivalents of Modern Deposits from Oceanic Spreading Centers. Geological Society of America Bulletin, 87(1): 83-94. https://doi.org/10.1130/0016-7606(1976)87 < 83:mdftao > 2.0.co; 2 doi: 10.1130/0016-7606(1976)87<83:mdftao>2.0.co;2

Buehn, B., Stanistreet, I. G., Okrusch, M., 1992. Late Proterozoic Outer Shelf Manganese and Iron Deposits at Otjosondu (Namibia) Related to the Damaran Oceanic Opening. Economic Geology, 87(5): 1393-1411. https://doi.org/10.2113/gsecongeo.87.5.1393

Bukhari, S. W. H., Mohibullah, M., Kasi, A. K., et al., 2016. Biostratigraphy of the Eocene Nisai Formation in Pishin Belt, Western Pakistan. Journal of Himalayan Earth Sciences, 49(1): 17-29

Cannon, W. F., Force, E. R., 1983. Potential for High-Grade Shallow Marine Manganese Deposits in North America. In: Shanks, W. C. III, ed., Cameron Volume on Unconventional Mineral Deposits. New York Society Mining Engineers/American Institute of Mining, Metallurgy and Petroleum Engineers, 177-190

Choi, J. H., Hariya, Y., 1992. Geochemistry and Depositional Environment of Mn Oxide Deposits in the Tokoro Belt, Northeastern Hokkaido, Japan. Economic Geology, 87(5): 1265-1274. https://doi.org/10.2113/gsecongeo.87.5.1265

Crerar, D. A., Namson, J., Chyi, M. S., et al., 1982. Manganiferous Cherts of the Franciscan Assemblage; I, General Geology, Ancient and Modern Analogues, and Implications for Hydrothermal Convection at Oceanic Spreading Centers. Economic Geology, 77(3): 519-540. https://doi.org/10.2113/gsecongeo.77.3.519

Dasgupta, H. C., Manickavasagam, R., 1981. Chemical and X-Ray Investigation of Braunite from the Metamorphosed Manganiferous Sediments of India. Neues Jahrbuchfür Mineralogie-Abhandlungen, 142: 149-160 http://www.researchgate.net/publication/292957803_Chemical_and_X-ray_investigation_of_braunite_from_the_metamorphosed_manganiferous_sediments_of_India

Fernández, A., Moro, M. C., 1998. Origin and Depositional Environment of Ordovician Stratiform Iron Mineralization from Zamora (NW Iberian Peninsula). Mineralium Deposita, 33(6): 606-619. https://doi.org/10.1007/s001260050176

Frakes, L., Bolton, B. R., 1992. Effects of Ocean Chemistry, Sea Level, and Climate on the Formation of Primary Sedimentary Manganese Ore Deposits. Economic Geology, 87(5): 1207-1217. https://doi.org/10.2113/gsecongeo.87.5.1207

Frenzel, G., 1980. The Manganese Ore Minerals. In: Varentsov, I. M., Grasselly, G., eds., Geology and Geochemistry of Manganese. Schweizerbart'sche Verlagsbuchhandlung, Stuttgart

Gultekin, A. H., 1998. Geochemistry and Origin of the Oligocene Binkiliç Manganese Deposit, Thrace Basin, Turkey. Turkish Journal of Earth Sciences, 7: 11-24 http://dergipark.ulakbim.gov.tr/tbtkearth/article/view/5000026501

Gutzmer, J., Beukes, N. J., 1997. Mineralogy and Mineral Chemistry of Oxide-Facies Manganese Ores of the Postmasburg Manganese Field, South Africa. Mineralogical Magazine, 61(405): 213-231. https://doi.org/10.1180/minmag.1997.061.405.05

Hein, J. R., Gibbs, A. E., Clague, D. A., et al., 1996. Hydrothermal Mineralization along Submarine Rift Zones, Hawaii. Marine Georesources & Geotechnology, 14(2): 177-203. https://doi.org/10.1080/10641199609388310

Hein, J. R., Hsueh-Wen, Y., Gunn, S. H., et al., 1994. Composition and Origin of Hydrothermal Ironstones from Central Pacific Seamounts. Geochimica et Cosmochimica Acta, 58(1): 179-189. https://doi.org/10.1016/0016-7037(94)90455-3

Hein, J. R., Koschinsky, A., Halbach, P., et al., 1997. Iron and Manganese Oxide Mineralization in the Pacific. In: Nicholson, K., Hein, J. R., Buhn, B., et al., eds., Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Geological Society Special Publication, 123-138

Hein, J. R., Schulz, M. S., Gein, L. M., 1992. Central Pacific Cobalt Rich Ferromanganese Crusts: Historical Perspective and Regional Variability. In: Keating, B. H., Bolton, B. R., eds., Geology and Offshore Mineral Resources of the Central Pacific Basin. Springer-Verlag, Berlin. 261

Heron, A. M., Crookshank, H., 1954. Directory of Economic Minerals of Pakistan. Geological Survey of Pakistan Record, 7: 2

Ingram, B. L., Hein, J. R., Farmer, G. L., 1990. Age Determinations and Growth Rates of Pacific Ferromanganese Deposits Using Strontium Isotopes. Geochimica et Cosmochimica Acta, 54(6): 1709-1721. https://doi.org/10.1016/0016-7037(90)90402-7

Jach, R., Dudek, T., 2005. Origin of a Toarcian Manganese Carbonate/Silicate Deposit from the Krížna Unit, Tatra Mountains, Poland Chemical Geology, 224: 136-152

Jones, A. G., 1961. Reconnaissance Geology of Part of West Pakistan. A Colombo Plan Cooperative Project, Government of Canada, Toronto. 550

Karakuş, A., Yavuz, B., Koç, S., 2010. Mineralogy and Major-Trace Element Geochemistry of the Haymana Manganese Mineralizations, Ankara, Turkey. Geochemistry International, 48(10): 1014-1027. https://doi.org/10.1134/s001670291010006x

Kuhn, T., Bau, M., Blum, N., et al., 1998. Origin of Negative Ce Anomalies in Mixed Hydrothermal-Hydrogenetic Fe-Mn Crusts from the Central Indian Ridge. Earth and Planetary Science Letters, 163(1/2/3/4): 207-220. https://doi.org/10.1016/s0012-821x(98)00188-5

Lotfi, M., Kahrazehi, M., Ghaderi, M., 2017. Geochemistry and Origin of Dehoo Manganese Deposit, South Zahedan, Southeastern Iran. Arabian Journal of Geosciences, 10(6): 142. https://doi.org/10.1007/s12517-017-2865-8

Marta Polgári, P. M. O., 1991. Stable Isotope Evidence for the Origin of the Urkut Manganese Ore Deposit, Hungary. SEPM Journal of Sedimentary Research, 61(3): 384-393. https://doi.org/10.1306/d426771c-2b26-11d7-8648000102c1865d

Muan, A., 1959. Phase Equilibria in the System Manganese Oxide-SiO₂ in Air. American Journal of Science, 257(4): 297-315. https://doi.org/10.2475/ajs.257.4.297

Mücke, A., Dzigbodi-Adjimah, K., Annor, A., 1999. Mineralogy, Petrography, Geochemistry and Genesis of the Paleoproterozoic Birimian Manganese-Formation of Nsuta/Ghana. Mineralium Deposita, 34(3): 297-311. https://doi.org/10.1007/s001260050205

Naseem, S., 1996. Genesis of Manganese Ore Deposits of Lasbela Area, Balochistan, Pakistan: [Dissertation]. University of Karachi, Pakistan. 259

Naseem, S., Sheikh, S. A., Mallick, K. A., 1997. Lithiophorite and Associated Manganese Mineralization in Lasbela Area, Balochistan, Pakistan. Geosciences Journal, 1(1): 10-15. https://doi.org/10.1007/bf02910445

Nicholson, K., 1992. Contrasting Mineralogical-Geochemical Signatures of Manganese Oxides; Guides to Metallogenesis. Economic Geology, 87(5): 1253-1264. https://doi.org/10.2113/gsecongeo.87.5.1253

Nicholson, K., Nayak, V. K., Nanda, J. K., 1997. Manganese Ores of the Ghoriajhor-Monmunda Area, Sundergarh District, Orissa, India: Geochemical Evidence for a Mixed Mn Source. Geological Society, London, Special Publications, 119(1): 117-121. https://doi.org/10.1144/gsl.sp.1997.119.01.08

Öksüz, N., 2011. Geochemical Characteristics of the Eymir (Sorgun-Yozgat) Manganese Deposit, Turkey. Journal of Rare Earths, 29(3): 287-296. https://doi.org/10.1016/s1002-0721(10)60446-2

Öksüz, N., Okuyucu, N., 2014. Mineralogy, Geochemistry, and Origin of Buyukmahal Manganese Mineralization in the Artova Ophiolitic Complex, Yozgat, Turkey. Journal of Chemistry, 2014(3): 1-11. https://doi.org/10.1155/2014/837972

Ostwald, J., Nayak, V. K., 1993. Braunite Mineralogy and Paragenesis from the Kajlidongri Mine, Madhya Pradesh, India. Mineralium Deposita, 28(2): 153-156. https://doi.org/10.1007/bf00196340

Ozturk, H., 1993. Manganese Mineralizations in Turkey: Processes of Formation and Types. Geological Engineering, 43: 24-33 (in Turkish)

Panagos, A. G., Varnavas, S. P., 1984. On the Genesis of Some Manganese Deposits from Eastern Greece. In: Wauschkuhn, A., ed., Syngenesis and Epigenesis in the Formation of Mineral Deposits. Spriger, Berlin. 553-561

Peters, T., 1988. Geochemistry of Manganese-Bearing Cherts Associated with Alpine Ophiolites and the Hawasina Formations in Oman. Marine Geology, 84(3/4): 229-238. https://doi.org/10.1016/0025-3227(88)90103-x

Polgári, M., Hein, J. R., Vigh, T., et al., 2012. Microbial Processes and the Origin of the Úrkút Manganese Deposit, Hungary. Ore Geology Reviews, 47: 87-109. https://doi.org/10.1016/j.oregeorev.2011.10.001

Rehman, S., 2019. Petrology of Ali Khanzai Block of Zhob Ophiolite, Balochistan, Pakistan: [Dissertation]. University of Balochistan, Quetta. 78

Roy, S., 1981. Manganese Deposits, Academic Press, London. 458

Roy, S., 1992. Environments and Processes of Manganese Deposition. Economic Geology, 87(5): 1218-1236. https://doi.org/10.2113/gsecongeo.87.5.1218

Roy, S., 1997. Genetic Diversity of Manganese Deposition in the Terrestrial Geological Record. In: Nicholson, K., Hein, J. R., Buhn, B., et al., eds., Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Geological Society of London Special Publication, 119: 5-27

Roy, S., Bandopadhyay, P. C., Perseil, E. A., et al., 1990. Late Diagenetic Changes in Manganese Ores of the Upper Proterozoic Penganga Group, India. Ore Geology Reviews, 5(4): 341-357. https://doi.org/10.1016/0169-1368(90)90038-o

Sabatino, N., Neri, R., Bellanca, A., et al., 2011. Petrography and High-Resolution Geochemical Records of Lower Jurassic Manganese-Rich Deposits from Monte Mangart, Julian Alps. Palaeogeography, Palaeoclimatology, Palaeoecology, 299(1/2): 97-109. https://doi.org/10.1016/j.palaeo.2010.10.039

Şaşmaz, A., Türkyilmaz, B., Öztürk, N., et al., 2014. Geology and Geochemistry of Middle Eocene Maden Complex Ferromanganese Deposits from the Elazığ-Malatya Region, Eastern Turkey. Ore Geology Reviews, 56: 352-372. https://doi.org/10.1016/j.oregeorev.2013.06.012

Şengor, A. M. C., 1987. Tectonics of the Tethysides: Orogenic Collage Development in a Collisional Setting. Annual Review of Earth and Planetary Sciences, 15(1): 213-244. https://doi.org/10.1146/annurev.ea.15.050187.001241

Shah, M. T., Khan, A., 1999. Geochemistry and Origin of Mn-Deposits in the Waziristan Ophiolite Complex, North Waziristan, Pakistan. Mineralium Deposita, 34(7): 697-704. https://doi.org/10.1007/s001260050228

Shah, M. T., Moon, C. J., 2004. Mineralogy, Geochemistry and Genesis of the Ferromanganese Ores from Hazara Area, NW Himalayas, Northern Pakistan. Journal of Asian Earth Sciences, 23(1): 1-15. https://doi.org/10.1016/s1367-9120(03)00099-3

Sugisaki, R., 1984. Relation between Chemical Composition and Sedimentation Rate of Pacific Ocean-Floor Sediments Deposited since the Middle Cretaceous: Basic Evidence for Chemical Constraints on Depositional Environments of Ancient Sediments. The Journal of Geology, 92(3): 235-259. https://doi.org/10.1086/628858

Toth, J. R., 1980. Deposition of Submarine Crusts Rich in Manganese and Iron. Geological Society of America Bulletin, 91(1): 44-54. https://doi.org/10.1130/0016-7606(1980)91 < 44:doscri > 2.0.co; 2 doi: 10.1130/0016-7606(1980)91<44:doscri>2.0.co;2

Usui, A., Nishimura, A., 1992. Submersible Observations of Hydrothermal Manganese Deposits on the Kaikata Seamount, Izu-Ogasawara (Bonin) Arc. Marine Geology, 106(3/4): 203-216. https://doi.org/10.1016/0025-3227(92)90130-a

Usui, A., Someya, M., 1997. Distribution and Composition of Marine Hydrogenetic and Hydrothermal Manganese Deposits in the Northwest Pacific. Geological Society, London, Special Publications, 119(1): 177-198. https://doi.org/10.1144/gsl.sp.1997.119.01.12

Zarasvandi, A., Lentz, D., Rezaei, M., et al., 2013. Genesis of the Nasirabad Manganese Occurrence, Fars Province, Iran: Geochemical Evidences. Geochemistry, 73(4): 495-508. https://doi.org/10.1016/j.chemer.2013.02.003

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