Citation: | Chenggui Lin, Xiaofeng Yao, Jingwen Mao, Tingjie Yan, Zhizhong Cheng, Kuifeng Mi, Hongxiang Jia, Lujun Lin. Source of Ore-Forming Fluid and Material in the Baiyun Gold Deposit, Liaoning Province, NE China: Constraints from H-O-S-Pb Isotopes and in-situ Analyses of Au-Bearing Pyrites. Journal of Earth Science, 2023, 34(1): 1-19. doi: 10.1007/s12583-021-1420-4 |
The Baiyun deposit is a large gold deposit at the western end of the Liaoji rift zone in Liaoning Province, which has produced both auriferous quartz-vein type and altered-rock type mineralization. The ore bodies are mainly hosted in schist from the Gaixian Formation of the Liaohe Group. A detailed field geological survey showed that the quartz-vein type gold ore bodies are distributed in the near EW-trending and occur in the extensional tectonic space of schist in the Gaixian Formation, and the altered-rock type gold ore bodies are distributed in the near EW-trending structural belt and occur near in the Gaixian Formation of biotite schist, biotite granulite, marble and the upper footwall of dike. To further elucidate the source of ore-forming fluid and material in the Baiyun gold deposit, the H-O isotopes for quartz, S and Pb isotopes,
Bajwah, Z. U., Seccombe, P. K., Offler, R., 1987. Trace Element Distribution, Co: Ni Ratios and Genesis of the Big Cadia Iron-Copper Deposit, New South Wales, Australia. Mineralium Deposita, 22(4): 292–300. https://doi.org/10.1007/BF00204522 |
Bi, J. H., Xing, D. H., Ge, W. C., et al., 2018. Age and Tectonic Setting of Meta-Acid Volcanic Rocks from the North Liaohe Group in the Liaodong Area: Paleoproterozoic Intracontinental Rift or Active Continental Margin?. Earth Science Frontiers, 25(3): 295-309. https://doi.org/10.13745/j.esf.2018.03.024 (in Chinese with English Abstract) |
Chen, J. F., Yu, G., Xue, C. J., et al., 2005. Pb Isotope Geochemistry of Lead, Zinc, Gold and Silver Deposit Clustered Region, Liaodong Rift Zone, Northeastern China. Science in China Series D: Earth Sciences, 48(4): 467–476. https://doi.org/10.1360/03yd0163 |
Chen, S., Li, X. P., Kong, F. M., et al., 2018. Metamorphic Evolution and Zircon U-Pb Ages of the Nanshankou Mafic High Pressure Granulites from the Jiaobei Terrane, North China Craton. Journal of Earth Science, 29(5): 1219–1235. https://doi.org/10.1007/s12583-017-0956-9 |
Chew, D. M., Babechuk, M. G., Cogné, N., et al., 2016. (LA, Q)-ICPMS Trace-Element Analyses of Durango and McClure Mountain Apatite and Implications for Making Natural LA-ICPMS Mineral Standards. Chemical Geology, 435: 35–48. https://doi.org/10.1016/j.chemgeo.2016.03.028 |
Clayton, R. N., Mayeda, T. K., 1963. The Use of Bromine Pentafluoride in the Extraction of Oxygen from Oxides and Silicates for Isotopic Analysis. Geochimica et Cosmochimica Acta, 27(1): 43–52. https://doi.org/10.1016/0016-7037(63)90071-1 |
Clayton, R. N., O'eil, J. R., Mayeda, T. K., 1972. Oxygen Isotope Exchange between Quartz and Water. Journal of Geophysical Research, 77(17): 3057–3067. https://doi.org/10.1029/jb077i017p03057 |
Deditius, A. P., 2014. The Coupled Geochemistry of Au and As in Pyrite from Hydrothermal Ore Deposits. Geochimica et Cosmochimica Acta, 140: 644–670. https://doi.org/10.1016/j.gca.2014.05.045 |
Deng, J., Liu, X., Wang, Q. F., et al., 2015. Origin of the Jiaodong-Type Xinli Gold Deposit, Jiaodong Peninsula, China: Constraints from Fluid Inclusion and C-D-O-S-Sr Isotope Compositions. Ore Geology Reviews, 65: 674–686. https://doi.org/10.1016/j.oregeorev.2014.04.018 |
Di, Q. Y., Xue, G. Q., Zeng, Q. D., et al., 2020. Magnetotelluric Exploration of Deep-Seated Gold Deposits in the Qingchengzi Orefield, Eastern Liaoning (China), Using a SEP System. Ore Geology Reviews, 122: 103501. https://doi.org/10.1016/j.oregeorev.2020.103501 |
Duan, X. X., Zeng, Q. D., Wang, J. B., et al., 2017. Genesis of the Pb-Zn Deposits of the Qingchengzi Ore Field, Eastern Liaoning, China: Constraints from Carbonate LA-ICPMS Trace Element Analysis and C-O-S-Pb Isotopes. Ore Geology Reviews, 89: 752–771. https://doi.org/10.1016/j.oregeorev.2017.07.012 |
Fan, H. R., Li, X. H., Zuo, Y. B., et al., 2018. In situ LA (MC) ICPMS and (Nano) SIMS Trace Elements and Sulfur Isotope Analyses on Sulfides and Application to Confine Metallogenic Process of Ore Deposit. Acta Petrologica Sinica, 34(12): 3479–3496 (in Chinese with English Abstract) |
Fu, J. L., Hu, Z. C., Zhang, W., et al., 2016. In situ Sulfur Isotopes (δ34S and δ33S) Analyses in Sulfides and Elemental Sulfur Using High Sensitivity Cones Combined with the Addition of Nitrogen by Laser Ablation MC-ICP-MS. Analytica Chimica Acta, 911: 14–26. https://doi.org/10.1016/j.aca.2016.01.026 |
Guo, C. Y., 2009. Tectonic Setting, Magmatic Sequence and Fluid of Gold Metallogenic System in the Sanshandao-Cangshang Fault: [Dissertation]. China University of Geosciences, Beijing. 1-185 (in Chinese with English Abstract) |
Hao, L. B., Zhao, X., Zhao, Y. Y., 2017. Stable Isotope Characteristics and Ore Genesis of the Baiyun Gold Deposit, Liaoning Province. Journal of Jilin University (Earth Science Edition), 47(2): 442–451. https://doi.org/10.13278/j.cnki.jjuese.201702110 (in Chinese with English Abstract) |
He, C. Z., Zhang, D. H., Wu, M. Q., et al., 2017. Fluid Inclusion of Yaojiagou Porphyry Mo Deposit in Qingchengzi in Liaoning Province. Journal of Jilin University (Earth Science Edition), 47(6): 1717–1731. https://doi.org/10.13278/j.cnki.jjuese.201706111 (in Chinese with English Abstract) |
Lang, F. Q., Chen, H., Liu, H. G., 2007. Geologic Characteristics and Ore Prospecting Orientation of Baiyun Gold Deposit in Liaoning Province. Gold, 28(11): 16–20 (in Chinese with English Abstract) |
Large, R. R., Danyushevsky, L., Hollit, C., et al., 2009. Gold and Trace Element Zonation in Pyrite Using a Laser Imaging Technique: Implications for the Timing of Gold in Orogenic and Carlin-Style Sediment-Hosted Deposits. Economic Geology, 104(5): 635–668. https://doi.org/10.2113/gsecongeo.104.5.635 |
Li, D. D., Wang, Y. W., Zhang, Z. C., et al., 2019. Characteristics of Metallotectonics and Ore-Forming Structural Plane in Baiyun Gold Deposit, Liaoning. Journal of Geomechanics, 25(S1): 10–20. https://doi.org/10.12090/j.issn.1006-6616.2019.25.S1.003 (in Chinese with English Abstract) |
Li, D. D., Wang, Y. W., Zhou, G. C., et al., 2016. Preliminary Analysis of the Relationship between Dikes and Gold Mineralization in Baiyun Gold Deposit, Liaoning. Mineral Exploration, 7(1): 113–119 (in Chinese with English Abstract) doi: 10.3969/j.issn.1674-7801.2016.01.013 |
Li, J. X., Deng, J., Wu, W. G., et al. 2004. Study on the Sulfur-Lead Isotope of Zhaoyuan Gold Mineralization Area and Wall Rocks. Geoscience, 18(2): 187–192 (in Chinese with English Abstract) |
Li, J., Wang, K. Y., Cai, W. Y., et al., 2020. Triassic Gold-Silver Metallogenesis in Qingchengzi Orefield, North China Craton: Perspective from Fluid Inclusions, REE and H-O-S-Pb Isotope Systematics. Ore Geology Reviews, 121: 103567. https://doi.org/10.1016/j.oregeorev.2020.103567 |
Li, L., Santosh, M., Li, S. R., 2015. The 'Jiaodong Type' Gold Deposits: Characteristics, Origin and Prospecting. Ore Geology Reviews, 65: 589–611. https://doi.org/10.1016/j.oregeorev.2014.06.021 |
Li, S. Z., Zhao, G. C., Sun, M., et al., 2006. Are the South and North Liaohe Groups of North China Craton Different Exotic Terranes? Nd Isotope Constraints. Gondwana Research, 9(1/2): 198–208. https://doi.org/10.1016/j.gr.2005.06.011 |
Liu, G. P., Ai, Y. F., 1999. A Discussion on some Major Problems of the Baiyun Gold Deposit, Eastern Liaoning. Mineral Deposits, 18(3): 219–225, 290 (in Chinese with English Abstract) doi: 10.3969/j.issn.0258-7106.1999.03.003 |
Liu, J., Liu, F. X., Li, S, H., et al., 2019. Formation of the Baiyun Gold Deposit, Liaodong Gold Province, NE China: Constraints from Zircon U-Pb Age, Fluid Inclusion, and C-H-O-Pb-He Isotopes. Ore Geology Reviews, 104: 686–706. https://doi.org/10.1016/j.oregeorev.2018.12.006 |
Liu, Y. S., Hu, Z. C., Gao, S., et al., 2008. In situ Analysis of Major and Trace Elements of Anhydrous Minerals by LA-ICP-MS without Applying an Internal Standard. Chemical Geology, 257(1/2): 34–43. https://doi.org/10.1016/j.chemgeo.2008.08.004 |
Liu, Z. Y., Xu, X. C., 2007. Synthetic Information Models and Analyses of Prospecting Perspective of the Qingchengzi Polymetal Metallogenic Mine in Eastern Liaoning Province. Journal of Jilin University (Earth Science Edition), 37(3): 437–443. https://doi.org/10.13278/j.cnki.jjuese.2007.03.004 (in Chinese with English Abstract) |
Mao, J. W., Li, H, M., Wang, Y. T., et al., 2005. The Relationship between Mantle-Derived Fluid and Gold Ore-Formation in the Eastern Shandong Peninsula: Evidences from D-O-C-S Isotopes. Acta Geologica Sinica, 79(6): 839–857. https://doi.org/10.1360/gs050303 (in Chinese with English Abstract) |
Muntean, J. L., Cline, J. S., Simon, A. C., et al., 2011. Magmatic-Hydrothermal Origin of Nevada's Carlin-Type Gold Deposits. Nature Geoscience, 4(2): 122–127. https://doi.org/10.1038/ngeo1064 |
Reich, M., Kesler, S. E., Utsunomiya, S., et al., 2005. Solubility of Gold in Arsenian Pyrite. Geochimica et Cosmochimica Acta, 69(11): 2781–2796. https://doi.org/10.1016/j.gca.2005.01.011 |
Rye, R. O., 1993. The Evolution of Magmatic Fluids in the Epithermal Environment: The Stable Isotope Perspective. Economic Geology, 88(3): 733–752. https://doi.org/10.2113/gsecongeo.88.3.733 |
Sun, G. T., Zeng, Q. D., Li, T. Y., et al., 2019. Ore Genesis of the Baiyun Gold Deposit in Liaoning Province, NE China: Constraints from Fluid Inclusions and Zircon U-Pb Ages. Arabian Journal of Geosciences, 12(9): 299. https://doi.org/10.1007/s12517-019-4459-0 |
Sun, G. T., Zeng, Q. D., Zhou, L. L., 2020. Trace Element Contents and in Situ Sulfur Isotope Analyses of Pyrite in the Baiyun Gold Deposit, NE China: Implication for the Genesis of Intrusion-Related Gold Deposits. Ore Geology Reviews, 118: 103330. https://doi.org/10.1016/j.oregeorev.2020.103330 |
Sun, W. D., McDonough, W., 1989. Chemical and Isotopic Systematics of Oceanic Basalts: Implications for Mantle Composition and Processes. Geological Society, London, Special Publications, 42(1): 313-345. https://doi.org/10.1144/GSL.SP.1989.042.01.19 |
Sun, X. J., Ni, P., Yang, Y. L., et al., 2020. Constraints on the Genesis of the Qixiashan Pb-Zn Deposit, Nanjing: Evidence from Sulfide Trace Element Geochemistry. Journal of Earth Science, 31(2): 287–297. https://doi.org/10.1007/s12583-019-1270-5 |
Tang, Y. J., Zhang, H. F., Ying, J. F., et al., 2013. Widespread Refertilization of Cratonic and Circum-Cratonic Lithospheric Mantle. Earth-Science Reviews, 118: 45–68. https://doi.org/10.1016/j.earscirev.2013.01.004 |
Taylor, H. P., 1974. The Application of Oxygen and Hydrogen Isotope Studies to Problems of Hydrothermal Alteration and Ore Deposition. Economic Geology, 69(6): 843–883. https://doi.org/10.2113/gsecongeo.69.6.843 |
Wang, Q. F., Deng, J., Huang, D. H., et al., 2011. Deformation Model for the Tongling Ore Cluster Region, East-Central China. International Geology Review, 53(5/6): 562–579. https://doi.org/10.1080/00206814.2010.496236 |
Wang, X. Y., Yang, Z., Chen, N. S., et al., 2018. Petrogenesis and Ore Genesis of the Late Yanshanian Granites and Associated Porphyry-Skarn W-Mo Deposits from the Yunkai Area of South China: Evidence from the Zircon U-Pb Ages, Hf Isotopes and Sulfide S-Fe Isotopes. Journal of Earth Science, 29(4): 939–959. https://doi.org/10.1007/s12583-017-0901-1 |
Wang, Y. W., Xie, H. J., Li, D. D., et al., 2017. Prospecting Prediction of Ore Concentration Area Exemplified by Qingchengzi Pb-Zn-Au-Ag Ore Concentration Area, Eastern Liaoning Province. Mineral Deposits, 36(1): 1–24. https://doi.org/10.16111/j.0258-7106.2017.01.001 (in Chinese with English Abstract) |
Wang, Y. W., Xu, J. H., Ding, R. F., et al., 2020. Ore Forming Fluids of Several Gold Deposits in the Irtysh Gold Belt, Xinjiang, China. Journal of Earth Science, 31(2): 298–312. https://doi.org/10.1007/s12583-019-1274-1 |
Wei, J., Wang, E. D., Liu, F. X., et al., 2019. Geological Characteristics, Ore Genesis and Prospecting Direction of Baiyun Gold Belt in Fengcheng City, Liaoning Province. Metal Mine, (8): 120–130. https://doi.org/10.19614/j.cnki.jsks.201908022 (in Chinese with English Abstract) |
Xie, H. J., Wang, Y. W., Li, D. D., et al., 2018. Geochronology and Geochemistry Study of the Shuangdinggou Intrusion in the Qingchengzi Ore Concentration Area, Eastern Liaoning Province. Acta Geologica Sinica, 92(6): 1264-1279 (in Chinese with English Abstract) doi: 10.3969/j.issn.0001-5717.2018.06.011 |
Xu, L., Yang, J. H., Zeng, Q. D., et al., 2020. Pyrite Rb-Sr, Sm-Nd and Fe Isotopic Constraints on the Age and Genesis of Pb-Zn Deposits in Qingchengzi, Northeastern China. Ore Geology Reviews, 117: 103324. https://doi.org/10.1016/j.oregeorev.2020.103324 |
Xue, J. L., Pang, Z. S., Li, S. R., et al., 2019. The Genesis of Denggezhuang Gold Deposit in Jiaodong: Constraints from Multigeological Chronology and Isotope System. Acta Petrologica Sinica, 35(5): 1532–1550 (in Chinese with English Abstract) doi: 10.18654/1000-0569/2019.05.14 |
Yang, F. C., Song, Y. H., Chai, P., et al., 2017. Characteristics of Ore-Forming Fluids, Source of Ore-Forming Materials and Genesis of Baiyun Gold Deposit in Liaoning Province. Journal of Mineralogy and Petrology, 37(1): 30-39 (in Chinese with English Abstract) |
Yu, G., Chen, J. F., Xue, C. J., et al., 2009. Geochronological Framework and Pb, Sr Isotope Geochemistry of the Qingchengzi Pb-Zn-Ag-Au Orefield, Northeastern China. Ore Geology Reviews, 35(3/4): 367–382. https://doi.org/10.1016/j.oregeorev.2008.11.009 |
Zartman, R. E., Roe, B. R., 1981. Plumbotectonics—The Model. Tectonophysics, 75(1/2): 135–162. https://doi.org/10.1016/0040-1951(81)90213-4 |
Zhang, P., Kou, L. L., Zhao, Y., 2019. Fluid Inclusions, H-O, S, Pb, and Noble Gas Isotope Studies of the Baiyun Gold Deposit in the Qingchengzi Orefield, NE China. Journal of Geochemical Exploration, 200: 37–53. https://doi.org/10.1016/j.gexplo.2019.01.016 |
Zhang, P., Kou, L. L., Zhao, Y., et al., 2020. Genesis of the Wulong Gold Deposit, Liaoning Province, NE China: Constrains from Noble Gases, Radiogenic and Stable Isotope Studies. Geoscience Frontiers, 11(2): 547–563. https://doi.org/10.1016/j.gsf.2019.05.012 |
Zhang, P., Yang, H. Z., Li B., 2016. Ore Source, Ore-Forming Age and Geodynamic Setting of Yaojiagou Molybdenum Deposit in Qingchengzi Ore-Clustered Area, Eastern Liaoning Province. Journal of Jilin University (Earth Science Edition), 46(6): 1684–1696. https://doi.org/10.13278/j.cnki.jjuese.201606108 (in Chinese with English Abstract) |
Zhang, W., Hu, Z. C., Gunther, D., et al., 2016. Direct Lead Isotope Analysis in Hg-Rich Sulfides by LA-MC-ICP-MS with a Gas Exchange Device and Matrix-Matched Calibration. Analytica Chimica Acta, 948: 9–18. https://doi.org/10.1016/j.aca.2016.10.040 |
Zhao, H. Z., Yang, S. S., Li, H., 2009. Geologic Features of Baiyun Gold Ore Deposit and Discussion of the Genesis. Non-Ferrous Mining and Metallurgy, 25(3): 4–7 (in Chinese with English Abstract) |
Zhao, Y., Yang, H. Z., Yang, F. C., et al., 2020. Genesis of the Typical Gold Deposits in Qingchengzi Orefield, Liaodong Peninsula: Evidences from S-D-O Isotopes. Geology and Resources, 29(1): 21-28 (in Chinese with English Abstract) |
Zhao, Z. H., Zhao, H. L., Yang, W. H., et al., 1987. Trace Element Geochemical Characteristics of Cambrian-Ordovician Boundary Strata in the Duibian and Wushan Profiles. Geochimica, 16(2): 99–112 (in Chinese with English Abstract) |
Zhou, G. C., Wang, Y. W., Li, D. D., 2017. LA-ICP-MS Zircon U-Pb Dating of Dykes from the Baiyun Gold Deposit in Eastern Liaoning. Bulletin of Mineralogy, Petrology and Geochemistry, 36(4): 620–627. https://doi.org/10.3969/j.issn.1007-2802.2017.04.014 (in Chinese with English Abstract) |
Zhu, B. Q., 1998. Theory and Application of Isotopic Systems in Geosciences: Also on Crust and Mantle Evolution in China Mainland. Science Press, Beijing. 1-330 (in Chinese) |
Zhu, R. X., Fan, H. R., Li, J. W., et al., 2015. Decratonic Gold Deposits. Science China Earth Sciences, 58(9): 1523–1537. https://doi.org/10.1007/s11430-015-5139-x |
Zhu, Z. X., Zhao, X. F., Lin, Z. W., et al., 2020. In situ Trace Elements and Sulfur Isotope Analysis of Pyrite from Jinchiling Gold Deposit in the Jiaodong Region: Implications for Ore Genesis. Earth Science, 45(3): 945–959 (in Chinese with English Abstract) |
Zong, K. Q., Klemd, R., Yuan, Y., et al., 2017. The Assembly of Rodinia: The Correlation of Early Neoproterozoic (Ca. 900 Ma) High-Grade Metamorphism and Continental Arc Formation in the Southern Beishan Orogen, Southern Central Asian Orogenic Belt (CAOB). Precambrian Research, 290: 32–48. https://doi.org/10.1016/j.precamres.2016.12.010 |