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Volume 36 Issue 3
Jun 2025
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Journal of Earth Science  > 2025  >  36(3): 992-1017.
Yuchen Liu, Changqian Ma. Origins of Two Types of Serpentinites from Hong'an, Western Dabie Orogen, Central China and Associated Fluid/Melt-Rock Interactions: Implications from Geochemistry and Mineralogy. Journal of Earth Science, 2025, 36(3): 992-1017. doi: 10.1007/s12583-022-1774-2
Citation: Yuchen Liu, Changqian Ma. Origins of Two Types of Serpentinites from Hong'an, Western Dabie Orogen, Central China and Associated Fluid/Melt-Rock Interactions: Implications from Geochemistry and Mineralogy. Journal of Earth Science, 2025, 36(3): 992-1017. doi: 10.1007/s12583-022-1774-2
shu

Origins of Two Types of Serpentinites from Hong'an, Western Dabie Orogen, Central China and Associated Fluid/Melt-Rock Interactions: Implications from Geochemistry and Mineralogy

doi: 10.1007/s12583-022-1774-2
  • 1.

    State Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China

  • 2.

    Strategic Research Center of Oil and Gas Resources, Ministry of Natural Resources, Beijing 100860, China

More Information
  • Corresponding author: Changqian Ma, cqma@cug.edu.cn
  • Received Date: 29 Jul 2022
  • Accepted Date: 03 Nov 2022
    • Available Online: 11 Jun 2025
  • Issue Publish Date: 30 Jun 2025
    Abstract

  • A cluster of serpentinite bodies has been recognized tectonically emplaced within the greenschist-amphibolite-facies metamorphic terrane in Hong'an, western Dabie orogen, central China. Two types of serpentinites are identified on the basis of integrated petrographic, mineralogical and geochemical study. The first type, represented by Yinshanzhai serpentinite complex (Group 1) comprises heterogeneous lithology as a massive serpentinite matrix "intruded" by antigorite-enriched serpentinite lenses. They are both pseudomorphic textured with different mineral assemblages indicating an increasing temperature-pressure condition. Serpentinite matrix (Group 1a) is chemically characterized by high MgO/SiO2 and low Al2O3/SiO2, Ti and Ca contents, suggesting a depleted mantle wedge origin. The coexistence of compositionally-heterogeneous chromite with high-Cr# (0.78–0.96) and intermediate-Cr# (0.59–0.70) pristine cores indicates extensive mantle melting. Meanwhile, extremely high Fo olivine relicts (96–97) with considerably higher MnO and lower NiO contents than mantle olivine indicate that they are metamorphic products from serpentine decomposition. Accordingly, we propose that Yinshanzhai serpentinite complex experienced two distinct episodes of hydration. The serpentinite lenses (Group 1b) show higher SiO2 and lower MgO concentrations. Nevertheless, the trace elements of groups 1a and 1b are consistent: U-shaped REE patterns, positive Eu anomalies and enrichment of LILE (i.e., Cs, U) are all identified as forearc properties. They are affected by reducing slab-derived fluids in forearc mantle, with fO2 of 1 to 2 logarithmic units below fO2 of fayalite-magnetite-quartz buffer (FMQ-2~FMQ-1). The second type is antigorite-serpentinites (Group 2) represented by Ximaoshan and Wangchunwan blocks. They are non-pseudomorphic, with no primary framework silicate surviving. Fertile compositions (i.e., higher Al2O3 and Al2O3/SiO2, nearly flat REE patterns) and conjoint enrichment of LILE with HFSE suggest melt/rock interaction. Negative Ce, Eu anomalies, and enriched U relative to alkaline elements demonstrate interactions with more oxidized seawater or seafloor fluids (FMQ~FMQ-1). Remarkable Sr negative anomalies may be attributed to Sr release during lizardite/antigorite transition in subduction zone, indicating interaction with low-Sr slab fluids. We propose that Group 2 serpentinites originate either from mantle wedge or abyssal peridotites, refertilized by mantle melts, then hydrated in seafloor or shallow forearc and entrapped into subduction channel. Combined with geochronology and tectonic constraints of associated eclogites in Hong'an terrane, the two types of serpentinites may correlate with subduction of different oceanic basins during the late Paleozoic and/or Proterozoic eras. It raises possibility of defining an ophiolitic setting in Hong'an Orogen for which further evidence is required.

     

    • Electronic Supplementary Materials: Supplementary materials (Tables S1–S4) are available in the online version of this article at https://doi.org/10.1007/s12583-022-1774-2.
    Conflict of Interest
    The authors declare that they have no conflict of interest.
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