Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 13 Issue 1
Mar 2002
Turn off MathJax
Article Contents
Shuji Oishi, Hirafumi Yamamoto, Takaomi Suzuki. Growth of Emerald Crystals by Evaporation of Na2O-MoO3 Flux. Journal of Earth Science, 2002, 13(1): 35-39.
Citation: Shuji Oishi, Hirafumi Yamamoto, Takaomi Suzuki. Growth of Emerald Crystals by Evaporation of Na2O-MoO3 Flux. Journal of Earth Science, 2002, 13(1): 35-39.

Growth of Emerald Crystals by Evaporation of Na2O-MoO3 Flux

  • Received Date: 07 Dec 2001
  • Accepted Date: 03 Jan 2002
  • Well-formed crystals of emerald, Be3Al2Si6O18 : Cr, were easily grown from an Na2O-MoO3 flux by an isothermal technique. The crystal growth was conducted by heating a mixture of solute and flux at 1 100 ℃ for 24 h. The evaporation loss of flux depended on the amount of Na2O added to MoO3. Emerald crystals of lengths up to 2.1 mm and widths of 1.4 mm were grown. The crystal sizes were dependent on the evaporation loss of the flux. The obtained crystals were transparent and exhibited the typical emerald~green color. The form of the emerald crystals was a twelve sided prism bounded by well~developed faces. The aspect ratios were in the region of 1.4 to 2.3. The density was (2.64±0.02) g/cm3. The IR absorption bands were in good agreement with the literature data.

     

  • loading
  • Elwell D. 1979. Man-Made Gemstones. Chichester: EIlls Horwood Ltd
    Elwell D, Scheel H J, 1975. Crystal Growth from High-Temperature Solutions. London: Aeademic Press
    Kodaira K, Iwase Y, Tsunashima A, Matsusbita T, 1982. High-Pressure Hydrothetmal Synthesis of Beryl Crystals. J Cryst Growth, 60: 172-174 doi: 10.1016/0022-0248(82)90193-2
    Miller R P. Mercer R A. 1965 The High-Temperature Behaviour of Beryl Melts and Glasses. Mineral Mag, 35: 250-276
    Nassau K, 1976. Synthetic Emerald: The Confusing History and the Current Technologies. J Cryst Growth, 35: 211-222 doi: 10.1016/0022-0248(76)90172-X
    Oishi S. Hirao M. 1991. Growth of Emerald Crystals from PbO-V2O5 Flux. J Mater Sci, 26: 6401-6407 doi: 10.1007/BF02387821
    Oishi S, Mochizuki K. 1993, Growth of Emerald Crystals by the Evaporation of Molybdenum Trioxide Flux. Brit Ceram Trans, 92: 214-216
    Oishi S, Mochizuki K, 1995. Growth of Emerald Crystals by the Evaporation of Li2O-MoO3 Flux. J Mater Chem, 5: 1257-1260 doi: 10.1039/JM9950501257
    Oishi S, Moehizuki K, Hirano S, 1994. Growth of Emerald Crystals by the Flux Evaporation Method in MoO3-B2O3 System. J Ceram Soc Jpn, 102: 502-504 doi: 10.2109/jcersj.102.502
    Oishi S, Yamamoto H. 1996. Growth of Emerald Crystals by Evaporation of a K2O-MoO3 Flux. J Mater Chem, 6: 1687-1691 doi: 10.1039/JM9960601687
    Ushio M, Sumiyoshi Y, 1972. Flux-Growth of Emerald Single Crystals. Nippon Kagaku Kaishi. 1648-1655
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(5)  / Tables(1)

    Article Metrics

    Article views(1134) PDF downloads(64) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return