Advanced Search

Indexed by SCI、CA、РЖ、PA、CSA、ZR、etc .

Volume 18 Issue 2
Apr 2007
Turn off MathJax
Article Contents
Journal of Earth Science  > 2007  >  18(2): 153-157.
Guiying Liao, Shengbin Jiang. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2): 153-157.
Citation: Guiying Liao, Shengbin Jiang. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2): 153-157.
shu

Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts

  • 1.

    Faculty of Material Science and Chemical Engineering, China University of Geosciences, Wuhan 430074, China

  • 2.

    Hubei Research Institute of Chemistry, Wuhan 430074, China

Funds:

China University of Geosciences CUGQNL0613

More Information
  • Corresponding author: Liao Guiying, liaogy2001@yahoo.com.cn
  • Received Date: 25 Jan 2007
  • Accepted Date: 20 Mar 2007
    Abstract

  • Poly (n-octyl acrylate) with uniform polystyrene grafts (POA-g-PS) was obtained by radical copolymerization of n-octyl acrylate (OA) with PS macromer, in solution. The reactivity ratio and effects of copolymerization conditions on grafting efficiency were studied. The crude products were purified by extraction with cyclohexane and n-butanol successively. POA-g-PS exhibited a very good compatibilizing effect on the acrylic rubber/polystyrene blends. 2%–3% of the graft copolymer was enough for enhancing the tensile strength of the blends. DSC and SEM demonstrated the enhancement of compatibility in the presence of the graft copolymer.

     

    • FullText(HTML)
  • loading
    • References(11)
  • Cui, M. H., Guo, J. S., Xie, H. Q., 1995. Synthesis, Characterization, and Conductivities of Poly (2-Vinylpyridine)-Graft-Polyoxyethylene Using a Macromer Technique. J. M. S. -Pure Appl. Chem., A32 (7): 1293–1303
    Ito, K., Usami, N., Yamashita, Y., 1980. Syntheses of Methyl Methacrylate-Stearyl Methacrylate Graft Copolymers and Characterization by Inverse Gas Chromatography. Macromolecules, 13: 216–221 doi: 10.1021/ma60074a003
    Kennedy, J. P., Hongu, Y., 1985. Synthesis and Characterization of Amphiphilic Polyisobutylene/Poly (Ethylene Glycol) Di- and Triblock Copolymers 2. Characterization of Polyisobutylene/Poly (Ethylene Glycol). Polym. Bull., 13(2): 123–130
    Liao, G. Y., Xie, H. Q., 2002. Synthesis of Amphiphilic Graft Copolymers (PAM-g-PBA) via Macromer Techniques. Petrochemical Technology and Application, 20(2): 88–92 (in Chinese with English Abstract)
    Liao, G. Y., Jiang, S. B., 2001. Synthesis of Polymethyl Methacrylate with Uniform Polybutyl Acrylate Grafts via Macromer Techniques. Advances in Fine Petrochemicals, 2(8): 5–10 (in Chinese with English Abstract)
    Shah, N. M., Pool, M. D., Metters, A. T., 2006. Influence of Network Structure on the Degradation of Photo-Cross-Linked PLA-b-PEG-b-PLA Hydrogels. Biomacromolecules, 7(11): 3171–3177 doi: 10.1021/bm060339z
    Wathier, M., Jung, P. J., Carnahan, M. A., et al., 2004. Dendritic Macromers as in situ Polymerizing Biomaterials for Securing Cataract Incisions. J. Am. Chem. Soc. (Communication), 126(40): 12744–12745 doi: 10.1021/ja045870l
    Xie, H. Q., Liao, G. Y., Gao, Y., 2004. Synthesis of Polyacrylamide with Pendant Poly (Butyl Acrylate) Chains Using the Macromer Technique and Studies on Their Properties. Chinese Journal of Polymer Science, 22 (1): 91–98
    Xie, H. Q., Pan, S. B., Guo, J. S., 2003. Ring-Opening Copolymerization of Epoxy-Terminated Polystyrene Macromer with Epichlorohydrin and Study on Properties of the Copolymers. European Polymer Journal, 39(4): 715–724 doi: 10.1016/S0014-3057(02)00277-X
    Xie, H. Q., Wu, X. D., Guo, J. S., 1994. Synthesis and Properties of Two Kinds of Amphiphilic Graft Copolymers with Well-Defined Structure. J. Appl. Polym. Sci., 54(8): 1079–1086 doi: 10.1002/app.1994.070540810
    Xie, H. Q., Xie, D., 1999. Molecular Design, Synthesis and Properties of Block and Graft Copolymers Containing Polyoxyethylene Segments. Prog. Polym. Sci., 24: 275–313 doi: 10.1016/S0079-6700(98)00020-3
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(1)  / Tables(7)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views(506) PDF downloads(33) Cited by()
    Proportional views
    Related

    Copyright © 2013-2020 Journal of Earth Science 鄂ICP备15021562号-2

    Tel: +86-27-67885075 Fax: +86-27-67885075 E-mail: xbb@cug.edu.cn

    Address: Editorial Office of Journal, China University of Geosciences, Yujiashan, Wuhan, Hubei 430074, P. R. China

    Supported by: Beijing Renhe Information Technology Co. Ltd  E-mail: info@rhhz.net  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return