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Volume 18 Issue 2
Apr.  2007
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廖桂英, 姜胜斌. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2).
Citation: 廖桂英, 姜胜斌. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2).

Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts

  • Received Date: 2018-07-15
  • Rev Recd Date: 2018-07-15
  • Publish Date: 2018-07-15
  • Poly(n-octylacrylate)withuniformpolystyrenegrafts(POA-g-PS)wasobtainedbyradicalcopolymerizationofn-octylacrylate(OA)withPSmacromer,insolution.Thereactivityratioandeffectsofcopolymerizationconditionsongraftingefficiencywerestudied.Thecrudeproductswerepurifiedbyextractionwithcyclohexaneandn-butanolsuccessively.POA-g-PSexhibitedaverygoodcompatibilizingeffectontheacrylicrubber/polystyreneblends.2%–3%ofthegraftcopolymerwasenoughforenhancingthetensilestrengthoftheblends.DSCandSEMdemonstratedtheenhancementofcompatibilityinthepresenceofthegraftcopolymer.
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通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts

Abstract: Poly(n-octylacrylate)withuniformpolystyrenegrafts(POA-g-PS)wasobtainedbyradicalcopolymerizationofn-octylacrylate(OA)withPSmacromer,insolution.Thereactivityratioandeffectsofcopolymerizationconditionsongraftingefficiencywerestudied.Thecrudeproductswerepurifiedbyextractionwithcyclohexaneandn-butanolsuccessively.POA-g-PSexhibitedaverygoodcompatibilizingeffectontheacrylicrubber/polystyreneblends.2%–3%ofthegraftcopolymerwasenoughforenhancingthetensilestrengthoftheblends.DSCandSEMdemonstratedtheenhancementofcompatibilityinthepresenceofthegraftcopolymer.

廖桂英, 姜胜斌. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2).
Citation: 廖桂英, 姜胜斌. Synthesis and Properties of Poly (n-Octyl Acrylate) with Uniform Polystyrene Grafts. Journal of Earth Science, 2007, 18(2).

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