2020, 31(3): 456-467.
doi: 10.1007/s12583-020-1305-y
Abstract:
The effects of melt composition, temperature and pressure on the solubility of fluorite (CaF2), i.e., fluorine concentration in silicate melts in equilibrium with fluorite, are summarized in this paper. The authors present a statistic study based on experimental data in literature and propose a predictive model to estimate F concentration in melt at the saturation of fluorite (CF in meltFl-sat). The modeling indicates that the compositional effect of melt cations on the variation in CF in meltFl-sat can be expressed quantitatively as one parameter FSI (fluorite saturation index):FSI=(3AlNM+Fe2++6Mg+Ca+1.5Na-K)/(Si+Ti+AlNF+Fe3+), in which all cations are in mole, and AlNF and AlNM are Al as network-forming and network-modifying cations, respectively. The dependence of CF in meltFl-sat on FSI is regressed as:CF in meltFl-sat=1.130-2.014·exp (1 000/T)+2.747·exp (P/T)+0.111·CmeltH2O+17.641·FSI, in which T is temperature in Kelvin, P is pressure in MPa, CmeltH2O is melt H2O content in wt.%, and CF in meltFl-sat is in wt.% (normalized to anhydrous basis). The reference dataset used to establish the expression for conditions within 540-1 010 ℃, 50-500 MPa, 0-7 wt.% melt H2O content, 0.4 to 1.7 for A/CNK, 0.3 wt.%-7.0 wt.% for CF in meltFl-sat. The discrepancy of CF in meltFl-sat between calculated and measured values is less than ±0.62 wt.% with a confidence interval of 95%. The expression of FSI and its effect on CF in meltFl-sat indicate that fluorine incorporation in silicate melts is largely controlled by bonding with network-modifying cations, favorably with Mg, AlNM, Na, Ca and Fe2+ in a decreasing order. The proposed model for predicting CF in meltFl-sat is also supported by our new experiments saturated with magmatic fluorite performed at 100-200 MPa and 800-900 ℃. The modeling of magma fractional crystallization emphasizes that the saturation of fluorite is dependent on both the compositions of primary magmas and their initial F contents.KEY WORDS:fluorine, fluorite solubility, silicate melt, experimental petrology.